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Title: Crystal structure of {l_brace}NH{sub 2}C(NHC{sub 6}H{sub 5}){sub 2}{r_brace}{sub 3}[UO{sub 2}(C{sub 2}O{sub 4}){sub 2}(NCS)] . 1.25H{sub 2}O

Abstract

Synthesis and X-ray diffraction study of {l_brace}NH{sub 2}C(NHC{sub 6}H{sub 5}){sub 2}{r_brace}{sub 3}[UO{sub 2}(C{sub 2}O{sub 4}){sub 2}(NCS)] . 1.25H{sub 2}O single crystals have been performed. This compound is crystallized in the orthorhombic system, with the unit-cell parameters a = 45.2646(8) A, b = 57.7359(11) A, c = 7.9244(3) A, sp. gr. Fdd2, Z = 16, V = 20 709.6(10) A{sup 3}, and R = 0.0477. The uranium-containing structural units of the crystals are one-core groups of the [UO{sub 2}(C{sub 2}O{sub 4}){sub 2}(NCS)]{sup 3-} composition, belonging to the crystallochemical group AB{sub 2}{sup 01}M{sup 1} (A = UO{sub 2}{sup +2}, B{sup 01} = C{sub 2}O{sub 4}{sup 2-}, M{sup 1} = NCS{sup -}) of uranyl complexes. The uranium-containing complexes are connected into a three-dimensional framework owing to the electrostatic interactions with the outer-sphere cations and a system of hydrogen bonds.

Authors:
;  [1]; ;  [2]
  1. Russian Academy of Sciences, Institute of Inorganic Chemistry, Siberian Branch (Russian Federation)
  2. Samara State University (Russian Federation)
Publication Date:
OSTI Identifier:
22050951
Resource Type:
Journal Article
Journal Name:
Crystallography Reports
Additional Journal Information:
Journal Volume: 53; Journal Issue: 4; Other Information: Copyright (c) 2008 Pleiades Publishing, Ltd.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 1063-7745
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; CATIONS; INTERACTIONS; MONOCRYSTALS; ORTHORHOMBIC LATTICES; OXALATES; SYNTHESIS; URANYL COMPLEXES; X-RAY DIFFRACTION

Citation Formats

Serezhkina, L. B., E-mail: lserezh@ssu.samara.ru, Peresypkina, E V, Virovets, A V, Neklyudova, N A, and Pushkin, D V. Crystal structure of {l_brace}NH{sub 2}C(NHC{sub 6}H{sub 5}){sub 2}{r_brace}{sub 3}[UO{sub 2}(C{sub 2}O{sub 4}){sub 2}(NCS)] . 1.25H{sub 2}O. United States: N. p., 2008. Web. doi:10.1134/S1063774508040160.
Serezhkina, L. B., E-mail: lserezh@ssu.samara.ru, Peresypkina, E V, Virovets, A V, Neklyudova, N A, & Pushkin, D V. Crystal structure of {l_brace}NH{sub 2}C(NHC{sub 6}H{sub 5}){sub 2}{r_brace}{sub 3}[UO{sub 2}(C{sub 2}O{sub 4}){sub 2}(NCS)] . 1.25H{sub 2}O. United States. https://doi.org/10.1134/S1063774508040160
Serezhkina, L. B., E-mail: lserezh@ssu.samara.ru, Peresypkina, E V, Virovets, A V, Neklyudova, N A, and Pushkin, D V. 2008. "Crystal structure of {l_brace}NH{sub 2}C(NHC{sub 6}H{sub 5}){sub 2}{r_brace}{sub 3}[UO{sub 2}(C{sub 2}O{sub 4}){sub 2}(NCS)] . 1.25H{sub 2}O". United States. https://doi.org/10.1134/S1063774508040160.
@article{osti_22050951,
title = {Crystal structure of {l_brace}NH{sub 2}C(NHC{sub 6}H{sub 5}){sub 2}{r_brace}{sub 3}[UO{sub 2}(C{sub 2}O{sub 4}){sub 2}(NCS)] . 1.25H{sub 2}O},
author = {Serezhkina, L. B., E-mail: lserezh@ssu.samara.ru and Peresypkina, E V and Virovets, A V and Neklyudova, N A and Pushkin, D V},
abstractNote = {Synthesis and X-ray diffraction study of {l_brace}NH{sub 2}C(NHC{sub 6}H{sub 5}){sub 2}{r_brace}{sub 3}[UO{sub 2}(C{sub 2}O{sub 4}){sub 2}(NCS)] . 1.25H{sub 2}O single crystals have been performed. This compound is crystallized in the orthorhombic system, with the unit-cell parameters a = 45.2646(8) A, b = 57.7359(11) A, c = 7.9244(3) A, sp. gr. Fdd2, Z = 16, V = 20 709.6(10) A{sup 3}, and R = 0.0477. The uranium-containing structural units of the crystals are one-core groups of the [UO{sub 2}(C{sub 2}O{sub 4}){sub 2}(NCS)]{sup 3-} composition, belonging to the crystallochemical group AB{sub 2}{sup 01}M{sup 1} (A = UO{sub 2}{sup +2}, B{sup 01} = C{sub 2}O{sub 4}{sup 2-}, M{sup 1} = NCS{sup -}) of uranyl complexes. The uranium-containing complexes are connected into a three-dimensional framework owing to the electrostatic interactions with the outer-sphere cations and a system of hydrogen bonds.},
doi = {10.1134/S1063774508040160},
url = {https://www.osti.gov/biblio/22050951}, journal = {Crystallography Reports},
issn = {1063-7745},
number = 4,
volume = 53,
place = {United States},
year = {Tue Jul 15 00:00:00 EDT 2008},
month = {Tue Jul 15 00:00:00 EDT 2008}
}