Structural chemistry of peroxo compounds of group VI transition metals: II. Peroxo complexes of molybdenum and tungsten: A review

Journal Article · Tue Jan 15 00:00:00 EST 2008 · Crystallography Reports

DOI:https://doi.org/10.1134/S1063774508010045· OSTI ID:21090669

Sergienko, V. S. ^[1]

---

1. Russian Academy of Sciences, Kurnakov Institute of General and Inorganic Chemistry (Russian Federation), E-mail: [e-mail]

The specific features revealed in the structure of the molybdenum and tungsten peroxo complexes with the ratios M: O{sub 2} = 1: 1, 1: 2, and 1: 4 are considered. It is demonstrated that the geometry of the coordination polyhedron of the metal atom is primarily determined by the 'metal: peroxo ligand' ratio. Formally, the pentagonal bipyramidal coordination polyhedra of the Mo(VI) and W(VI) oxo monoperoxo and oxo diperoxo complexes (the coordination numbers of the metal atoms are equal to seven) have different geometries, namely, the MO(O{sub 2})A{sub 4} pseudooctahedral and MO(O{sub 2}){sub 2}A{sub 2} pseudotrigonal bipyramidal configurations.

• OSTI ID: 21090669
• Journal Information: Crystallography Reports, Vol. 53, Issue 1; Other Information: DOI: 10.1134/S1063774508010045; Copyright (c) 2008 Nauka/Interperiodica; Article Copyright (c) 2008 Pleiades Publishing, Inc; Country of input: International Atomic Energy Agency (IAEA); ISSN 1063-7745
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
LIGANDS
MOLECULAR STRUCTURE
MOLYBDENUM COMPLEXES
PEROXIDES
TUNGSTEN COMPLEXES