Hydrothermal syntheses, structures and characterizations of two luminescent cadmium(II) complexes with p-xylenediphosphonic acid and N-donor ligands
- Department of Chemistry, Fuzhou University, Fuzhou 350002 (China)
Two novel cadmium diphosphonates [Cd(cis-H{sub 4}BDPP)(2,2 Prime -bipy){sub 2}]{center_dot}(trans-H{sub 2}BDPP)]{sub n} (1) and [Cd(trans-H{sub 2}BDPP)(phen)]{sub n} (2) (H{sub 4}BDPP=p-xylenediphosphonic acid, phen=1,10-phenanthroline, 2,2 Prime -bipy=2,2 Prime -bipyridine) were hydrothermally synthesized from p-xylenediphosphonic acid and CdSO{sub 4}{center_dot}3H{sub 2}O with phen or 2,2 Prime -bipy as second ligand components and characterized by means of elemental analyses, IR, TG analysis, luminescence spectroscopy and single crystal X-ray diffraction. Compound 1 consists of a novel one-dimensional (1D) sinusoidal [Cd(cis-H{sub 4}BDPP)(2,2 Prime -bipy){sub 2}] chains and trans-H{sub 2}BDPP anions. Compound 2 possesses a three-dimensional architecture built from double zigzag -Cd-O-P-O-Cd- chains pillared by trans-p-xylylenediphosphonate ligands from four different directions. There are hexagonal channels running along the c-axis and the coordinated phen ligands suspend in the hexagonal channels. The results indicate that p-xylenediphosphonic acid can adopt varied coordination modes and conformations in the formation of the complexes and the influence of the N-donor ligands on the structure of the complexes is discussed. - Graphical abstract: Two new cadmium diphosphonates were obtained by using two different auxiliary ligands. The influence of the N-donor ligands on the structure of the complexes is discussed. Highlights: Black-Right-Pointing-Pointer The first example of cadmium(II)-p-xylenediphosphonates templated by second ligand. Black-Right-Pointing-Pointer The role of size of the auxiliary ligand on the structure of cadmium p-xylenediphosphonates. Black-Right-Pointing-Pointer The cis and trans configurations of p-xylenediphosphonates exist in the same crystal structure. Black-Right-Pointing-Pointer Three-dimensional 4-connected framework with PtS network topology.
- OSTI ID:
- 21612910
- Journal Information:
- Journal of Solid State Chemistry, Vol. 186; Other Information: DOI: 10.1016/j.jssc.2011.11.043; PII: S0022-4596(11)00649-9; Copyright (c) 2011 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
BIPYRIDINES
CADMIUM
CADMIUM SULFATES
COMPLEXES
CRYSTAL STRUCTURE
HYDROTHERMAL SYNTHESIS
LIGANDS
LUMINESCENCE
MONOCRYSTALS
PHENANTHROLINES
PHOSPHONATES
SPECTROSCOPY
THERMAL GRAVIMETRIC ANALYSIS
TOPOLOGY
X-RAY DIFFRACTION
AROMATICS
AZAARENES
AZINES
CADMIUM COMPOUNDS
CHEMICAL ANALYSIS
COHERENT SCATTERING
CRYSTALS
DIFFRACTION
ELEMENTS
EMISSION
GRAVIMETRIC ANALYSIS
HETEROCYCLIC COMPOUNDS
MATHEMATICS
METALS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
OXYGEN COMPOUNDS
PHOTON EMISSION
PYRIDINES
QUANTITATIVE CHEMICAL ANALYSIS
SCATTERING
SULFATES
SULFUR COMPOUNDS
SYNTHESIS
THERMAL ANALYSIS