Investigation of the structure of C{sub 60} fullerene halides by the neutron and synchrotron diffraction methods

Journal Article · Sun Oct 15 00:00:00 EDT 2006 · Crystallography Reports

DOI:https://doi.org/10.1134/S1063774506050051· OSTI ID:21091446

Troyanov, S. I. ^[1]

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1. Moscow State University, Department of Chemistry (Russian Federation), E-mail: [e-mail]

The crystal and molecular structures of bromofullerenes and chlorofullerenes, namely, C{sub 60}Br{sub 6} . 0.5PhCl . 0.5Br{sub 2}, C{sub 60}Br{sub 8} . TiBr{sub 4} . Br{sub 2}, C{sub 60}Br{sub 24} . Br{sub 2}, and C{sub 60}Cl{sub 24} . TiCl{sub 4}, are determined and refined using neutron and synchrotron diffraction. The interatomic distances are determined with an accuracy higher than the accuracy in the determination of the corresponding parameters for the same molecular structures with the use of X-ray laboratory equipment.

• OSTI ID: 21091446
• Journal Information: Crystallography Reports, Vol. 51, Issue 5; Other Information: DOI: 10.1134/S1063774506050051; Copyright (c) 2006 Nauka/Interperiodica; Article Copyright (c) 2006 Pleiades Publishing, Inc; Country of input: International Atomic Energy Agency (IAEA); ISSN 1063-7745
• Country of Publication: United States
• Language: English

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
CRYSTAL STRUCTURE
DIFFRACTION METHODS
FULLERENES
INTERATOMIC DISTANCES
LABORATORY EQUIPMENT
MOLECULAR STRUCTURE
NEUTRON DIFFRACTION
SYNCHROTRON RADIATION
TITANIUM BROMIDES
TITANIUM CHLORIDES
X RADIATION