Hydrothermal synthesis, characterization and fluorescence property of a novel layered fluorinated gallium phosphite with heptameric building unit
- College of Chemistry, Jilin University, Changchun 130012 (China)
A new fluorinated gallium phosphite, Ga{sub 3}F{sub 2}(2,2'-bipy){sub 2}(HPO{sub 3}){sub 2}(H{sub 1.5}PO{sub 3}){sub 2}1, which is the first layered gallium phosphite with neutral framework, has been hydrothermally synthesized in the presence of 2,2'-bipyridine (2,2'-bipy) acting as a ligand. The as-synthesized product was characterized by single-crystal X-ray diffraction, powder X-ray diffraction, IR spectroscopy, thermogravimetric analysis (TGA), ICP-AES and elemental analyses and fluorescent spectrum. Single-crystal X-ray diffraction analysis reveals that compound 1 crystallizes in the monoclinic space group C2/c (No. 15) with cell parameters a=17.633(3) A, b=9.883(2) A, c=16.793(3) A, {beta}=109.88(3){sup o}, V=2752.1(9) A{sup 3} and Z=4. The construction of two-dimensional (2D)-layered structure in compound 1 may be viewed as the assembly of heptameric building unit, which is the first to be found in gallium phosphate/phosphite. The heptameric building unit exists in two types of configuration, which alternately connect through oxygen atoms from HPO{sub 3} pseudo-pyramids to form a layer with 10-membered ring windows viewed along the a-axis. The adjacent layers are stably packed together and exhibit interesting three-dimensional (3D) supramolecular array via {pi}-{pi} interactions of the 2,2'-bipy groups. Additionally, compound 1 shows strong fluorescent property in solid state at room temperature. - Graphical abstract: The first two-dimensional layer gallium phosphite Ga{sub 3}F{sub 2}(2,2'-bipy){sub 2}(HPO{sub 3}){sub 2}(H{sub 1.5}PO{sub 3}){sub 2} with 10-membered ring windows along the a-axis, which is built from the novel heptameric building unit.
- OSTI ID:
- 21128308
- Journal Information:
- Journal of Solid State Chemistry, Vol. 181, Issue 6; Other Information: DOI: 10.1016/j.jssc.2008.01.040; PII: S0022-4596(08)00072-8; Copyright (c) 2008 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA); ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
AUGER ELECTRON SPECTROSCOPY
BIPYRIDINES
FLUORESCENCE
GALLIUM PHOSPHATES
HYDROTHERMAL SYNTHESIS
INFRARED SPECTRA
LAYERS
MONOCLINIC LATTICES
MONOCRYSTALS
PHOSPHOROUS ACID
SPACE GROUPS
TEMPERATURE RANGE 0273-0400 K
THERMAL GRAVIMETRIC ANALYSIS
X-RAY DIFFRACTION