Growth and crystal structure of binary molybdate CsFe(MoO{sub 4}){sub 2}
Journal Article
·
· Crystallography Reports
- Russian Academy of Sciences, Baikal Institute of Nature Management, Siberian Branch (Russian Federation)
- Russian Academy of Sciences, Institute of Inorganic Chemistry, Siberian Branch (Russian Federation)
- Russian Academy of Sciences, Institute of Chemistry and Chemical Technology, Siberian Branch (Russian Federation)
CsFe(MoO{sub 4}){sub 2} single crystals have been grown by solution-melt crystallization with a charge-to-solvent ratio of 1: 3 (with Cs{sub 2}Mo{sub 3}O{sub 10} used as a solvent). The crystal structure of this compound has been refined by X-ray diffraction (X8 APEX automatic diffractometer, MoK{sub {alpha}} radiation, 356 F(hkl), R = 0.0178). The trigonal unit cell has the following parameters: a = b = 5.6051(2) A, c = 8.0118(4) A, V = 217.985(15) A{sup 3}, Z = 1, {rho}{sub calc} = 3.875 g/cm{sup 3}, and sp. gr. P3-barm1. The structure is composed of alternating layers of FeO{sub 6} octahedra (with MoO{sub 4} tetrahedra attached by sharing vertices) and CsO{sub 12} icosahedra.
- OSTI ID:
- 22051188
- Journal Information:
- Crystallography Reports, Vol. 55, Issue 4; Other Information: Copyright (c) 2010 Pleiades Publishing, Ltd.; Country of input: International Atomic Energy Agency (IAEA); ISSN 1063-7745
- Country of Publication:
- United States
- Language:
- English
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