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Title: The d{sup 10} metal-sulfosalicylate complexes: Herring-bone, ladder and double-stranded chain frameworks with green luminescences

Abstract

Assembly of 5-sulfosalicylic acid (H{sub 3}L) and d{sup 10} transition metal ions (Cd{sup II}, Ag{sup I}) with the neutral N-donor ligands produces five new complexes: [Cd{sub 2}(HL){sub 2}(4,4'-bipy){sub 3}]{sub n}.2nH{sub 2}O (1), {l_brace}[Cd{sub 2}(mu{sub 2}-HCO{sub 2}){sub 2}(4,4'-bipy){sub 2}(H{sub 2}O){sub 4}][Cd(HL){sub 2}(4,4'-bipy)(H{sub 2}O){sub 2}]{r_brace}{sub n} (2), {l_brace}[Cd(4,4'-bipy)(H{sub 2}O){sub 4}][HL].H{sub 2}O{r_brace}{sub n} (3), [Cd(HL)(dpp){sub 2}(H{sub 2}O)]{sub n}.4nH{sub 2}O (4), {l_brace}[Ag(4,4'-bipy)][Hhbs]{r_brace}{sub n} (5) (4,4'-bipy=4,4'-bipyridine, dpp=1,3-di(pyridin-4-yl)propane, H{sub 2}hbs=4-hydroxybenzenesulfonic acid, the decarboxylation product of H{sub 3}L). Complex 1 adopts a 5-connected 3D bilayer topology. Complex 2 has the herring-bone and ladder chain, which are extended to a 3D network via hydrogen bonding. In 3-4 complexes, 3 is a 3D supermolecular structure formed by polymeric chains and 2D network of HL{sup 2-}, while 4 gives the double-stranded chains. In 5, ladder arrays are stacked with the 2D networks of Hhbs{sup -} anions in an -ABAB- sequence. Complexes 1-4 display green luminescences in solid state at room temperature, while emission spectra of 3 and 4 show obvious blue-shifts at low temperature. - Graphical abstract: Reactions of 5-sulfosalicylic acid (H{sub 3}L) and d{sup 10} metal ions (Cd{sup II}, Ag{sup I}) produce five new complexes. Complexes 1-4 all display green luminescences at room temperature.

Authors:
 [1]; ;  [1]; ;  [1]
  1. Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002 (China)
Publication Date:
OSTI Identifier:
21372402
Resource Type:
Journal Article
Journal Name:
Journal of Solid State Chemistry
Additional Journal Information:
Journal Volume: 182; Journal Issue: 11; Other Information: DOI: 10.1016/j.jssc.2009.08.025; PII: S0022-4596(09)00412-5; Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Journal ID: ISSN 0022-4596
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ANIONS; BIPYRIDINES; CADMIUM COMPLEXES; CRYSTAL STRUCTURE; DECARBOXYLATION; EMISSION SPECTRA; FLUORESCENCE; LAYERS; LIGANDS; SALICYLIC ACID; SILVER COMPLEXES; TEMPERATURE RANGE 0273-0400 K; AZINES; CARBOXYLIC ACIDS; CHARGED PARTICLES; CHEMICAL REACTIONS; COMPLEXES; EMISSION; HETEROCYCLIC COMPOUNDS; HYDROXY ACIDS; IONS; LUMINESCENCE; ORGANIC ACIDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; PHOTON EMISSION; PYRIDINES; SPECTRA; TEMPERATURE RANGE; TRANSITION ELEMENT COMPLEXES

Citation Formats

Chunfeng, Yan, Graduate School of Chinese Academy of Science, Beijing, Feilong, Jiang, Lian, Chen, Rui, Feng, Ming, Yang, Graduate School of Chinese Academy of Science, Beijing, and Hong Maochun, E-mail: hmc@fjirsm.ac.c. The d{sup 10} metal-sulfosalicylate complexes: Herring-bone, ladder and double-stranded chain frameworks with green luminescences. United States: N. p., 2009. Web.
Chunfeng, Yan, Graduate School of Chinese Academy of Science, Beijing, Feilong, Jiang, Lian, Chen, Rui, Feng, Ming, Yang, Graduate School of Chinese Academy of Science, Beijing, & Hong Maochun, E-mail: hmc@fjirsm.ac.c. The d{sup 10} metal-sulfosalicylate complexes: Herring-bone, ladder and double-stranded chain frameworks with green luminescences. United States.
Chunfeng, Yan, Graduate School of Chinese Academy of Science, Beijing, Feilong, Jiang, Lian, Chen, Rui, Feng, Ming, Yang, Graduate School of Chinese Academy of Science, Beijing, and Hong Maochun, E-mail: hmc@fjirsm.ac.c. Sun . "The d{sup 10} metal-sulfosalicylate complexes: Herring-bone, ladder and double-stranded chain frameworks with green luminescences". United States.
@article{osti_21372402,
title = {The d{sup 10} metal-sulfosalicylate complexes: Herring-bone, ladder and double-stranded chain frameworks with green luminescences},
author = {Chunfeng, Yan and Graduate School of Chinese Academy of Science, Beijing and Feilong, Jiang and Lian, Chen and Rui, Feng and Ming, Yang and Graduate School of Chinese Academy of Science, Beijing and Hong Maochun, E-mail: hmc@fjirsm.ac.c},
abstractNote = {Assembly of 5-sulfosalicylic acid (H{sub 3}L) and d{sup 10} transition metal ions (Cd{sup II}, Ag{sup I}) with the neutral N-donor ligands produces five new complexes: [Cd{sub 2}(HL){sub 2}(4,4'-bipy){sub 3}]{sub n}.2nH{sub 2}O (1), {l_brace}[Cd{sub 2}(mu{sub 2}-HCO{sub 2}){sub 2}(4,4'-bipy){sub 2}(H{sub 2}O){sub 4}][Cd(HL){sub 2}(4,4'-bipy)(H{sub 2}O){sub 2}]{r_brace}{sub n} (2), {l_brace}[Cd(4,4'-bipy)(H{sub 2}O){sub 4}][HL].H{sub 2}O{r_brace}{sub n} (3), [Cd(HL)(dpp){sub 2}(H{sub 2}O)]{sub n}.4nH{sub 2}O (4), {l_brace}[Ag(4,4'-bipy)][Hhbs]{r_brace}{sub n} (5) (4,4'-bipy=4,4'-bipyridine, dpp=1,3-di(pyridin-4-yl)propane, H{sub 2}hbs=4-hydroxybenzenesulfonic acid, the decarboxylation product of H{sub 3}L). Complex 1 adopts a 5-connected 3D bilayer topology. Complex 2 has the herring-bone and ladder chain, which are extended to a 3D network via hydrogen bonding. In 3-4 complexes, 3 is a 3D supermolecular structure formed by polymeric chains and 2D network of HL{sup 2-}, while 4 gives the double-stranded chains. In 5, ladder arrays are stacked with the 2D networks of Hhbs{sup -} anions in an -ABAB- sequence. Complexes 1-4 display green luminescences in solid state at room temperature, while emission spectra of 3 and 4 show obvious blue-shifts at low temperature. - Graphical abstract: Reactions of 5-sulfosalicylic acid (H{sub 3}L) and d{sup 10} metal ions (Cd{sup II}, Ag{sup I}) produce five new complexes. Complexes 1-4 all display green luminescences at room temperature.},
doi = {},
url = {https://www.osti.gov/biblio/21372402}, journal = {Journal of Solid State Chemistry},
issn = {0022-4596},
number = 11,
volume = 182,
place = {United States},
year = {2009},
month = {11}
}