Designing better electrolytes

Meng, Y. Shirley; Srinivasan, Venkat; Xu, Kang

doi:10.1126/science.abq3750

Designing better electrolytes

Journal Article · 09 December 2022 · Science

DOI:https://doi.org/10.1126/science.abq3750· OSTI ID:2205190

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Pritzker School of Molecular Engineering, The University of Chicago, Chicago, IL 60637, USA.;Argonne Collaborative Center for Energy Storage Science (ACCESS), Argonne National Laboratory, Lemont, IL 60439, USA.
Argonne Collaborative Center for Energy Storage Science (ACCESS), Argonne National Laboratory, Lemont, IL 60439, USA.;Joint Center for Energy Storage Research (JCESR), Argonne National Laboratory, Lemont, IL 60439, USA.
Joint Center for Energy Storage Research (JCESR), Argonne National Laboratory, Lemont, IL 60439, USA.;Battery Science Branch, Energy Science Division, US Army Combat Capabilities Development Command (CCDC) Research Laboratory, Adelphi Laboratory Center, MD 20783, USA.

Electrolytes and the associated interphases constitute the critical components to support the emerging battery chemistries that promise tantalizing energy but involve drastic phase and structure complications. Designing better electrolytes and interphases holds the key to the success of these batteries. As the only component that interfaces with every other component in the device, an electrolyte must satisfy multiple criteria simultaneously. These include transporting ions while insulating electrons between the electrodes and maintaining stability against electrodes of extreme chemical natures: the strongly oxidative cathode and the strongly reductive anode. In most advanced batteries, the two electrodes operate at potentials far beyond the thermodynamic stability limits of electrolytes, so the stability therein has to be realized kinetically through an interphase formed from the sacrificial reactions between electrolyte and electrodes.

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 2205190

Journal Information:: Science, Vol. 378, Issue 6624; ISSN 0036-8075

Country of Publication:: United States

Language:: English

References (96)

Before Li Ion Batteries Winter, Martin; Barnett, Brian; Xu, Kang Chemical Reviews, Vol. 118, Issue 23 https://doi.org/10.1021/acs.chemrev.8b00422	journal	November 2018
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Xu, Kang Chemical Reviews, Vol. 104, Issue 10, p. 4303-4418 https://doi.org/10.1021/cr030203g	journal	October 2004
The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems—The Solid Electrolyte Interphase Model Peled, E. Journal of The Electrochemical Society, Vol. 126, Issue 12 https://doi.org/10.1149/1.2128859	journal	January 1979
New insights into the structure-property relationship of high-voltage electrolyte components for lithium-ion batteries using the pKa value Gallus, Dennis Roman; Wagner, Ralf; Wiemers-Meyer, Simon Electrochimica Acta, Vol. 184 https://doi.org/10.1016/j.electacta.2015.10.002	journal	December 2015
The Solid Electrolyte Interphase – The Most Important and the Least Understood Solid Electrolyte in Rechargeable Li Batteries Winter, Martin Zeitschrift für Physikalische Chemie, Vol. 223, Issue 10-11 https://doi.org/10.1524/zpch.2009.6086	journal	December 2009
Challenges for Rechargeable Li Batteries Goodenough, John B.; Kim, Youngsik Chemistry of Materials, Vol. 22, Issue 3, p. 587-603 https://doi.org/10.1021/cm901452z	journal	February 2010
Li-ion battery electrolytes Xu, Kang Nature Energy, Vol. 6, Issue 7 https://doi.org/10.1038/s41560-021-00841-6	journal	July 2021
Solvation Sheath of Li ⁺ in Nonaqueous Electrolytes and Its Implication of Graphite/Electrolyte Interface Chemistry Xu, Kang; Lam, Yiufai; Zhang, Sheng S. The Journal of Physical Chemistry C, Vol. 111, Issue 20 https://doi.org/10.1021/jp068691u	journal	May 2007
Identification of the Source of Evolved Gas in Li-Ion Batteries Using [sup 13]C-labeled Solvents Onuki, Masamichi; Kinoshita, Shinichi; Sakata, Yuuichi Journal of The Electrochemical Society, Vol. 155, Issue 11 https://doi.org/10.1149/1.2969947	journal	January 2008
Lithium Ethylene Dicarbonate Identified as the Primary Product of Chemical and Electrochemical Reduction of EC in 1.2 M LiPF ₆ /EC:EMC Electrolyte Zhuang, Guorong V.; Xu, Kang; Yang, Hui The Journal of Physical Chemistry B, Vol. 109, Issue 37 https://doi.org/10.1021/jp052474w	journal	September 2005
Preferential Solvation of Li+ Directs Formation of Interphase on Graphitic Anode von Cresce, Arthur; Xu, Kang Electrochemical and Solid-State Letters, Vol. 14, Issue 10 https://doi.org/10.1149/1.3615828	journal	January 2011
Understanding Li ⁺ –Solvent Interaction in Nonaqueous Carbonate Electrolytes with ¹⁷ O NMR Bogle, Xavier; Vazquez, Rafael; Greenbaum, Steven The Journal of Physical Chemistry Letters, Vol. 4, Issue 10 https://doi.org/10.1021/jz400661k	journal	May 2013
In situ quantification of interphasial chemistry in Li-ion battery Liu, Tongchao; Lin, Lingpiao; Bi, Xuanxuan Nature Nanotechnology, Vol. 14, Issue 1 https://doi.org/10.1038/s41565-018-0284-y	journal	November 2018
Identifying the components of the solid–electrolyte interphase in Li-ion batteries Wang, Luning; Menakath, Anjali; Han, Fudong Nature Chemistry, Vol. 11, Issue 9 https://doi.org/10.1038/s41557-019-0304-z	journal	August 2019
A Guide to Ethylene Carbonate-Free Electrolyte Making for Li-Ion Cells Ma, Lin; Glazier, S. L.; Petibon, R. Journal of The Electrochemical Society, Vol. 164, Issue 1 https://doi.org/10.1149/2.0191701jes	journal	November 2016
Understanding the Outstanding High‐Voltage Performance of NCM523\|\|Graphite Lithium Ion Cells after Elimination of Ethylene Carbonate Solvent from Conventional Electrolyte Klein, Sven; van Wickeren, Stefan; Röser, Stephan Advanced Energy Materials, Vol. 11, Issue 14 https://doi.org/10.1002/aenm.202003738	journal	January 2021
Film Formation at Positive Electrodes in Lithium-Ion Batteries Würsig, Andreas; Buqa, Hilmi; Holzapfel, Michael Electrochemical and Solid-State Letters, Vol. 8, Issue 1 https://doi.org/10.1149/1.1836114	journal	January 2005
Conventional Electrolyte and Inactive Electrode Materials in Lithium‐Ion Batteries: Determining Cumulative Impact of Oxidative Decomposition at High Voltage Streipert, Benjamin; Stolz, Lukas; Homann, Gerrit ChemSusChem, Vol. 13, Issue 19 https://doi.org/10.1002/cssc.202001530	journal	August 2020
Aging of the LiNi[sub 1∕2]Mn[sub 1∕2]O[sub 2] Positive Electrode Interface in Electrolyte Dupré, Nicolas; Martin, Jean-Frédéric; Oliveri, Julie Journal of The Electrochemical Society, Vol. 156, Issue 5 https://doi.org/10.1149/1.3098494	journal	January 2009
Electrolyte Additive in Support of 5 V Li Ion Chemistry von Cresce, Arthur; Xu, Kang Journal of The Electrochemical Society, Vol. 158, Issue 3, p. A337-A342 https://doi.org/10.1149/1.3532047	journal	January 2011
Energy storage emerging: A perspective from the Joint Center for Energy Storage Research Trahey, Lynn; Brushett, Fikile R.; Balsara, Nitash P. Proceedings of the National Academy of Sciences, Vol. 117, Issue 23 https://doi.org/10.1073/pnas.1821672117	journal	June 2020
"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries Suo, L.; Borodin, O.; Gao, T. Science, Vol. 350, Issue 6263 https://doi.org/10.1126/science.aab1595	journal	November 2015
Advanced High-Voltage Aqueous Lithium-Ion Battery Enabled by “Water-in-Bisalt” Electrolyte Suo, Liumin; Borodin, Oleg; Sun, Wei Angewandte Chemie International Edition, Vol. 55, Issue 25 https://doi.org/10.1002/anie.201602397	journal	April 2016
Hydrate-melt electrolytes for high-energy-density aqueous batteries Yamada, Yuki; Usui, Kenji; Sodeyama, Keitaro Nature Energy, Vol. 1, Issue 10 https://doi.org/10.1038/nenergy.2016.129	journal	August 2016
Research Development on Sodium-Ion Batteries Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500192f	journal	October 2014
Research Development on K-Ion Batteries Hosaka, Tomooki; Kubota, Kei; Hameed, A. Shahul Chemical Reviews, Vol. 120, Issue 14 https://doi.org/10.1021/acs.chemrev.9b00463	journal	January 2020
Electrolyte roadblocks to a magnesium rechargeable battery Muldoon, John; Bucur, Claudiu B.; Oliver, Allen G. Energy & Environmental Science, Vol. 5, Issue 3, p. 5941-5950 https://doi.org/10.1039/c2ee03029b	journal	January 2012
Achievements, Challenges, and Prospects of Calcium Batteries Arroyo-de Dompablo, M. Elena; Ponrouch, Alexandre; Johansson, Patrik Chemical Reviews https://doi.org/10.1021/acs.chemrev.9b00339	journal	October 2019
An ultrafast rechargeable aluminium-ion battery Lin, Meng-Chang; Gong, Ming; Lu, Bingan Nature, Vol. 520, Issue 7547 https://doi.org/10.1038/nature14340	journal	April 2015
Nano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells Kasavajjula, Uday; Wang, Chunsheng; Appleby, A. John Journal of Power Sources, Vol. 163, Issue 2, p. 1003-1039 https://doi.org/10.1016/j.jpowsour.2006.09.084	journal	January 2007
High-performance lithium battery anodes using silicon nanowires Chan, Candace K.; Peng, Hailin; Liu, Gao Nature Nanotechnology, Vol. 3, Issue 1, p. 31-35 https://doi.org/10.1038/nnano.2007.411	journal	December 2007
Alloy Negative Electrodes for Li-Ion Batteries Obrovac, M. N.; Chevrier, V. L. Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500207g	journal	October 2014
Lithium metal anodes for rechargeable batteries Xu, Wu; Wang, Jiulin; Ding, Fei Energy Environ. Sci., Vol. 7, Issue 2 https://doi.org/10.1039/C3EE40795K	journal	January 2014
Quantifying inactive lithium in lithium metal batteries Fang, Chengcheng; Li, Jinxing; Zhang, Minghao Nature, Vol. 572, Issue 7770 https://doi.org/10.1038/s41586-019-1481-z	journal	August 2019
Diagnosing and correcting anode-free cell failure via electrolyte and morphological analysis Louli, A. J.; Eldesoky, A.; Weber, Rochelle Nature Energy, Vol. 5, Issue 9 https://doi.org/10.1038/s41560-020-0668-8	journal	August 2020
Current status and future directions of multivalent metal-ion batteries Liang, Yanliang; Dong, Hui; Aurbach, Doron Nature Energy, Vol. 5, Issue 9 https://doi.org/10.1038/s41560-020-0655-0	journal	July 2020
A sobering examination of the feasibility of aqueous aluminum batteries Pastel, Glenn R.; Chen, Ying; Pollard, Travis P. Energy & Environmental Science, Vol. 15, Issue 6 https://doi.org/10.1039/D2EE00134A	journal	January 2022
Solvation Structure and Dynamics of Mg(TFSI) ₂ Aqueous Electrolyte Yu, Zhou; Juran, Taylor R.; Liu, Xinyi ENERGY & ENVIRONMENTAL MATERIALS https://doi.org/10.1002/eem2.12174	journal	February 2021
An artificial interphase enables reversible magnesium chemistry in carbonate electrolytes Son, Seoung-Bum; Gao, Tao; Harvey, Steve P. Nature Chemistry, Vol. 10, Issue 5 https://doi.org/10.1038/s41557-018-0019-6	journal	April 2018
Realizing high zinc reversibility in rechargeable batteries Ma, Lin; Schroeder, Marshall A.; Borodin, Oleg Nature Energy, Vol. 5, Issue 10 https://doi.org/10.1038/s41560-020-0674-x	journal	August 2020
Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries Albertus, Paul; Babinec, Susan; Litzelman, Scott Nature Energy, Vol. 3, Issue 1 https://doi.org/10.1038/s41560-017-0047-2	journal	December 2017
A rechargeable zinc-air battery based on zinc peroxide chemistry Sun, Wei; Wang, Fei; Zhang, Bao Science, Vol. 371, Issue 6524 https://doi.org/10.1126/science.abb9554	journal	December 2020
High Performance Printed AgO-Zn Rechargeable Battery for Flexible Electronics Yin, Lu; Scharf, Jonathan; Ma, Jessica Joule, Vol. 5, Issue 1 https://doi.org/10.1016/j.joule.2020.11.008	journal	January 2021
Nanostructured high-energy cathode materials for advanced lithium batteries Sun, Yang-Kook; Chen, Zonghai; Noh, Hyung-Joo Nature Materials, Vol. 11, Issue 11 https://doi.org/10.1038/nmat3435	journal	October 2012
Recent advances in the electrolytes for interfacial stability of high-voltage cathodes in lithium-ion batteries Choi, Nam-Soon; Han, Jung-Gu; Ha, Se-Young RSC Advances, Vol. 5, Issue 4 https://doi.org/10.1039/C4RA11575A	journal	January 2015
The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials Seo, Dong-Hwa; Lee, Jinhyuk; Urban, Alexander Nature Chemistry, Vol. 8, Issue 7 https://doi.org/10.1038/nchem.2524	journal	May 2016
Conversion cathodes for rechargeable lithium and lithium-ion batteries Wu, Feixiang; Yushin, Gleb Energy & Environmental Science, Vol. 10, Issue 2 https://doi.org/10.1039/C6EE02326F	journal	January 2017
High energy-density and reversibility of iron fluoride cathode enabled via an intercalation-extrusion reaction Fan, Xiulin; Hu, Enyuan; Ji, Xiao Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04476-2	journal	June 2018
Rechargeable Lithium–Sulfur Batteries Manthiram, Arumugam; Fu, Yongzhu; Chung, Sheng-Heng Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500062v	journal	July 2014
Current Challenges and Routes Forward for Nonaqueous Lithium–Air Batteries Liu, Tao; Vivek, J. Padmanabhan; Zhao, Evan Wenbo Chemical Reviews, Vol. 120, Issue 14 https://doi.org/10.1021/acs.chemrev.9b00545	journal	February 2020
New Concepts in Electrolytes Li, Matthew; Wang, Chunsheng; Chen, Zhongwei Chemical Reviews https://doi.org/10.1021/acs.chemrev.9b00531	journal	February 2020
Uncharted Waters: Super-Concentrated Electrolytes Borodin, Oleg; Self, Julian; Persson, Kristin A. Joule, Vol. 4, Issue 1 https://doi.org/10.1016/j.joule.2019.12.007	journal	January 2020
High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes Chen, Shuru; Zheng, Jianming; Mei, Donghai Advanced Materials, Vol. 30, Issue 21 https://doi.org/10.1002/adma.201706102	journal	March 2018
Synergetic Effects of Inorganic Components in Solid Electrolyte Interphase on High Cycle Efficiency of Lithium Ion Batteries Zhang, Qinglin; Pan, Jie; Lu, Peng Nano Letters, Vol. 16, Issue 3 https://doi.org/10.1021/acs.nanolett.5b05283	journal	February 2016
Perspective—Fluorinating Interphases Wang, Chunsheng; Meng, Ying Shirley; Xu, Kang Journal of The Electrochemical Society, Vol. 166, Issue 3 https://doi.org/10.1149/2.0281903jes	journal	December 2018
New Insights on the Structure of Electrochemically Deposited Lithium Metal and Its Solid Electrolyte Interphases via Cryogenic TEM Wang, Xuefeng; Zhang, Minghao; Alvarado, Judith Nano Letters, Vol. 17, Issue 12 https://doi.org/10.1021/acs.nanolett.7b03606	journal	November 2017
Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy Li, Yuzhang; Li, Yanbin; Pei, Allen Science, Vol. 358, Issue 6362 https://doi.org/10.1126/science.aam6014	journal	October 2017
Li ₂ O Solid Electrolyte Interphase: Probing Transport Properties at the Chemical Potential of Lithium Guo, Rui; Gallant, Betar M. Chemistry of Materials, Vol. 32, Issue 13 https://doi.org/10.1021/acs.chemmater.0c00333	journal	May 2020
Suspension electrolyte with modified Li+ solvation environment for lithium metal batteries Kim, Mun Sek; Zhang, Zewen; Rudnicki, Paul E. Nature Materials, Vol. 21, Issue 4 https://doi.org/10.1038/s41563-021-01172-3	journal	January 2022
Lithium battery chemistries enabled by solid-state electrolytes Manthiram, Arumugam; Yu, Xingwen; Wang, Shaofei Nature Reviews Materials, Vol. 2, Issue 4 https://doi.org/10.1038/natrevmats.2016.103	journal	February 2017
Mobile Ions in Composite Solids Zou, Zheyi; Li, Yajie; Lu, Ziheng Chemical Reviews, Vol. 120, Issue 9 https://doi.org/10.1021/acs.chemrev.9b00760	journal	April 2020
Electrolytes and Interphases in Li-Ion Batteries and Beyond Xu, Kang Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500003w	journal	October 2014
Copper-coordinated cellulose ion conductors for solid-state batteries Yang, Chunpeng; Wu, Qisheng; Xie, Weiqi Nature, Vol. 598, Issue 7882 https://doi.org/10.1038/s41586-021-03885-6	journal	October 2021
First principles study on electrochemical and chemical stability of solid electrolyte–electrode interfaces in all-solid-state Li-ion batteries Zhu, Yizhou; He, Xingfeng; Mo, Yifei Journal of Materials Chemistry A, Vol. 4, Issue 9 https://doi.org/10.1039/C5TA08574H	journal	January 2016
Interfaces and Interphases in All-Solid-State Batteries with Inorganic Solid Electrolytes Banerjee, Abhik; Wang, Xuefeng; Fang, Chengcheng Chemical Reviews, Vol. 120, Issue 14 https://doi.org/10.1021/acs.chemrev.0c00101	journal	June 2020
Computational Screening of Cathode Coatings for Solid-State Batteries Xiao, Yihan; Miara, Lincoln J.; Wang, Yan Joule, Vol. 3, Issue 5 https://doi.org/10.1016/j.joule.2019.02.006	journal	May 2019
Toward a Fundamental Understanding of the Lithium Metal Anode in Solid-State Batteries—An Electrochemo-Mechanical Study on the Garnet-Type Solid Electrolyte Li _6.25 Al _0.25 La ₃ Zr ₂ O ₁₂ Krauskopf, Thorben; Hartmann, Hannah; Zeier, Wolfgang G. ACS Applied Materials & Interfaces, Vol. 11, Issue 15 https://doi.org/10.1021/acsami.9b02537	journal	March 2019
Pressure-tailored lithium deposition and dissolution in lithium metal batteries Fang, Chengcheng; Lu, Bingyu; Pawar, Gorakh Nature Energy, Vol. 6, Issue 10 https://doi.org/10.1038/s41560-021-00917-3	journal	October 2021
Effect of Pressure on Lithium Metal Deposition and Stripping against Sulfide-Based Solid Electrolytes Wang, Yuxing; Liu, Tongjie; Kumar, Jitendra ACS Applied Materials & Interfaces, Vol. 12, Issue 31 https://doi.org/10.1021/acsami.0c06201	journal	July 2020
Mechanical vs. chemical stability of sulphide-based solid-state batteries. Which one is the biggest challenge to tackle? Overview of solid-state batteries and hybrid solid state batteries Mangani, Léa Rose; Villevieille, Claire Journal of Materials Chemistry A, Vol. 8, Issue 20 https://doi.org/10.1039/D0TA02984J	journal	January 2020
Carbon-free high-loading silicon anodes enabled by sulfide solid electrolytes Tan, Darren H. S.; Chen, Yu-Ting; Yang, Hedi Science, Vol. 373, Issue 6562 https://doi.org/10.1126/science.abg7217	journal	September 2021
Single-ion conducting polymer electrolytes as a key jigsaw piece for next-generation battery applications Gao, Jingyi; Wang, Cong; Han, Dong-Wook Chemical Science, Vol. 12, Issue 40 https://doi.org/10.1039/D1SC04023E	journal	January 2021
Liquefied gas electrolytes for electrochemical energy storage devices Rustomji, Cyrus S.; Yang, Yangyuchen; Kim, Tae Kyoung Science, Vol. 356, Issue 6345 https://doi.org/10.1126/science.aal4263	journal	June 2017
High-Efficiency Lithium-Metal Anode Enabled by Liquefied Gas Electrolytes Yang, Yangyuchen; Davies, Daniel M.; Yin, Yijie Joule, Vol. 3, Issue 8 https://doi.org/10.1016/j.joule.2019.06.008	journal	August 2019
A Safer, Wide-Temperature Liquefied Gas Electrolyte Based on Difluoromethane Davies, Daniel M.; Yang, Yangyuchen; Sablina, Ekaterina S. Journal of Power Sources, Vol. 493 https://doi.org/10.1016/j.jpowsour.2021.229668	journal	May 2021
High-Efficiency Zinc-Metal Anode Enabled by Liquefied Gas Electrolytes Ma, Lin; Lee, Jungwoo Z.; Pollard, Travis P. ACS Energy Letters, Vol. 6, Issue 12 https://doi.org/10.1021/acsenergylett.1c02084	journal	November 2021
Anomalous Increase in Carbon Capacitance at Pore Sizes Less Than 1 Nanometer Chmiola, J. Science, Vol. 313, Issue 5794 https://doi.org/10.1126/science.1132195	journal	September 2006
Stable lithium electrodeposition in liquid and nanoporous solid electrolytes Lu, Yingying; Tu, Zhengyuan; Archer, Lynden A. Nature Materials, Vol. 13, Issue 10 https://doi.org/10.1038/nmat4041	journal	August 2014
A Liquid Electrolyte with De-Solvated Lithium Ions for Lithium-Metal Battery Chang, Zhi; Qiao, Yu; Deng, Han Joule, Vol. 4, Issue 8 https://doi.org/10.1016/j.joule.2020.06.011	journal	August 2020
Beyond the concentrated electrolyte: further depleting solvent molecules within a Li ⁺ solvation sheath to stabilize high-energy-density lithium metal batteries Chang, Zhi; Qiao, Yu; Yang, Huijun Energy & Environmental Science, Vol. 13, Issue 11 https://doi.org/10.1039/D0EE02769C	journal	January 2020
Vertically Aligned and Continuous Nanoscale Ceramic–Polymer Interfaces in Composite Solid Polymer Electrolytes for Enhanced Ionic Conductivity Zhang, Xiaokun; Xie, Jin; Shi, Feifei Nano Letters, Vol. 18, Issue 6 https://doi.org/10.1021/acs.nanolett.8b01111	journal	May 2018
Identification of LiH and nanocrystalline LiF in the solid–electrolyte interphase of lithium metal anodes Shadike, Zulipiya; Lee, Hongkyung; Borodin, Oleg Nature Nanotechnology, Vol. 16, Issue 5 https://doi.org/10.1038/s41565-020-00845-5	journal	January 2021
Solvation structure and energetics of electrolytes for multivalent energy storage Lapidus, Saul H.; Rajput, Nav Nidhi; Qu, Xiaohui Phys. Chem. Chem. Phys., Vol. 16, Issue 40 https://doi.org/10.1039/C4CP03015J	journal	January 2014
Cryo-STEM mapping of solid–liquid interfaces and dendrites in lithium-metal batteries Zachman, Michael J.; Tu, Zhengyuan; Choudhury, Snehashis Nature, Vol. 560, Issue 7718 https://doi.org/10.1038/s41586-018-0397-3	journal	August 2018
Accelerating Electrolyte Discovery for Energy Storage with High-Throughput Screening Cheng, Lei; Assary, Rajeev S.; Qu, Xiaohui The Journal of Physical Chemistry Letters, Vol. 6, Issue 2 https://doi.org/10.1021/jz502319n	journal	January 2015
Computation-Accelerated Design of Materials and Interfaces for All-Solid-State Lithium-Ion Batteries Nolan, Adelaide M.; Zhu, Yizhou; He, Xingfeng Joule, Vol. 2, Issue 10 https://doi.org/10.1016/j.joule.2018.08.017	journal	October 2018
Modeling Insight into Battery Electrolyte Electrochemical Stability and Interfacial Structure Borodin, Oleg; Ren, Xiaoming; Vatamanu, Jenel Accounts of Chemical Research, Vol. 50, Issue 12 https://doi.org/10.1021/acs.accounts.7b00486	journal	November 2017
Solvation sheath reorganization enables divalent metal batteries with fast interfacial charge transfer kinetics Hou, Singyuk; Ji, Xiao; Gaskell, Karen Science, Vol. 374, Issue 6564 https://doi.org/10.1126/science.abg3954	journal	October 2021
The Electrolyte Genome project: A big data approach in battery materials discovery Qu, Xiaohui; Jain, Anubhav; Rajput, Nav Nidhi Computational Materials Science, Vol. 103 https://doi.org/10.1016/j.commatsci.2015.02.050	journal	June 2015
Autonomous Discovery of Battery Electrolytes with Robotic Experimentation and Machine Learning Dave, Adarsh; Mitchell, Jared; Kandasamy, Kirthevasan Cell Reports Physical Science, Vol. 1, Issue 12 https://doi.org/10.1016/j.xcrp.2020.100264	journal	December 2020
Insight into SEI Growth in Li-Ion Batteries using Molecular Dynamics and Accelerated Chemical Reactions Alzate-Vargas, Lorena; Blau, Samuel M.; Spotte-Smith, Evan Walter Clark The Journal of Physical Chemistry C, Vol. 125, Issue 34 https://doi.org/10.1021/acs.jpcc.1c04149	journal	August 2021
Molecular Dynamics Simulations of Multicomponent Diffusion. 1. Equilibrium Method Wheeler, Dean R.; Newman, John The Journal of Physical Chemistry B, Vol. 108, Issue 47 https://doi.org/10.1021/jp047850b	journal	November 2004
Concentration and velocity profiles in a polymeric lithium-ion battery electrolyte Steinrück, Hans-Georg; Takacs, Christopher J.; Kim, Hong-Keun Energy & Environmental Science, Vol. 13, Issue 11 https://doi.org/10.1039/D0EE02193H	journal	January 2020
Simulation of local ion transport in lamellar block copolymer electrolytes based on electron micrographs Chintapalli, Mahati; Higa, Kenneth; Chen, X. Chelsea Journal of Polymer Science Part B: Polymer Physics, Vol. 55, Issue 3 https://doi.org/10.1002/polb.24268	journal	December 2016
An Experimental Checklist for Reporting Battery Performances Sun, Yang-Kook ACS Energy Letters, Vol. 6, Issue 6 https://doi.org/10.1021/acsenergylett.1c00870	journal	June 2021
Standardized Battery Reporting Guidelines Stephan, Alexandra K. Joule, Vol. 5, Issue 1 https://doi.org/10.1016/j.joule.2020.12.026	journal	January 2021

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