Electric field suppression of ultracold confined chemical reactions
- JILA, NIST and University of Colorado, Boulder, Colorado 80309-0440 (United States)
We consider ultracold collisions of polar molecules confined in a one-dimensional optical lattice. Using a quantum scattering formalism and a frame transformation method, we calculate elastic and chemical quenching rate constants for fermionic molecules. Taking {sup 40}K{sup 87}Rb molecules as a prototype, we find that the rate of quenching collisions is enhanced at zero electric field as the confinement is increased but that this rate is suppressed when the electric field is turned on. For molecules with 500 nK of collision energy, for realistic molecular densities, and for achievable experimental electric fields and trap confinements, we predict lifetimes for KRb molecules to be 1 s. We find a ratio of elastic to quenching collision rates of about 100, which may be sufficient to achieve efficient evaporative cooling of polar KRb molecules.
- OSTI ID:
- 21407873
- Journal Information:
- Physical Review. A, Vol. 81, Issue 6; Other Information: DOI: 10.1103/PhysRevA.81.060701; (c) 2010 The American Physical Society; ISSN 1050-2947
- Country of Publication:
- United States
- Language:
- English
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