Nano/micro-scaled La(1,3,5-BTC)(H{sub 2}O){sub 6} coordination polymer: Facile morphology-controlled fabrication and color-tunable photoluminescence properties by co-doping Eu{sup 3+},Tb{sup 3+}

Journal Article · Fri Oct 15 00:00:00 EDT 2010 · Journal of Solid State Chemistry

OSTI ID:21483652

Kai, Liu; Yuhua, Zheng; Guang, Jia; Mei, Yang; Yanhua, Song; Ning, Guo ^[1]

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1. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China)

Nano/micro-sized coordination polymer La(1,3,5-BTC)(H{sub 2}O){sub 6} with controllable morphologies have been successfully prepared on a large scale via a simple solution phase method at room temperature. By rationally adjusting the synthetic parameters such as concentration, molar ratio of reactants, surfactant, and solvent, the La(1,3,5-BTC)(H{sub 2}O){sub 6} with 3D flowerlike, wheatearlike, spherical, sheaflike, taillike, bundlelike hierarchical architectures, and 1D nanorods can be selectively prepared. More interestingly, the photoluminescence color of codoped Eu{sup 3+} and Tb{sup 3+} lanthanum 1,3,5-benzenetricarboxylate phosphors can be easily tuned from red, orange, yellow, green-yellow to green by changing co-doping concentration of activator ions, making the material has potential applications in building minioptoelectronic devices, biomedicine, and color display fields. - Graphical abstract: La(1,3,5-BTC)(H{sub 2}O){sub 6} with 3D flowerlike, wheatearlike, spherical, sheaflike, taillike, bundlelike architectures, and 1D nanorods were selectively prepared; color-tunable photoluminescence from red to green was also realized by co-doping Eu{sup 3+} and Tb{sup 3+}.

• OSTI ID: 21483652
• Journal Information: Journal of Solid State Chemistry, Vol. 183, Issue 10; Other Information: DOI: 10.1016/j.jssc.2010.07.040; PII: S0022-4596(10)00322-1; Copyright (c) 2010 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; ISSN 0022-4596
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
CRYSTAL GROWTH
EUROPIUM IONS
FABRICATION
LANTHANUM COMPLEXES
MORPHOLOGY
NANOSTRUCTURES
PHOSPHORS
PHOTOLUMINESCENCE
POLYMERS
SOLUTIONS
SOLVENTS
SURFACTANTS
TEMPERATURE RANGE 0273-0400 K
TERBIUM IONS
CHARGED PARTICLES
COMPLEXES
DISPERSIONS
EMISSION
HOMOGENEOUS MIXTURES
IONS
LUMINESCENCE
MIXTURES
PHOTON EMISSION
RARE EARTH COMPLEXES
TEMPERATURE RANGE