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Title: Time-Resolved X-Ray Absorption Spectroscopy Data for the Study of Chemical Reaction Intermediate States

Abstract

Energy-dispersive X-ray absorption Spectroscopy is an increasingly powerful tool for the investigation of kinetic processes in chemical systems as an element-specific local structure and electronic-state probe. In this paper we present a study of the structural evolution of the inner-sphere electron transfer reaction between [IrCl6]2- and [Co(CN)5]3-. The experimental requirements necessary for the extraction of maximal structural and electronic information are discussed.

Authors:
 [1];  [2];  [3]
  1. Diamond Light Source, Chilton, Didcot, OX11 ODE (United Kingdom)
  2. ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, OX11 0QX (United Kingdom)
  3. School of Chemistry, University of Southampton, Southampton S017 1BJ (United Kingdom)
Publication Date:
OSTI Identifier:
21054760
Resource Type:
Journal Article
Resource Relation:
Journal Name: AIP Conference Proceedings; Journal Volume: 882; Journal Issue: 1; Conference: XAFS13: 13. international conference on X-ray absorption fine structure, Stanford, CA (United States), 9-14 Jul 2006; Other Information: DOI: 10.1063/1.2644682; (c) 2007 American Institute of Physics; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ABSORPTION SPECTROSCOPY; CARBON NITRIDES; CHEMICAL REACTIONS; COBALT COMPOUNDS; CYANIDES; ELECTRON TRANSFER; ELECTRONIC STRUCTURE; INTERMEDIATE STATE; IRIDIUM CHLORIDES; RADICALS; REACTION KINETICS; TIME RESOLUTION; X-RAY SPECTRA; X-RAY SPECTROSCOPY

Citation Formats

Diaz Moreno, Sofia, Bowron, Daniel T., and Evans, John. Time-Resolved X-Ray Absorption Spectroscopy Data for the Study of Chemical Reaction Intermediate States. United States: N. p., 2007. Web. doi:10.1063/1.2644682.
Diaz Moreno, Sofia, Bowron, Daniel T., & Evans, John. Time-Resolved X-Ray Absorption Spectroscopy Data for the Study of Chemical Reaction Intermediate States. United States. doi:10.1063/1.2644682.
Diaz Moreno, Sofia, Bowron, Daniel T., and Evans, John. Fri . "Time-Resolved X-Ray Absorption Spectroscopy Data for the Study of Chemical Reaction Intermediate States". United States. doi:10.1063/1.2644682.
@article{osti_21054760,
title = {Time-Resolved X-Ray Absorption Spectroscopy Data for the Study of Chemical Reaction Intermediate States},
author = {Diaz Moreno, Sofia and Bowron, Daniel T. and Evans, John},
abstractNote = {Energy-dispersive X-ray absorption Spectroscopy is an increasingly powerful tool for the investigation of kinetic processes in chemical systems as an element-specific local structure and electronic-state probe. In this paper we present a study of the structural evolution of the inner-sphere electron transfer reaction between [IrCl6]2- and [Co(CN)5]3-. The experimental requirements necessary for the extraction of maximal structural and electronic information are discussed.},
doi = {10.1063/1.2644682},
journal = {AIP Conference Proceedings},
number = 1,
volume = 882,
place = {United States},
year = {Fri Feb 02 00:00:00 EST 2007},
month = {Fri Feb 02 00:00:00 EST 2007}
}