## Detailed numerical modeling of chemical and thermal nonequilibrium in hypersonic flows

Interest in hypersonic flows has created a large demand for physicochemical models for air flow computations around reentry bodies. Detailed physicochemical models for air in chemical and thermal nonequilibrium are needed for a realistic prediction of hypersonic flowfields. In this paper we develop a model, based on elementary physicochemical processes, for a detailed description of chemical nonequilibrium together with the excitation of internal DOFs. This model is implemented in a 2D Navier-Stokes code in order to show the strong influence of thermal nonequilibrium on the flowfields. The algorithm presented here is based on a fully conservative discretization of the inviscidmore »