Gaseous fission product management for molten salt reactors and vented fuel systems
- Massachusetts Inst. of Technology, 77 Massachusetts Ave., 54-1717, Cambridge, MA 02139 (United States)
- Massachusetts Inst. of Technology, 77 Massachusetts Ave., 24-207, Cambridge, MA 02139 (United States)
- Massachusetts Inst. of Technology, 77 Massachusetts Ave., NW12-230, Cambridge, MA 02139 (United States)
Fission gas disposal is one of the unresolved difficulties for Molten Salt Reactors (MSRs) and advanced reactors with vented fuel systems. As these systems operate, they produce many radioactive isotopes of xenon and krypton (e.g. {sup 135}Xe t{sub 1/2} = 9.14 hours and {sup 85}Kr t{sub 1/2}= 10.73 years). Removing these gases proves vital to the success of such reactor designs for two reasons. First, the gases act as large neutron sinks which decrease reactivity and must be counterbalanced by increasing fuel loading. Second, for MSRs, inert fission product gases naturally separate quickly from high temperature salts, thus creating high vapor pressure which poses safety concerns. For advanced reactors with solid vented fuel, the gases are allowed to escape into an off-gas system and thus must be managed. Because of time delays in transport of fission product gases in vented fuel systems, some of the shorter-lived radionuclides will decay away thereby reducing the fission gas source term relative to an MSR. To calculate the fission gas source term of a typical molten salt reactor, we modeled a 1000 MWe graphite moderated thorium MSR similar to that detailed in Mathieu et al. [1]. The fuel salt used in these calculations was LiF (78 mole percent) - (HN)F 4 (22 mole percent) with a heavy nuclide composition of 3.86% {sup 233}U and 96.14% {sup 232}Th by mass. Before we can remove the fission product gases produced by this reactor configuration, we must first develop an appropriate storage mechanism. The gases could be stored in pressurized containers but then one must be concerned about bottle failure. Methods to trap noble gases in matrices are expensive and complex. Alternatively, there are direct storage/disposal options: direct injection into the Earth or injecting a grout-based product into the Earth. Advances in drilling technologies, hydro fracture technologies, and methods for the sequestration of carbon dioxide from fossil fuel plants are creating new options for disposal of fission gas wastes. In each option, lithostatic pressure, a kilometer or more underground, eliminates the pressure driving force for noble gas release and dissolves any untrapped gas in deep groundwater or into incorporated solid waste forms. The options, challenges, and potential for these methods to dispose of gaseous fission products are described. With this research, we hope to help both MSRs and other advanced reactors come one step closer to commercialization. (authors)
- Research Organization:
- American Nuclear Society, 555 North Kensington Avenue, La Grange Park, IL 60526 (United States)
- OSTI ID:
- 22107870
- Resource Relation:
- Conference: ICAPP '12: 2012 International Congress on Advances in Nuclear Power Plants, Chicago, IL (United States), 24-28 Jun 2012; Other Information: Country of input: France; 6 refs.; Related Information: In: Proceedings of the 2012 International Congress on Advances in Nuclear Power Plants - ICAPP '12| 2799 p.
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS
CARBON DIOXIDE
FISSION PRODUCTS
FOSSIL FUELS
FRACTURES
FUEL SYSTEMS
GRAPHITE
GROUND WATER
KRYPTON
KRYPTON 85
LITHIUM FLUORIDES
MOLTEN SALT REACTORS
RADIOACTIVE WASTE DISPOSAL
REACTOR FUELING
SOLID WASTES
TEMPERATURE RANGE 0400-1000 K
THORIUM 232
URANIUM 233
XENON
XENON 135