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Title: Synthesis and physicochemical characterization of a porous coordination polymer of Sn-Cu xylarate: The structure of [Sn{sub 4}Cu{sub 8.5}(HL){sub 2}(L){sub 4}O{sub 2}(OH)(H{sub 2}O){sub 12.5}] {center_dot} 17.2H{sub 2}O

Abstract

A porous coordination polymer of Sn-Cu xylarate [Sn{sub 4}Cu{sub 8.5}(HL){sub 2}(L){sub 4}O{sub 2}(OH)(H{sub 2}O){sub 12.5}] {center_dot} 17.2H{sub 2}O (H{sub 5}L is xylaric acid) is synthesized for the first time and characterized by chemical analysis, IR spectroscopy, and X-ray diffraction. Centrosymmetric heterometallic fragments [Sn{sub 4}Cu{sub 6}(HL){sub 2}(L){sub 4}O{sub 2}(H{sub 2}O){sub 6}] (A) including copper Cu1-3 and tin Sn1,2 atoms are distinguished in the structure. The Cu4(OH){sub 0.5}(H{sub 2}O){sub 2.5} bridges connect A units into chains running along the c axis, and the Cu5(OH)(H{sub 2}O) bridges connect A fragments into layers perpendicular to the c axis. The Cu4,5 atoms form a framework whose voids accommodate the crystallization water molecules.

Authors:
;  [1];  [2];
  1. Mechnikov Odessa National University (Ukraine)
  2. Russian Academy of Sciences, Kurnakov Institute of General and Inorganic Chemistry (Russian Federation)
Publication Date:
OSTI Identifier:
22156327
Resource Type:
Journal Article
Journal Name:
Crystallography Reports
Additional Journal Information:
Journal Volume: 58; Journal Issue: 2; Other Information: Copyright (c) 2013 Pleiades Publishing, Ltd.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 1063-7745
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; CHEMICAL ANALYSIS; COPPER; CRYSTALLIZATION; INFRARED SPECTRA; LAYERS; POLYMERS; POROUS MATERIALS; SYNTHESIS; TIN; WATER; X-RAY DIFFRACTION

Citation Formats

Sergienko, V. S., E-mail: sergienko@igic.ras.ru, Chebanenko, E. A., Martsinko, E. E., Ilyukhin, A. B., and Seifullina, I. I. Synthesis and physicochemical characterization of a porous coordination polymer of Sn-Cu xylarate: The structure of [Sn{sub 4}Cu{sub 8.5}(HL){sub 2}(L){sub 4}O{sub 2}(OH)(H{sub 2}O){sub 12.5}] {center_dot} 17.2H{sub 2}O. United States: N. p., 2013. Web. doi:10.1134/S1063774513020247.
Sergienko, V. S., E-mail: sergienko@igic.ras.ru, Chebanenko, E. A., Martsinko, E. E., Ilyukhin, A. B., & Seifullina, I. I. Synthesis and physicochemical characterization of a porous coordination polymer of Sn-Cu xylarate: The structure of [Sn{sub 4}Cu{sub 8.5}(HL){sub 2}(L){sub 4}O{sub 2}(OH)(H{sub 2}O){sub 12.5}] {center_dot} 17.2H{sub 2}O. United States. https://doi.org/10.1134/S1063774513020247
Sergienko, V. S., E-mail: sergienko@igic.ras.ru, Chebanenko, E. A., Martsinko, E. E., Ilyukhin, A. B., and Seifullina, I. I. 2013. "Synthesis and physicochemical characterization of a porous coordination polymer of Sn-Cu xylarate: The structure of [Sn{sub 4}Cu{sub 8.5}(HL){sub 2}(L){sub 4}O{sub 2}(OH)(H{sub 2}O){sub 12.5}] {center_dot} 17.2H{sub 2}O". United States. https://doi.org/10.1134/S1063774513020247.
@article{osti_22156327,
title = {Synthesis and physicochemical characterization of a porous coordination polymer of Sn-Cu xylarate: The structure of [Sn{sub 4}Cu{sub 8.5}(HL){sub 2}(L){sub 4}O{sub 2}(OH)(H{sub 2}O){sub 12.5}] {center_dot} 17.2H{sub 2}O},
author = {Sergienko, V. S., E-mail: sergienko@igic.ras.ru and Chebanenko, E. A. and Martsinko, E. E. and Ilyukhin, A. B. and Seifullina, I. I.},
abstractNote = {A porous coordination polymer of Sn-Cu xylarate [Sn{sub 4}Cu{sub 8.5}(HL){sub 2}(L){sub 4}O{sub 2}(OH)(H{sub 2}O){sub 12.5}] {center_dot} 17.2H{sub 2}O (H{sub 5}L is xylaric acid) is synthesized for the first time and characterized by chemical analysis, IR spectroscopy, and X-ray diffraction. Centrosymmetric heterometallic fragments [Sn{sub 4}Cu{sub 6}(HL){sub 2}(L){sub 4}O{sub 2}(H{sub 2}O){sub 6}] (A) including copper Cu1-3 and tin Sn1,2 atoms are distinguished in the structure. The Cu4(OH){sub 0.5}(H{sub 2}O){sub 2.5} bridges connect A units into chains running along the c axis, and the Cu5(OH)(H{sub 2}O) bridges connect A fragments into layers perpendicular to the c axis. The Cu4,5 atoms form a framework whose voids accommodate the crystallization water molecules.},
doi = {10.1134/S1063774513020247},
url = {https://www.osti.gov/biblio/22156327}, journal = {Crystallography Reports},
issn = {1063-7745},
number = 2,
volume = 58,
place = {United States},
year = {Fri Mar 15 00:00:00 EDT 2013},
month = {Fri Mar 15 00:00:00 EDT 2013}
}