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Title: Electron-ion-ion triple-coincidence spectroscopic study of site-specific fragmentation caused by Si:2p core-level photoionization of F{sub 3}SiCH{sub 2}CH{sub 2}Si(CH{sub 3}){sub 3} vapor

Abstract

Site-specific fragmentation caused by Si:2p core-level photoionization of F{sub 3}SiCH{sub 2}CH{sub 2}Si(CH{sub 3}){sub 3} vapor was studied by means of high-resolution energy-selected-electron photoion-photoion triple-coincidence spectroscopy. The ab initio molecular orbital method was used for the theoretical description. F{sub 3}SiCH{sub 2}CH{sub 2}{sup +}-Si(CH{sub 3}){sub 3}{sup +} ion pairs were produced by the 2p photoionization of the Si atoms bonded to the three methyl groups, and SiF{sup +}-containing ion pairs were produced by the 2p photoionization of the Si atoms bonded to the three F atoms.

Authors:
; ;  [1]; ; ; ; ;  [2]; ;  [3];  [4]; ; ;  [5]
  1. Department of Chemistry, Ehime University, Matsuyama 790-8577 (Japan)
  2. Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980-8577 (Japan)
  3. JASRI, 1-1-1 Kouto, Sayo-cho, Sayo-gun 679-5198 (Japan)
  4. AIST, Tsukuba 305-8568 (Japan)
  5. Department of Chemistry, Hiroshima University, Higashi-Hiroshima 739-8526 (Japan)
Publication Date:
OSTI Identifier:
20982050
Resource Type:
Journal Article
Resource Relation:
Journal Name: Physical Review. A; Journal Volume: 75; Journal Issue: 2; Other Information: DOI: 10.1103/PhysRevA.75.020502; (c) 2007 The American Physical Society; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
74 ATOMIC AND MOLECULAR PHYSICS; ATOMS; COINCIDENCE SPECTROMETRY; DISSOCIATION; ELECTRONS; FRAGMENTATION; ION PAIRS; IONS; MOLECULAR IONS; MOLECULAR ORBITAL METHOD; ORGANIC COMPOUNDS; PHOTOELECTRON SPECTROSCOPY; PHOTOIONIZATION; PHOTOLYSIS; PHOTON-MOLECULE COLLISIONS; RESOLUTION; SILICON FLUORIDES; SILICON IONS; VAPORS

Citation Formats

Nagaoka, S., Hino, M., Takemoto, M., Pruemper, G., Fukuzawa, H., Liu, X.-J., Lischke, T., Ueda, K., Tamenori, Y., Harries, J., Suzuki, I. H., Takahashi, O., Okada, K., and Tabayashi, K.. Electron-ion-ion triple-coincidence spectroscopic study of site-specific fragmentation caused by Si:2p core-level photoionization of F{sub 3}SiCH{sub 2}CH{sub 2}Si(CH{sub 3}){sub 3} vapor. United States: N. p., 2007. Web. doi:10.1103/PHYSREVA.75.020502.
Nagaoka, S., Hino, M., Takemoto, M., Pruemper, G., Fukuzawa, H., Liu, X.-J., Lischke, T., Ueda, K., Tamenori, Y., Harries, J., Suzuki, I. H., Takahashi, O., Okada, K., & Tabayashi, K.. Electron-ion-ion triple-coincidence spectroscopic study of site-specific fragmentation caused by Si:2p core-level photoionization of F{sub 3}SiCH{sub 2}CH{sub 2}Si(CH{sub 3}){sub 3} vapor. United States. doi:10.1103/PHYSREVA.75.020502.
Nagaoka, S., Hino, M., Takemoto, M., Pruemper, G., Fukuzawa, H., Liu, X.-J., Lischke, T., Ueda, K., Tamenori, Y., Harries, J., Suzuki, I. H., Takahashi, O., Okada, K., and Tabayashi, K.. Thu . "Electron-ion-ion triple-coincidence spectroscopic study of site-specific fragmentation caused by Si:2p core-level photoionization of F{sub 3}SiCH{sub 2}CH{sub 2}Si(CH{sub 3}){sub 3} vapor". United States. doi:10.1103/PHYSREVA.75.020502.
@article{osti_20982050,
title = {Electron-ion-ion triple-coincidence spectroscopic study of site-specific fragmentation caused by Si:2p core-level photoionization of F{sub 3}SiCH{sub 2}CH{sub 2}Si(CH{sub 3}){sub 3} vapor},
author = {Nagaoka, S. and Hino, M. and Takemoto, M. and Pruemper, G. and Fukuzawa, H. and Liu, X.-J. and Lischke, T. and Ueda, K. and Tamenori, Y. and Harries, J. and Suzuki, I. H. and Takahashi, O. and Okada, K. and Tabayashi, K.},
abstractNote = {Site-specific fragmentation caused by Si:2p core-level photoionization of F{sub 3}SiCH{sub 2}CH{sub 2}Si(CH{sub 3}){sub 3} vapor was studied by means of high-resolution energy-selected-electron photoion-photoion triple-coincidence spectroscopy. The ab initio molecular orbital method was used for the theoretical description. F{sub 3}SiCH{sub 2}CH{sub 2}{sup +}-Si(CH{sub 3}){sub 3}{sup +} ion pairs were produced by the 2p photoionization of the Si atoms bonded to the three methyl groups, and SiF{sup +}-containing ion pairs were produced by the 2p photoionization of the Si atoms bonded to the three F atoms.},
doi = {10.1103/PHYSREVA.75.020502},
journal = {Physical Review. A},
number = 2,
volume = 75,
place = {United States},
year = {Thu Feb 15 00:00:00 EST 2007},
month = {Thu Feb 15 00:00:00 EST 2007}
}