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Title: A series of 2D metal-quinolone complexes: Syntheses, structures, and physical properties

Abstract

Six novel 2D metal-quinolone complexes, namely [Cd(cfH)(bpdc)]{center_dot}H{sub 2}O (1), [M(norfH)(bpdc)]{center_dot}H{sub 2}O (M=Cd (2) and Mn (3)), [Mn{sub 2}(cfH)(odpa)(H{sub 2}O){sub 3}]{center_dot}0.5H{sub 2}O (4), [Co{sub 2}(norfH)(bpta)({mu}{sub 2}-H{sub 2}O)(H{sub 2}O){sub 2}]{center_dot}H{sub 2}O (5) and [Co{sub 3}(saraH){sub 2}(Hbpta){sub 2}(H{sub 2}O){sub 4}]{center_dot}9H{sub 2}O (6) (cfH=ciprofloxacin, norfH=norfloxacin, saraH=sarafloxacin, bpdc=4,4 Prime -biphenyldicarboxylate, odpa=4,4 Prime -oxydiphthalate, bpta=3,3 Prime ,4,4 Prime -biphenyltetracarboxylate) have been synthesized and characterized. Compounds 1-3 consist of 2D arm-shaped layers based on the 1D {l_brace}M(COO){r_brace}{sub n}{sup n+} chains. Compounds 4 and 5 display 2D structures based on tetranuclear manganese or cobalt clusters with (3,6)-connected kgd topology. Compound 6 exhibits a 2D bilayer structure, which represents the first example of metal-quinolone complexes with 2D bilayer structure. By inspection of the structures of 1-6, it is believed that the long aromatic polycarboxylate ligands are important for the formation of 2D metal-quinolone complexes. The magnetic properties of compounds 3-6 was studied, indicating the existence of antiferromagnetic interactions. Furthermore, the luminescent properties of compounds 1-2 are discussed. - Graphical abstract: Six novel 2D metal-quinolone complexes have been prepared by self-assemblies of the quinolones and metal salts in the presence of long aromatic polycarboxylates. Highlights: Black-Right-Pointing-Pointer Compounds 1-3 consist of novel 2D arm-shaped layers based on the 1D {l_brace}M(COO){r_brace}{sub n}{supmore » n+} chains. Black-Right-Pointing-Pointer Compounds 4 and 5 are two novel 2D layers based on tetranuclear Mn or Co clusters with kgd topology. Black-Right-Pointing-Pointer Compound 6 is the first example of metal-quinolone complexes with 2D bilayer structure. Black-Right-Pointing-Pointer Compounds 1-6 represent six unusual examples of 2D metal-quinolone complexes.« less

Authors:
 [1];  [1]; ; ; ; ;  [1];  [1];  [2]
  1. College of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715 (China)
  2. Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun 130024 (China)
Publication Date:
OSTI Identifier:
22150029
Resource Type:
Journal Article
Journal Name:
Journal of Solid State Chemistry
Additional Journal Information:
Journal Volume: 198; Other Information: Copyright (c) 2012 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0022-4596
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; ANTIFERROMAGNETISM; COBALT; HYDROTHERMAL SYNTHESIS; INTERACTIONS; LAYERS; LIGANDS; MAGNETIC PROPERTIES; MANGANESE; WATER

Citation Formats

He, Jiang-Hong, Xiao, Dong-Rong, Chen, Hai-Yan, Sun, Dian-Zhen, Yan, Shi-Wei, Wang, Xin, Ye, Zhong-Li, Luo, Qun-Li, and Wang, En-Bo. A series of 2D metal-quinolone complexes: Syntheses, structures, and physical properties. United States: N. p., 2013. Web. doi:10.1016/J.JSSC.2012.10.015.
He, Jiang-Hong, Xiao, Dong-Rong, Chen, Hai-Yan, Sun, Dian-Zhen, Yan, Shi-Wei, Wang, Xin, Ye, Zhong-Li, Luo, Qun-Li, & Wang, En-Bo. A series of 2D metal-quinolone complexes: Syntheses, structures, and physical properties. United States. doi:10.1016/J.JSSC.2012.10.015.
He, Jiang-Hong, Xiao, Dong-Rong, Chen, Hai-Yan, Sun, Dian-Zhen, Yan, Shi-Wei, Wang, Xin, Ye, Zhong-Li, Luo, Qun-Li, and Wang, En-Bo. Fri . "A series of 2D metal-quinolone complexes: Syntheses, structures, and physical properties". United States. doi:10.1016/J.JSSC.2012.10.015.
@article{osti_22150029,
title = {A series of 2D metal-quinolone complexes: Syntheses, structures, and physical properties},
author = {He, Jiang-Hong and Xiao, Dong-Rong and Chen, Hai-Yan and Sun, Dian-Zhen and Yan, Shi-Wei and Wang, Xin and Ye, Zhong-Li and Luo, Qun-Li and Wang, En-Bo},
abstractNote = {Six novel 2D metal-quinolone complexes, namely [Cd(cfH)(bpdc)]{center_dot}H{sub 2}O (1), [M(norfH)(bpdc)]{center_dot}H{sub 2}O (M=Cd (2) and Mn (3)), [Mn{sub 2}(cfH)(odpa)(H{sub 2}O){sub 3}]{center_dot}0.5H{sub 2}O (4), [Co{sub 2}(norfH)(bpta)({mu}{sub 2}-H{sub 2}O)(H{sub 2}O){sub 2}]{center_dot}H{sub 2}O (5) and [Co{sub 3}(saraH){sub 2}(Hbpta){sub 2}(H{sub 2}O){sub 4}]{center_dot}9H{sub 2}O (6) (cfH=ciprofloxacin, norfH=norfloxacin, saraH=sarafloxacin, bpdc=4,4 Prime -biphenyldicarboxylate, odpa=4,4 Prime -oxydiphthalate, bpta=3,3 Prime ,4,4 Prime -biphenyltetracarboxylate) have been synthesized and characterized. Compounds 1-3 consist of 2D arm-shaped layers based on the 1D {l_brace}M(COO){r_brace}{sub n}{sup n+} chains. Compounds 4 and 5 display 2D structures based on tetranuclear manganese or cobalt clusters with (3,6)-connected kgd topology. Compound 6 exhibits a 2D bilayer structure, which represents the first example of metal-quinolone complexes with 2D bilayer structure. By inspection of the structures of 1-6, it is believed that the long aromatic polycarboxylate ligands are important for the formation of 2D metal-quinolone complexes. The magnetic properties of compounds 3-6 was studied, indicating the existence of antiferromagnetic interactions. Furthermore, the luminescent properties of compounds 1-2 are discussed. - Graphical abstract: Six novel 2D metal-quinolone complexes have been prepared by self-assemblies of the quinolones and metal salts in the presence of long aromatic polycarboxylates. Highlights: Black-Right-Pointing-Pointer Compounds 1-3 consist of novel 2D arm-shaped layers based on the 1D {l_brace}M(COO){r_brace}{sub n}{sup n+} chains. Black-Right-Pointing-Pointer Compounds 4 and 5 are two novel 2D layers based on tetranuclear Mn or Co clusters with kgd topology. Black-Right-Pointing-Pointer Compound 6 is the first example of metal-quinolone complexes with 2D bilayer structure. Black-Right-Pointing-Pointer Compounds 1-6 represent six unusual examples of 2D metal-quinolone complexes.},
doi = {10.1016/J.JSSC.2012.10.015},
journal = {Journal of Solid State Chemistry},
issn = {0022-4596},
number = ,
volume = 198,
place = {United States},
year = {2013},
month = {2}
}