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Title: Synthesis and luminescence properties of hybrid organic-inorganic transparent titania thin film activated by in-situ formed lanthanide complexes

Abstract

Stable transparent titania thin films were fabricated at room temperature by combining thenoyltrifluoroacetone (TTFA)-modified titanium precursors with amphiphilic triblock poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) (PEO-PPO-PEO, P123) copolymers. The obtained transparent titania thin films were systematically investigated by IR spectroscopy, PL emission and excitation spectroscopy and transmission electron microscopy. IR spectroscopy indicates that TTFA coordinates the titanium center during the process of hydrolysis and condensation. Luminescence spectroscopy confirms the in-situ formation of lanthanide complexes in the transparent titania thin film. TEM image shows that the in-situ formed lanthanide complexes were homogeneously distributed throughout the whole thin film. The quantum yield and the number of water coordinated to lanthanide metal center have been theoretically determined based on the luminescence data. - Graphical abstract: Novel stable luminescent organic-inorganic hybrid titania thin film with high transparency activated by in-situ formed lanthanide complexes have been obtained at room temperature via a simple one-pot synthesis approach by using TTFA-modified titanium precursor with amphiphilic triblock copolymer P123. The obtained hybrid thin film displays bright red (or green), near-monochromatic luminescence due to the in-situ formed lanthanide complex.

Authors:
;  [1];  [2]; ; ; ;  [1]; ;  [3]
  1. School of Chemical Engineering, Hebei University of Technology, Tianjin 300130 (China)
  2. School of Chemical Engineering, Hebei University of Technology, Tianjin 300130 (China), E-mail: lihuanrong@hebut.edu.cn
  3. Key Lab of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China)
Publication Date:
OSTI Identifier:
21043925
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 181; Journal Issue: 3; Other Information: DOI: 10.1016/j.jssc.2007.12.018; PII: S0022-4596(07)00527-0; Copyright (c) 2008 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; COPOLYMERS; INFRARED SPECTRA; LUMINESCENCE; RARE EARTH COMPLEXES; SPECTROSCOPY; TEMPERATURE RANGE 0273-0400 K; THIN FILMS; TITANIUM OXIDES; TRANSMISSION ELECTRON MICROSCOPY

Citation Formats

Wang Yige, Wang Li, Li Huanrong, Liu Peng, Qin Dashan, Liu Binyuan, Zhang Wenjun, Deng Ruiping, and Zhang Hongjie. Synthesis and luminescence properties of hybrid organic-inorganic transparent titania thin film activated by in-situ formed lanthanide complexes. United States: N. p., 2008. Web. doi:10.1016/j.jssc.2007.12.018.
Wang Yige, Wang Li, Li Huanrong, Liu Peng, Qin Dashan, Liu Binyuan, Zhang Wenjun, Deng Ruiping, & Zhang Hongjie. Synthesis and luminescence properties of hybrid organic-inorganic transparent titania thin film activated by in-situ formed lanthanide complexes. United States. doi:10.1016/j.jssc.2007.12.018.
Wang Yige, Wang Li, Li Huanrong, Liu Peng, Qin Dashan, Liu Binyuan, Zhang Wenjun, Deng Ruiping, and Zhang Hongjie. Sat . "Synthesis and luminescence properties of hybrid organic-inorganic transparent titania thin film activated by in-situ formed lanthanide complexes". United States. doi:10.1016/j.jssc.2007.12.018.
@article{osti_21043925,
title = {Synthesis and luminescence properties of hybrid organic-inorganic transparent titania thin film activated by in-situ formed lanthanide complexes},
author = {Wang Yige and Wang Li and Li Huanrong and Liu Peng and Qin Dashan and Liu Binyuan and Zhang Wenjun and Deng Ruiping and Zhang Hongjie},
abstractNote = {Stable transparent titania thin films were fabricated at room temperature by combining thenoyltrifluoroacetone (TTFA)-modified titanium precursors with amphiphilic triblock poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) (PEO-PPO-PEO, P123) copolymers. The obtained transparent titania thin films were systematically investigated by IR spectroscopy, PL emission and excitation spectroscopy and transmission electron microscopy. IR spectroscopy indicates that TTFA coordinates the titanium center during the process of hydrolysis and condensation. Luminescence spectroscopy confirms the in-situ formation of lanthanide complexes in the transparent titania thin film. TEM image shows that the in-situ formed lanthanide complexes were homogeneously distributed throughout the whole thin film. The quantum yield and the number of water coordinated to lanthanide metal center have been theoretically determined based on the luminescence data. - Graphical abstract: Novel stable luminescent organic-inorganic hybrid titania thin film with high transparency activated by in-situ formed lanthanide complexes have been obtained at room temperature via a simple one-pot synthesis approach by using TTFA-modified titanium precursor with amphiphilic triblock copolymer P123. The obtained hybrid thin film displays bright red (or green), near-monochromatic luminescence due to the in-situ formed lanthanide complex.},
doi = {10.1016/j.jssc.2007.12.018},
journal = {Journal of Solid State Chemistry},
number = 3,
volume = 181,
place = {United States},
year = {Sat Mar 15 00:00:00 EDT 2008},
month = {Sat Mar 15 00:00:00 EDT 2008}
}
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