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Title: Spectroscopy of cyanodiacetylene in solid argon and the photochemical generation of isocyanodiacetylene

Abstract

Following the measurements of UV and mid-IR spectra of cyanodiacetylene, H-(CC){sub 2}-CN, isolated in low temperature Ar matrices, the first photochemical study on this compound and on its {sup 2}H isotopomer was carried out with the laser light tuned to 267 nm and with far-UV discharge lamps. Evidence for the formation of isocyanodiacetylene, H-(CC){sub 2}-NC, was found in infrared absorption spectra interpreted with the aid of available theoretical predictions.

Authors:
; ; ; ; ; ;  [1];  [2];  [3];  [2];  [3]
  1. UMR CNRS 6633, Physique des Interactions Ioniques et Moleculaires, Equipe de Spectrometries et Dynamique Moleculaires, Universite de Provence, Case 252, Centre de St. Jerome, 13397 Marseille Cedex 20 (France)
  2. (Poland)
  3. (France)
Publication Date:
OSTI Identifier:
20991255
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Chemical Physics; Journal Volume: 126; Journal Issue: 16; Other Information: DOI: 10.1063/1.2720842; (c) 2007 American Institute of Physics; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ABSORPTION SPECTRA; ARGON; DENSITY FUNCTIONAL METHOD; DEUTERIUM; INFRARED SPECTRA; ORGANIC NITROGEN COMPOUNDS; PHOTOCHEMISTRY; REACTION KINETICS; SPECTROSCOPY; ULTRAVIOLET SPECTRA

Citation Formats

Coupeaud, Anne, Turowski, Michal, Gronowski, Marcin, Pietri, Nathalie, Couturier-Tamburelli, Isabelle, Kolos, Robert, Aycard, Jean-Pierre, Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44, 01-224 Warsaw, UMR CNRS 6633, Physique des Interactions Ioniques et Moleculaires, Equipe de Spectrometries et Dynamique Moleculaires, Universite de Provence, Case 252, Centre de St. Jerome, 13397 Marseille Cedex 20, Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44, 01-224 Warsaw, and UMR CNRS 6633, Physique des Interactions Ioniques et Moleculaires, Equipe de Spectrometries et Dynamique Moleculaires, Universite de Provence, Case 252, Centre de St. Jerome, 13397 Marseille Cedex 20. Spectroscopy of cyanodiacetylene in solid argon and the photochemical generation of isocyanodiacetylene. United States: N. p., 2007. Web. doi:10.1063/1.2720842.
Coupeaud, Anne, Turowski, Michal, Gronowski, Marcin, Pietri, Nathalie, Couturier-Tamburelli, Isabelle, Kolos, Robert, Aycard, Jean-Pierre, Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44, 01-224 Warsaw, UMR CNRS 6633, Physique des Interactions Ioniques et Moleculaires, Equipe de Spectrometries et Dynamique Moleculaires, Universite de Provence, Case 252, Centre de St. Jerome, 13397 Marseille Cedex 20, Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44, 01-224 Warsaw, & UMR CNRS 6633, Physique des Interactions Ioniques et Moleculaires, Equipe de Spectrometries et Dynamique Moleculaires, Universite de Provence, Case 252, Centre de St. Jerome, 13397 Marseille Cedex 20. Spectroscopy of cyanodiacetylene in solid argon and the photochemical generation of isocyanodiacetylene. United States. doi:10.1063/1.2720842.
Coupeaud, Anne, Turowski, Michal, Gronowski, Marcin, Pietri, Nathalie, Couturier-Tamburelli, Isabelle, Kolos, Robert, Aycard, Jean-Pierre, Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44, 01-224 Warsaw, UMR CNRS 6633, Physique des Interactions Ioniques et Moleculaires, Equipe de Spectrometries et Dynamique Moleculaires, Universite de Provence, Case 252, Centre de St. Jerome, 13397 Marseille Cedex 20, Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44, 01-224 Warsaw, and UMR CNRS 6633, Physique des Interactions Ioniques et Moleculaires, Equipe de Spectrometries et Dynamique Moleculaires, Universite de Provence, Case 252, Centre de St. Jerome, 13397 Marseille Cedex 20. Sat . "Spectroscopy of cyanodiacetylene in solid argon and the photochemical generation of isocyanodiacetylene". United States. doi:10.1063/1.2720842.
@article{osti_20991255,
title = {Spectroscopy of cyanodiacetylene in solid argon and the photochemical generation of isocyanodiacetylene},
author = {Coupeaud, Anne and Turowski, Michal and Gronowski, Marcin and Pietri, Nathalie and Couturier-Tamburelli, Isabelle and Kolos, Robert and Aycard, Jean-Pierre and Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44, 01-224 Warsaw and UMR CNRS 6633, Physique des Interactions Ioniques et Moleculaires, Equipe de Spectrometries et Dynamique Moleculaires, Universite de Provence, Case 252, Centre de St. Jerome, 13397 Marseille Cedex 20 and Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44, 01-224 Warsaw and UMR CNRS 6633, Physique des Interactions Ioniques et Moleculaires, Equipe de Spectrometries et Dynamique Moleculaires, Universite de Provence, Case 252, Centre de St. Jerome, 13397 Marseille Cedex 20},
abstractNote = {Following the measurements of UV and mid-IR spectra of cyanodiacetylene, H-(CC){sub 2}-CN, isolated in low temperature Ar matrices, the first photochemical study on this compound and on its {sup 2}H isotopomer was carried out with the laser light tuned to 267 nm and with far-UV discharge lamps. Evidence for the formation of isocyanodiacetylene, H-(CC){sub 2}-NC, was found in infrared absorption spectra interpreted with the aid of available theoretical predictions.},
doi = {10.1063/1.2720842},
journal = {Journal of Chemical Physics},
number = 16,
volume = 126,
place = {United States},
year = {Sat Apr 28 00:00:00 EDT 2007},
month = {Sat Apr 28 00:00:00 EDT 2007}
}