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Title: Hydrothermal synthesis, crystal structure, and magnetic properties of a novel organo-templated iron(III) borophosphate: (C{sub 3}H{sub 12}N{sub 2})Fe{sup III} {sub 6}(H{sub 2}O){sub 4}[B{sub 4}P{sub 8}O{sub 32}(OH){sub 8}]

Abstract

The organo-templated iron(III) borophosphate (C{sub 3}H{sub 12}N{sub 2})Fe{sup III} {sub 6}(H{sub 2}O){sub 4}[B{sub 4}P{sub 8}O{sub 32}(OH){sub 8}] was prepared under mild hydrothermal conditions (at 443 K) and the crystal structure was determined from single crystal X-ray data at 295 K (monoclinic, P2{sub 1}/c (No. 14), a=5.014(2) A, b=9.309(2) A, c=20.923(7) A, beta=110.29(2){sup o}, V=915.9(5) A{sup 3}, Z=2, R1=0.049, wR2=0.107 for all data, 2234 observed reflections with I>2sigma(I)). The title compound contains a complex inorganic framework of borophosphate trimers [BP{sub 2}O{sub 8}(OH){sub 2}]{sup 5-} together with FeO{sub 4}(OH)(H{sub 2}O)- and FeO{sub 4}(OH){sub 2}-octahedra forming channels with ten-membered ring apertures in which the diaminopropane cations are located. The magnetization measurements confirm the Fe(III)-state and show an antiferromagnetic ordering at T{sub N}{approx}14.0(1) K. - Graphical abstract: The complex inorganic open-framework of (C{sub 3}H{sub 12}N{sub 2})Fe{sup III} {sub 6}(H{sub 2}O){sub 4}[B{sub 4}P{sub 8}O{sub 32}(OH){sub 8}] consists of borophosphate trimers and iron(III) coordination octahedra arranged to form channels with ten-membered ring apertures in which the organic 1,3-diaminopropane cations are located.

Authors:
 [1];  [2]; ; ;  [1];  [1]
  1. Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Strasse 40, 01187 Dresden (Germany)
  2. (China)
Publication Date:
OSTI Identifier:
21370357
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 182; Journal Issue: 4; Other Information: DOI: 10.1016/j.jssc.2009.01.012; PII: S0022-4596(09)00020-6; Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; ANTIFERROMAGNETISM; BORON PHOSPHATES; HYDROTHERMAL SYNTHESIS; IRON COMPOUNDS; MAGNETIC PROPERTIES; MAGNETIZATION; MONOCLINIC LATTICES; TEMPERATURE RANGE 0273-0400 K; BORON COMPOUNDS; CRYSTAL LATTICES; CRYSTAL STRUCTURE; MAGNETISM; OXYGEN COMPOUNDS; PHOSPHATES; PHOSPHORUS COMPOUNDS; PHYSICAL PROPERTIES; SYNTHESIS; TEMPERATURE RANGE; TRANSITION ELEMENT COMPOUNDS

Citation Formats

Huang Yaxi, Department of Materials Science and Engineering, College of Materials, Xiamen University, 361005 Xiamen, Schnelle, Walter, Zhang Hui, Borrmann, Horst, and Kniep, Ruediger, E-mail: kniep@cpfs.mpg.d. Hydrothermal synthesis, crystal structure, and magnetic properties of a novel organo-templated iron(III) borophosphate: (C{sub 3}H{sub 12}N{sub 2})Fe{sup III} {sub 6}(H{sub 2}O){sub 4}[B{sub 4}P{sub 8}O{sub 32}(OH){sub 8}]. United States: N. p., 2009. Web. doi:10.1016/j.jssc.2009.01.012.
Huang Yaxi, Department of Materials Science and Engineering, College of Materials, Xiamen University, 361005 Xiamen, Schnelle, Walter, Zhang Hui, Borrmann, Horst, & Kniep, Ruediger, E-mail: kniep@cpfs.mpg.d. Hydrothermal synthesis, crystal structure, and magnetic properties of a novel organo-templated iron(III) borophosphate: (C{sub 3}H{sub 12}N{sub 2})Fe{sup III} {sub 6}(H{sub 2}O){sub 4}[B{sub 4}P{sub 8}O{sub 32}(OH){sub 8}]. United States. doi:10.1016/j.jssc.2009.01.012.
Huang Yaxi, Department of Materials Science and Engineering, College of Materials, Xiamen University, 361005 Xiamen, Schnelle, Walter, Zhang Hui, Borrmann, Horst, and Kniep, Ruediger, E-mail: kniep@cpfs.mpg.d. Wed . "Hydrothermal synthesis, crystal structure, and magnetic properties of a novel organo-templated iron(III) borophosphate: (C{sub 3}H{sub 12}N{sub 2})Fe{sup III} {sub 6}(H{sub 2}O){sub 4}[B{sub 4}P{sub 8}O{sub 32}(OH){sub 8}]". United States. doi:10.1016/j.jssc.2009.01.012.
@article{osti_21370357,
title = {Hydrothermal synthesis, crystal structure, and magnetic properties of a novel organo-templated iron(III) borophosphate: (C{sub 3}H{sub 12}N{sub 2})Fe{sup III} {sub 6}(H{sub 2}O){sub 4}[B{sub 4}P{sub 8}O{sub 32}(OH){sub 8}]},
author = {Huang Yaxi and Department of Materials Science and Engineering, College of Materials, Xiamen University, 361005 Xiamen and Schnelle, Walter and Zhang Hui and Borrmann, Horst and Kniep, Ruediger, E-mail: kniep@cpfs.mpg.d},
abstractNote = {The organo-templated iron(III) borophosphate (C{sub 3}H{sub 12}N{sub 2})Fe{sup III} {sub 6}(H{sub 2}O){sub 4}[B{sub 4}P{sub 8}O{sub 32}(OH){sub 8}] was prepared under mild hydrothermal conditions (at 443 K) and the crystal structure was determined from single crystal X-ray data at 295 K (monoclinic, P2{sub 1}/c (No. 14), a=5.014(2) A, b=9.309(2) A, c=20.923(7) A, beta=110.29(2){sup o}, V=915.9(5) A{sup 3}, Z=2, R1=0.049, wR2=0.107 for all data, 2234 observed reflections with I>2sigma(I)). The title compound contains a complex inorganic framework of borophosphate trimers [BP{sub 2}O{sub 8}(OH){sub 2}]{sup 5-} together with FeO{sub 4}(OH)(H{sub 2}O)- and FeO{sub 4}(OH){sub 2}-octahedra forming channels with ten-membered ring apertures in which the diaminopropane cations are located. The magnetization measurements confirm the Fe(III)-state and show an antiferromagnetic ordering at T{sub N}{approx}14.0(1) K. - Graphical abstract: The complex inorganic open-framework of (C{sub 3}H{sub 12}N{sub 2})Fe{sup III} {sub 6}(H{sub 2}O){sub 4}[B{sub 4}P{sub 8}O{sub 32}(OH){sub 8}] consists of borophosphate trimers and iron(III) coordination octahedra arranged to form channels with ten-membered ring apertures in which the organic 1,3-diaminopropane cations are located.},
doi = {10.1016/j.jssc.2009.01.012},
journal = {Journal of Solid State Chemistry},
number = 4,
volume = 182,
place = {United States},
year = {Wed Apr 15 00:00:00 EDT 2009},
month = {Wed Apr 15 00:00:00 EDT 2009}
}