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Title: Study of lithium borosilicotitanate glasses with LiCl

Abstract

The effect of LiCl addition on the properties of Li{sub 2}O: B{sub 2}O{sub 3}: SiO{sub 2}: TiO{sub 2} glasses has been studied. It has been observed that the ionic conductivity increases by about half an order with LiCl addition. The decrease in glass transition temperature T{sub g} and increase in the molar volume with LiCl addition have good correlation with conductivity results. The observed increase in density of glasses has been explained on the basis of heavier Cl{sup -} ion which is accommodated in the interstices in the glass network.

Authors:
;  [1]
  1. Department of Applied Physics Visvesvaraya National Institute of Technology, Nagpur, 440010 (India)
Publication Date:
OSTI Identifier:
22004121
Resource Type:
Journal Article
Journal Name:
AIP Conference Proceedings
Additional Journal Information:
Journal Volume: 1447; Journal Issue: 1; Conference: 56. DAE solid state physics symposium 2011, Kattankulathur, Tamilnadu (India), 19-23 Dec 2011; Other Information: (c) 2012 American Institute of Physics; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0094-243X
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 36 MATERIALS SCIENCE; BORON OXIDES; BOROSILICATE GLASS; CHLORINE IONS; CORRELATIONS; DENSITY; INTERSTITIALS; IONIC CONDUCTIVITY; LITHIUM CHLORIDES; LITHIUM OXIDES; SILICON OXIDES; TITANIUM OXIDES; TRANSITION TEMPERATURE

Citation Formats

Deshpande, A. V., and Paighan, N. S. Study of lithium borosilicotitanate glasses with LiCl. United States: N. p., 2012. Web. doi:10.1063/1.4710146.
Deshpande, A. V., & Paighan, N. S. Study of lithium borosilicotitanate glasses with LiCl. United States. doi:10.1063/1.4710146.
Deshpande, A. V., and Paighan, N. S. Tue . "Study of lithium borosilicotitanate glasses with LiCl". United States. doi:10.1063/1.4710146.
@article{osti_22004121,
title = {Study of lithium borosilicotitanate glasses with LiCl},
author = {Deshpande, A. V. and Paighan, N. S.},
abstractNote = {The effect of LiCl addition on the properties of Li{sub 2}O: B{sub 2}O{sub 3}: SiO{sub 2}: TiO{sub 2} glasses has been studied. It has been observed that the ionic conductivity increases by about half an order with LiCl addition. The decrease in glass transition temperature T{sub g} and increase in the molar volume with LiCl addition have good correlation with conductivity results. The observed increase in density of glasses has been explained on the basis of heavier Cl{sup -} ion which is accommodated in the interstices in the glass network.},
doi = {10.1063/1.4710146},
journal = {AIP Conference Proceedings},
issn = {0094-243X},
number = 1,
volume = 1447,
place = {United States},
year = {2012},
month = {6}
}