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Title: Two-electron centers with negative correlation energy in Pb{sub 1-x}Sn{sub x}Se solid solutions

Journal Article · · Semiconductors
; ; ;  [1]
  1. St. Petersburg State Polytechnic University (Russian Federation)

In Pb{sub 1-x-y}Sn{sub x}Na{sub y}Se solid solutions, the chemical potential F lies lower than the valence-band top E{sub v}, and the dependences F(T) are linear, with the extrapolation to T = 0 K yielding a value E{sub V} - F{sub 0} = (210 {+-} 10) meV for solid solutions containing 0.3 at % of sodium and (250 {+-} 10) meV for those with 0.5 at % of sodium (F{sub 0} is the position of the chemical potential at T = 0 K). The dependences of F{sub 0} on the content of sodium are also linear, with the extrapolation to zero content yielding a value F{sub 0} = 162 {+-} 10 meV for solid solutions containing 2 at % of tin. The correlation energy U of two-electron tin centers in PbSe is independent of the content of tin and sodium and equal to U = (-65 {+-} 10) meV.

OSTI ID:
21088640
Journal Information:
Semiconductors, Vol. 40, Issue 11; Other Information: DOI: 10.1134/S1063782606110091; Copyright (c) 2006 Nauka/Interperiodica; Article Copyright (c) 2006 Pleiades Publishing, Inc; Country of input: International Atomic Energy Agency (IAEA); ISSN 1063-7826
Country of Publication:
United States
Language:
English