Spectroscopy of cyanodiacetylene in solid argon and the photochemical generation of isocyanodiacetylene
Journal Article
·
· Journal of Chemical Physics
- UMR CNRS 6633, Physique des Interactions Ioniques et Moleculaires, Equipe de Spectrometries et Dynamique Moleculaires, Universite de Provence, Case 252, Centre de St. Jerome, 13397 Marseille Cedex 20 (France)
Following the measurements of UV and mid-IR spectra of cyanodiacetylene, H-(CC){sub 2}-CN, isolated in low temperature Ar matrices, the first photochemical study on this compound and on its {sup 2}H isotopomer was carried out with the laser light tuned to 267 nm and with far-UV discharge lamps. Evidence for the formation of isocyanodiacetylene, H-(CC){sub 2}-NC, was found in infrared absorption spectra interpreted with the aid of available theoretical predictions.
- OSTI ID:
- 20991255
- Journal Information:
- Journal of Chemical Physics, Vol. 126, Issue 16; Other Information: DOI: 10.1063/1.2720842; (c) 2007 American Institute of Physics; Country of input: International Atomic Energy Agency (IAEA); ISSN 0021-9606
- Country of Publication:
- United States
- Language:
- English
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