Ternary metal nitrides by the urea route
Abstract
Interstitial molybdenum ternary nitrides, M {sub n}Mo{sub 3}N (M = Fe and Co, n = 3; M = Ni, n = 2), can be obtained by heating the molybdate precursors, FeMoO{sub 4}, CoMoO{sub 4} and NiMoO{sub 4} with urea in the 1:12 molar ratio in the 900-1000 deg. C range. Fe{sub 3}Mo{sub 3}N and Co{sub 3}Mo{sub 3}N are obtained in pure form. The nickel nitride has the composition Ni{sub 2}Mo{sub 3}N and therefore is in admixture with nickel. All the nitrides have been characterized by various physical methods.
- Authors:
-
- Chemistry and Physics Materials Unit and CSIR Centre of Excellence in Chemistry, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur P.O., Bangalore, Karnataka 560 064 (India)
- Publication Date:
- OSTI Identifier:
- 21000634
- Resource Type:
- Journal Article
- Journal Name:
- Materials Research Bulletin
- Additional Journal Information:
- Journal Volume: 42; Journal Issue: 5; Other Information: DOI: 10.1016/j.materresbull.2006.08.021; PII: S0025-5408(06)00349-7; Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0025-5408
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; HEATING; INTERSTITIALS; MOLYBDATES; MOLYBDENUM; MOLYBDENUM NITRIDES; NICKEL; NICKEL NITRIDES; PRECURSOR; UREA
Citation Formats
Gomathi, A. Ternary metal nitrides by the urea route. United States: N. p., 2007.
Web. doi:10.1016/j.materresbull.2006.08.021.
Gomathi, A. Ternary metal nitrides by the urea route. United States. https://doi.org/10.1016/j.materresbull.2006.08.021
Gomathi, A. 2007.
"Ternary metal nitrides by the urea route". United States. https://doi.org/10.1016/j.materresbull.2006.08.021.
@article{osti_21000634,
title = {Ternary metal nitrides by the urea route},
author = {Gomathi, A},
abstractNote = {Interstitial molybdenum ternary nitrides, M {sub n}Mo{sub 3}N (M = Fe and Co, n = 3; M = Ni, n = 2), can be obtained by heating the molybdate precursors, FeMoO{sub 4}, CoMoO{sub 4} and NiMoO{sub 4} with urea in the 1:12 molar ratio in the 900-1000 deg. C range. Fe{sub 3}Mo{sub 3}N and Co{sub 3}Mo{sub 3}N are obtained in pure form. The nickel nitride has the composition Ni{sub 2}Mo{sub 3}N and therefore is in admixture with nickel. All the nitrides have been characterized by various physical methods.},
doi = {10.1016/j.materresbull.2006.08.021},
url = {https://www.osti.gov/biblio/21000634},
journal = {Materials Research Bulletin},
issn = {0025-5408},
number = 5,
volume = 42,
place = {United States},
year = {Thu May 03 00:00:00 EDT 2007},
month = {Thu May 03 00:00:00 EDT 2007}
}
Other availability
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.