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Title: Crystal structure of a new basic nitrate of neodymium(III), [Nd{sub 6}O(OH){sub 8}(H{sub 2}O){sub 14}(NO{sub 3}){sub 6}](NO{sub 3}){sub 2} . 2H{sub 2}O

Abstract

A new basic Nd{sup 3+} nitrate, [Nd{sub 6}O(OH){sub 8}(H{sub 2}O){sub 14}(NO{sub 3}){sub 6}](NO{sub 3}){sub 2} . 2H{sub 2}O (I), is isolated in the crystal form and studied. Compound I differs from the basic Ln nitrates containing [Ln{sub 6}O(OH){sub 8}] clusters in that it involves a larger number of water molecules. The incorporation of additional water molecules is accompanied by changes in the coordination environment of one of the three crystallographically independent Nd{sup 3+} cations. Two cations have coordination polyhedra in the form of a monocapped tetragonal antiprism with a coordination number of 9, and the third cation has a polyhedron in the form of a bicapped tetragonal antiprism with a coordination number of 10.

Authors:
 [1];  [2]
  1. Russian Academy of Sciences, Institute of Physical Chemistry and Electrochemistry (Russian Federation), E-mail: chara@ipc.rssi.ru
  2. Commissariat a l'Energie Atomique (France)
Publication Date:
OSTI Identifier:
21090951
Resource Type:
Journal Article
Resource Relation:
Journal Name: Crystallography Reports; Journal Volume: 52; Journal Issue: 2; Other Information: DOI: 10.1134/S1063774507020101; Copyright (c) 2007 Nauka/Interperiodica; Article Copyright (c) 2007 Pleiades Publishing, Inc; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; CATIONS; COORDINATION NUMBER; CRYSTAL STRUCTURE; CRYSTALS; NEODYMIUM COMPOUNDS; NEODYMIUM IONS; NITRATES

Citation Formats

Charushnikova, I. A., and Auwer, C. Den. Crystal structure of a new basic nitrate of neodymium(III), [Nd{sub 6}O(OH){sub 8}(H{sub 2}O){sub 14}(NO{sub 3}){sub 6}](NO{sub 3}){sub 2} . 2H{sub 2}O. United States: N. p., 2007. Web. doi:10.1134/S1063774507020101.
Charushnikova, I. A., & Auwer, C. Den. Crystal structure of a new basic nitrate of neodymium(III), [Nd{sub 6}O(OH){sub 8}(H{sub 2}O){sub 14}(NO{sub 3}){sub 6}](NO{sub 3}){sub 2} . 2H{sub 2}O. United States. doi:10.1134/S1063774507020101.
Charushnikova, I. A., and Auwer, C. Den. Thu . "Crystal structure of a new basic nitrate of neodymium(III), [Nd{sub 6}O(OH){sub 8}(H{sub 2}O){sub 14}(NO{sub 3}){sub 6}](NO{sub 3}){sub 2} . 2H{sub 2}O". United States. doi:10.1134/S1063774507020101.
@article{osti_21090951,
title = {Crystal structure of a new basic nitrate of neodymium(III), [Nd{sub 6}O(OH){sub 8}(H{sub 2}O){sub 14}(NO{sub 3}){sub 6}](NO{sub 3}){sub 2} . 2H{sub 2}O},
author = {Charushnikova, I. A. and Auwer, C. Den},
abstractNote = {A new basic Nd{sup 3+} nitrate, [Nd{sub 6}O(OH){sub 8}(H{sub 2}O){sub 14}(NO{sub 3}){sub 6}](NO{sub 3}){sub 2} . 2H{sub 2}O (I), is isolated in the crystal form and studied. Compound I differs from the basic Ln nitrates containing [Ln{sub 6}O(OH){sub 8}] clusters in that it involves a larger number of water molecules. The incorporation of additional water molecules is accompanied by changes in the coordination environment of one of the three crystallographically independent Nd{sup 3+} cations. Two cations have coordination polyhedra in the form of a monocapped tetragonal antiprism with a coordination number of 9, and the third cation has a polyhedron in the form of a bicapped tetragonal antiprism with a coordination number of 10.},
doi = {10.1134/S1063774507020101},
journal = {Crystallography Reports},
number = 2,
volume = 52,
place = {United States},
year = {Thu Mar 15 00:00:00 EDT 2007},
month = {Thu Mar 15 00:00:00 EDT 2007}
}