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Title: Metal-enhanced chemiluminescence from chromium, copper, nickel, and zinc nanodeposits: Evidence for a second enhancement mechanism in metal-enhanced fluorescence

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.3492849· OSTI ID:21466938
 [1]; ;  [2]
  1. Institute of Fluorescence, University of Maryland Biotechnology Institute, 701 East Pratt Street, Baltimore, Maryland 21202 (United States)
  2. Department of Chemistry and Biochemistry, Institute of Fluorescence, University of Maryland, Baltimore County, 701 East Pratt Street, Baltimore, Maryland 21202 (United States)

Over the past decade metal-fluorophore interactions, metal-enhanced fluorescence, have attracted significant research attention, with the technology now becoming common place in life science applications. In this paper, we address the underlying mechanisms of metal-enhanced fluorescence (MEF) and experimentally show using chemiluminescence solutions that MEF is indeed underpinned by two complimentary mechanisms, consistent with the recent reports by Geddes and co-workers [Zhang et al., J. Phys. Chem. C 113, 12095 (2009)] and their enhanced fluorescence hypothesis.

OSTI ID:
21466938
Journal Information:
Applied Physics Letters, Vol. 97, Issue 13; Other Information: DOI: 10.1063/1.3492849; (c) 2010 American Institute of Physics; ISSN 0003-6951
Country of Publication:
United States
Language:
English