skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Two unprecedented inorganic-organic boxlike and chainlike hybrids based on arsenic-vanadium clusters linked by nickel complexes

Abstract

Two novel organic-inorganic hybrid arsenic-vanadates, [{l_brace}Ni(en){sub 2}{r_brace}{sub 4}(4,4'-bipy){sub 4}{l_brace}Ni(H{sub 2}O){sub 2}{r_brace}]{sub 2}[As{sub 8}V{sub 14}O{sub 42}(NO{sub 3})]{sub 4}.16H{sub 2}O 1 and [Ni(en){sub 2}(H{sub 2}O){sub 2}]{sub 2}[{l_brace}Ni(en){sub 2}(H{sub 2}O){r_brace}{sub 2}As{sub 8}V{sub 14}O{sub 42}(NO{sub 3})][{l_brace}Ni(en){sub 2}{r_brace}As{sub 8}V{sub 14}O{sub 42}(NO{sub 3})] .6H{sub 2}O 2 are reported in this study. Crystal data for compound 1: Tetragonal, I4/m, a=27.507(4) A, b=27.507(4) A, c=22.101(4) A; V=16722(5) A{sup 3}, Z=2, R(final)=0.0508. Crystal data for compound 2: Triclinic, P-1, a=11.530(2) A, b=14.883(3) A, c=21.330(4) A, {alpha}=76.94(3){sup o}, {beta}=76.58(3){sup o}, {gamma}=69.54(3){sup o}, V=3293.4(1) A{sup 3}, Z=1, R(final)=0.0559. The boxlike structure of compound 1 is designed from [{l_brace}Ni(en){sub 2}{r_brace}{sub 4}(4,4'-bipy){sub 4}{l_brace}Ni(H{sub 2}O){sub 2}{r_brace}] sheets pillared by [{alpha}-As{sub 8}V{sub 14}O{sub 42}] clusters, which represents the first mixed-organic ligand-decorated tetrameric As-V-O cluster. Compound 2 is constructed from the rarely [{beta}-As{sub 8}V{sub 14}O{sub 42}] clusters and Ni coordination complex fragments. The electrochemical property and magnetic property of compound 1 have been studied. - Graphical abstract: The boxlike structure of compound 1 with cavity is designed from [{l_brace}Ni(en){sub 2}{r_brace}{sub 4}(4,4'-bipy){sub 4}{l_brace}Ni(H{sub 2}O){sub 2}{r_brace}] sheets pillared by [{alpha}-As{sub 8}V{sub 14}O{sub 42}] clusters, which represents the first mixed-organic ligand-decorated tetrameric As-V-O cluster.

Authors:
 [1];  [1];  [2];  [1];  [1];  [1];  [1]
  1. Key Laboratory of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Institute of Polyoxometalate Chemistry, Northeast Normal University, Changchun, Jinlin 130024 (China)
  2. Key Laboratory of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Institute of Polyoxometalate Chemistry, Northeast Normal University, Changchun, Jinlin 130024 (China), E-mail: wangenbo@public.cc.jl.cn
Publication Date:
OSTI Identifier:
21015661
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 180; Journal Issue: 1; Other Information: DOI: 10.1016/j.jssc.2006.10.005; PII: S0022-4596(06)00541-X; Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ARSENIC COMPOUNDS; CRYSTALS; ELECTROCHEMISTRY; HYBRIDIZATION; LIGANDS; MAGNETIC PROPERTIES; NICKEL COMPLEXES; NITRATES; TETRAGONAL LATTICES; VANADATES

Citation Formats

Qi Yanfei, Li Yangguang, Wang Enbo, Jin Hua, Zhang Zhiming, Wang Xinglong, and Chang Song. Two unprecedented inorganic-organic boxlike and chainlike hybrids based on arsenic-vanadium clusters linked by nickel complexes. United States: N. p., 2007. Web.
Qi Yanfei, Li Yangguang, Wang Enbo, Jin Hua, Zhang Zhiming, Wang Xinglong, & Chang Song. Two unprecedented inorganic-organic boxlike and chainlike hybrids based on arsenic-vanadium clusters linked by nickel complexes. United States.
Qi Yanfei, Li Yangguang, Wang Enbo, Jin Hua, Zhang Zhiming, Wang Xinglong, and Chang Song. Mon . "Two unprecedented inorganic-organic boxlike and chainlike hybrids based on arsenic-vanadium clusters linked by nickel complexes". United States. doi:.
@article{osti_21015661,
title = {Two unprecedented inorganic-organic boxlike and chainlike hybrids based on arsenic-vanadium clusters linked by nickel complexes},
author = {Qi Yanfei and Li Yangguang and Wang Enbo and Jin Hua and Zhang Zhiming and Wang Xinglong and Chang Song},
abstractNote = {Two novel organic-inorganic hybrid arsenic-vanadates, [{l_brace}Ni(en){sub 2}{r_brace}{sub 4}(4,4'-bipy){sub 4}{l_brace}Ni(H{sub 2}O){sub 2}{r_brace}]{sub 2}[As{sub 8}V{sub 14}O{sub 42}(NO{sub 3})]{sub 4}.16H{sub 2}O 1 and [Ni(en){sub 2}(H{sub 2}O){sub 2}]{sub 2}[{l_brace}Ni(en){sub 2}(H{sub 2}O){r_brace}{sub 2}As{sub 8}V{sub 14}O{sub 42}(NO{sub 3})][{l_brace}Ni(en){sub 2}{r_brace}As{sub 8}V{sub 14}O{sub 42}(NO{sub 3})] .6H{sub 2}O 2 are reported in this study. Crystal data for compound 1: Tetragonal, I4/m, a=27.507(4) A, b=27.507(4) A, c=22.101(4) A; V=16722(5) A{sup 3}, Z=2, R(final)=0.0508. Crystal data for compound 2: Triclinic, P-1, a=11.530(2) A, b=14.883(3) A, c=21.330(4) A, {alpha}=76.94(3){sup o}, {beta}=76.58(3){sup o}, {gamma}=69.54(3){sup o}, V=3293.4(1) A{sup 3}, Z=1, R(final)=0.0559. The boxlike structure of compound 1 is designed from [{l_brace}Ni(en){sub 2}{r_brace}{sub 4}(4,4'-bipy){sub 4}{l_brace}Ni(H{sub 2}O){sub 2}{r_brace}] sheets pillared by [{alpha}-As{sub 8}V{sub 14}O{sub 42}] clusters, which represents the first mixed-organic ligand-decorated tetrameric As-V-O cluster. Compound 2 is constructed from the rarely [{beta}-As{sub 8}V{sub 14}O{sub 42}] clusters and Ni coordination complex fragments. The electrochemical property and magnetic property of compound 1 have been studied. - Graphical abstract: The boxlike structure of compound 1 with cavity is designed from [{l_brace}Ni(en){sub 2}{r_brace}{sub 4}(4,4'-bipy){sub 4}{l_brace}Ni(H{sub 2}O){sub 2}{r_brace}] sheets pillared by [{alpha}-As{sub 8}V{sub 14}O{sub 42}] clusters, which represents the first mixed-organic ligand-decorated tetrameric As-V-O cluster.},
doi = {},
journal = {Journal of Solid State Chemistry},
number = 1,
volume = 180,
place = {United States},
year = {Mon Jan 15 00:00:00 EST 2007},
month = {Mon Jan 15 00:00:00 EST 2007}
}