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Title: Novel 3D bismuth-based coordination polymers: Synthesis, structure, and second harmonic generation properties

Abstract

Two new 3D bismuth containing coordination polymers are reported along with their single crystal structures and SHG properties. Compound 1: Bi{sub 2}O{sub 2}(pydc) (pydc=pyridine-2, 5-dicarboxylate), crystallizes in the monoclinic, polar space group, P2{sub 1} (a=9.6479(9) A, b=4.2349(4) A, c=11.9615(11) A, {beta}=109.587(1) Degree-Sign ), which contains Bi{sub 2}O{sub 2} chains that are connected into a 3D structure via the pydc ligands. Compound 2: Bi{sub 4}Na{sub 4}(1R3S-cam){sub 8}(EtOH){sub 3.1}(H{sub 2}O){sub 3.4} (1R3S cam=1R3S-camphoric acid) crystallizes in the monoclinic, polar space group, P2{sub 1} (a=19.0855(7) A, b=13.7706(5) A, c=19.2429(7) A, {beta}=90.701(1) Degree-Sign ) and is a true 3D coordination polymer. These are two example of SHG compounds prepared using unsymmetric ligands (compound 1) or chiral ligands (compound 2), together with metals that often exhibit stereochemically-active lone pairs, such as Bi{sup 3+}, a synthetic approach that resulted in polar, non-centrosymmetric, 3D metal-organic coordination polymer. - Graphical Abstract: Structures of two new, polar, 3D Bismuth(III)-based coordination polymers: Bi{sub 2}O{sub 2}(pydc) (compound 1), and Bi{sub 4}Na{sub 4}(1R3S-cam){sub 8}(EtOH){sub 3.1}(H{sub 2}O){sub 3.4} (compound 2). Highlights: Black-Right-Pointing-Pointer New, polar, 3D Bismuth(III)-based coordination polymers. Black-Right-Pointing-Pointer First polar bismuth-based coordination polymers synthesized via a 'hybrid' strategy. Black-Right-Pointing-Pointer Combination of stereochemically-active lone pairs and unsymmetrical or chiral ligands. Black-Right-Pointing-Pointer Synthesis ofmore » class C-SHG materials based on Kurtz-Perry categories.« less

Authors:
;  [1]; ;  [2];  [1]
  1. Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, SC 29208 (United States)
  2. Department of Chemistry, University of Houston, 136 Fleming Building, Houston, TX 77204-5003 (United States)
Publication Date:
OSTI Identifier:
22149890
Resource Type:
Journal Article
Journal Name:
Journal of Solid State Chemistry
Additional Journal Information:
Journal Volume: 195; Other Information: Copyright (c) 2012 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0022-4596
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; BISMUTH; BISMUTH IONS; CHEMICAL PREPARATION; HARMONIC GENERATION; LIGANDS; MONOCLINIC LATTICES; MONOCRYSTALS; ORGANOMETALLIC COMPOUNDS; POLYMERS; SPACE GROUPS

Citation Formats

Wibowo, Arief C., Smith, Mark D., Yeon, Jeongho, Halasyamani, P. Shiv, and Loye, Hans-Conrad zur, E-mail: zurloye@mail.chem.sc.edu. Novel 3D bismuth-based coordination polymers: Synthesis, structure, and second harmonic generation properties. United States: N. p., 2012. Web. doi:10.1016/J.JSSC.2012.01.038.
Wibowo, Arief C., Smith, Mark D., Yeon, Jeongho, Halasyamani, P. Shiv, & Loye, Hans-Conrad zur, E-mail: zurloye@mail.chem.sc.edu. Novel 3D bismuth-based coordination polymers: Synthesis, structure, and second harmonic generation properties. United States. doi:10.1016/J.JSSC.2012.01.038.
Wibowo, Arief C., Smith, Mark D., Yeon, Jeongho, Halasyamani, P. Shiv, and Loye, Hans-Conrad zur, E-mail: zurloye@mail.chem.sc.edu. Thu . "Novel 3D bismuth-based coordination polymers: Synthesis, structure, and second harmonic generation properties". United States. doi:10.1016/J.JSSC.2012.01.038.
@article{osti_22149890,
title = {Novel 3D bismuth-based coordination polymers: Synthesis, structure, and second harmonic generation properties},
author = {Wibowo, Arief C. and Smith, Mark D. and Yeon, Jeongho and Halasyamani, P. Shiv and Loye, Hans-Conrad zur, E-mail: zurloye@mail.chem.sc.edu},
abstractNote = {Two new 3D bismuth containing coordination polymers are reported along with their single crystal structures and SHG properties. Compound 1: Bi{sub 2}O{sub 2}(pydc) (pydc=pyridine-2, 5-dicarboxylate), crystallizes in the monoclinic, polar space group, P2{sub 1} (a=9.6479(9) A, b=4.2349(4) A, c=11.9615(11) A, {beta}=109.587(1) Degree-Sign ), which contains Bi{sub 2}O{sub 2} chains that are connected into a 3D structure via the pydc ligands. Compound 2: Bi{sub 4}Na{sub 4}(1R3S-cam){sub 8}(EtOH){sub 3.1}(H{sub 2}O){sub 3.4} (1R3S cam=1R3S-camphoric acid) crystallizes in the monoclinic, polar space group, P2{sub 1} (a=19.0855(7) A, b=13.7706(5) A, c=19.2429(7) A, {beta}=90.701(1) Degree-Sign ) and is a true 3D coordination polymer. These are two example of SHG compounds prepared using unsymmetric ligands (compound 1) or chiral ligands (compound 2), together with metals that often exhibit stereochemically-active lone pairs, such as Bi{sup 3+}, a synthetic approach that resulted in polar, non-centrosymmetric, 3D metal-organic coordination polymer. - Graphical Abstract: Structures of two new, polar, 3D Bismuth(III)-based coordination polymers: Bi{sub 2}O{sub 2}(pydc) (compound 1), and Bi{sub 4}Na{sub 4}(1R3S-cam){sub 8}(EtOH){sub 3.1}(H{sub 2}O){sub 3.4} (compound 2). Highlights: Black-Right-Pointing-Pointer New, polar, 3D Bismuth(III)-based coordination polymers. Black-Right-Pointing-Pointer First polar bismuth-based coordination polymers synthesized via a 'hybrid' strategy. Black-Right-Pointing-Pointer Combination of stereochemically-active lone pairs and unsymmetrical or chiral ligands. Black-Right-Pointing-Pointer Synthesis of class C-SHG materials based on Kurtz-Perry categories.},
doi = {10.1016/J.JSSC.2012.01.038},
journal = {Journal of Solid State Chemistry},
issn = {0022-4596},
number = ,
volume = 195,
place = {United States},
year = {2012},
month = {11}
}