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Title: New organically templated photoluminescence iodocuprates(I)

Abstract

Two types of organic cyclic aliphatic diamine molecules piperazine (pip) and 1,3-bis(4-piperidyl)propane (bpp) were used, respectively, to react with an inorganic mixture of CuI and KI in the acidic CH{sub 3}OH solutions under the solvothermal conditions, generating finally three new organically templated iodocuprates as 2-D layered [(Hpip)Cu{sub 3}I{sub 4}] 1, 1-D chained [tmpip][Cu{sub 2}I{sub 4}] 2 (tmpip=N,N,N',N'-tetramethylpiperazinium) and dinuclear [H{sub 2}bpp]{sub 2}[Cu{sub 2}I{sub 5}] I.2H{sub 2}O 3. Note that the templating agent tmpip{sup 2+} in compound 2 originated from the in situ N-alkylation reaction between the pip molecule and the methanol solvent. The photoluminescence analysis indicates that the title compounds emit the different lights: yellow for 1, blue for 2 and yellow-green for 3, respectively. - Graphical abstract: The solvothermal self-assemblies of CuI, KI and pip/bpp in acidic CH{sub 3}OH solutions created three iodocuprates 2-D layered [(Hpip)Cu{sub 3}I{sub 4}] 1, 1-D chained [tmpip][Cu{sub 2}I{sub 4}] 2 and dinuclear [H{sub 2}bpp]{sub 2}[Cu{sub 2}I{sub 5}] I.2H{sub 2}O 3. Highlights: > A new layered iodocuprate(I) with 20-membered rings was hydrothermally prepared. > A simple approach to prepare the new organic templating agent was reported. > Photoluminescence analysis indicates the emission for iodocuprate(I) is associated with the Cu...Cu interactions.

Authors:
 [1];  [2];  [3];  [2];  [2];  [3];  [2];  [3];  [2];  [3]
  1. College of Chemistry and Material Science, Shandong Agricultural University, Taian, Shandong 271018 (China)
  2. College of Chemistry, Jilin University, Changchun 130023 (China)
  3. (China)
Publication Date:
OSTI Identifier:
21580130
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 184; Journal Issue: 7; Other Information: DOI: 10.1016/j.jssc.2011.05.010; PII: S0022-4596(11)00259-3; Copyright (c) 2011 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ALKYLATION; COPPER IODIDES; HYDROTHERMAL SYNTHESIS; INTERACTIONS; METHANOL; PHOTOLUMINESCENCE; PIPERAZINES; POTASSIUM IODIDES; PROPANE; SOLUTIONS; SOLVENTS; ALCOHOLS; ALKALI METAL COMPOUNDS; ALKANES; AZINES; CHEMICAL REACTIONS; COPPER COMPOUNDS; COPPER HALIDES; DISPERSIONS; EMISSION; HALIDES; HALOGEN COMPOUNDS; HETEROCYCLIC COMPOUNDS; HOMOGENEOUS MIXTURES; HYDROCARBONS; HYDROXY COMPOUNDS; INORGANIC PHOSPHORS; IODIDES; IODINE COMPOUNDS; LUMINESCENCE; MIXTURES; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; PHOSPHORS; PHOTON EMISSION; POTASSIUM COMPOUNDS; PYRAZINES; SYNTHESIS; TRANSITION ELEMENT COMPOUNDS

Citation Formats

Hou Qin, Zhao Jinjing, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, Zhao Tianqi, Jin Juan, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, Yu Jiehui, E-mail: jiehuiyu@yahoo.com.cn, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, Xu Jiqing, E-mail: xjq@mail.jlu.edu.cn, and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023. New organically templated photoluminescence iodocuprates(I). United States: N. p., 2011. Web.
Hou Qin, Zhao Jinjing, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, Zhao Tianqi, Jin Juan, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, Yu Jiehui, E-mail: jiehuiyu@yahoo.com.cn, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, Xu Jiqing, E-mail: xjq@mail.jlu.edu.cn, & State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023. New organically templated photoluminescence iodocuprates(I). United States.
Hou Qin, Zhao Jinjing, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, Zhao Tianqi, Jin Juan, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, Yu Jiehui, E-mail: jiehuiyu@yahoo.com.cn, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, Xu Jiqing, E-mail: xjq@mail.jlu.edu.cn, and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023. Fri . "New organically templated photoluminescence iodocuprates(I)". United States. doi:.
@article{osti_21580130,
title = {New organically templated photoluminescence iodocuprates(I)},
author = {Hou Qin and Zhao Jinjing and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023 and Zhao Tianqi and Jin Juan and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023 and Yu Jiehui, E-mail: jiehuiyu@yahoo.com.cn and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023 and Xu Jiqing, E-mail: xjq@mail.jlu.edu.cn and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023},
abstractNote = {Two types of organic cyclic aliphatic diamine molecules piperazine (pip) and 1,3-bis(4-piperidyl)propane (bpp) were used, respectively, to react with an inorganic mixture of CuI and KI in the acidic CH{sub 3}OH solutions under the solvothermal conditions, generating finally three new organically templated iodocuprates as 2-D layered [(Hpip)Cu{sub 3}I{sub 4}] 1, 1-D chained [tmpip][Cu{sub 2}I{sub 4}] 2 (tmpip=N,N,N',N'-tetramethylpiperazinium) and dinuclear [H{sub 2}bpp]{sub 2}[Cu{sub 2}I{sub 5}] I.2H{sub 2}O 3. Note that the templating agent tmpip{sup 2+} in compound 2 originated from the in situ N-alkylation reaction between the pip molecule and the methanol solvent. The photoluminescence analysis indicates that the title compounds emit the different lights: yellow for 1, blue for 2 and yellow-green for 3, respectively. - Graphical abstract: The solvothermal self-assemblies of CuI, KI and pip/bpp in acidic CH{sub 3}OH solutions created three iodocuprates 2-D layered [(Hpip)Cu{sub 3}I{sub 4}] 1, 1-D chained [tmpip][Cu{sub 2}I{sub 4}] 2 and dinuclear [H{sub 2}bpp]{sub 2}[Cu{sub 2}I{sub 5}] I.2H{sub 2}O 3. Highlights: > A new layered iodocuprate(I) with 20-membered rings was hydrothermally prepared. > A simple approach to prepare the new organic templating agent was reported. > Photoluminescence analysis indicates the emission for iodocuprate(I) is associated with the Cu...Cu interactions.},
doi = {},
journal = {Journal of Solid State Chemistry},
number = 7,
volume = 184,
place = {United States},
year = {Fri Jul 15 00:00:00 EDT 2011},
month = {Fri Jul 15 00:00:00 EDT 2011}
}