New organically templated gallium oxalate-phosphate structures based on Ga{sub 4}(PO{sub 4}){sub 4}(C{sub 2}O{sub 4}) building unit

Zhenxia, Chen; Songliang, Tan; Linhong, Weng; Yaming, Zhou; Xiang, Gao; Dongyuan, Zhao

doi:10.1016/j.jssc.2006.03.031

Title: New organically templated gallium oxalate-phosphate structures based on Ga{sub 4}(PO{sub 4}){sub 4}(C{sub 2}O{sub 4}) building unit

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Abstract

Five organic-inorganic hybrid gallium oxalate-phosphates, [Ga{sub 2}(PO{sub 4}){sub 2}(H{sub 2}O)(C{sub 2}O{sub 4}){sub 0.5}](C{sub 3}N{sub 2}H{sub 12}){sub 0.5}(H{sub 2}O) (1), [Ga{sub 2}(PO{sub 4}){sub 2}(C{sub 2}O{sub 4}){sub 0.5}](C{sub 2}N{sub 2}H{sub 10}){sub 0.5}(H{sub 2}O) (2), [Ga{sub 2}(PO{sub 4}){sub 2}(C{sub 2}O{sub 4}){sub 0.5}](C{sub 3}N{sub 2}H{sub 12}){sub 0.5} (3), [Ga{sub 2}(PO{sub 4}){sub 2}(H{sub 2}PO{sub 4}){sub 0.5}(C{sub 2}O{sub 4}){sub 0.5}](C{sub 4}N{sub 3}H{sub 16}){sub 0.5} (H{sub 2}O){sub 1.5} (4) and [Ga{sub 2.5}(PO{sub 4}){sub 2.5}(H{sub 2}O){sub 1.5}(C{sub 2}O{sub 4}){sub 0.5}](C{sub 4}N{sub 3}H{sub 15}){sub 0.5} (5), have been synthesized by using 1,3-diaminopropane, ethylenediamine and diethylene triamine as structure-directing agents under hydrothermal condition. The structures of 1-5 are based on Ga{sub 4}(PO{sub 4}){sub 4}(C{sub 2}O{sub 4}) building unit made up from Ga{sub 2}O{sub 8}(C{sub 2}O{sub 4}) oxalate-bridging dimer and alternating PO{sub 4} and GaO{sub 4} tetrahedral units. Compound 1 is layered structure where the building units link together in the same orientation. Corner sharing of these similar layers result in three-dimensional (3-D) structure 2. However, in compound 3, the building units arrange in a wave-like way to generate two types of eight member ring (8MR) channels. Both 4 and 5 contain the layers where the building units have an opposite orientation. Those layers are linked by H{sub 2}PO{sub 4} groupmore »« less

Authors:

Zhenxia, Chen ^[1]; Songliang, Tan ^[1]; Linhong, Weng ^[1]; Yaming, Zhou ^[1]; Xiang, Gao ^[1]; Dongyuan, Zhao ^[1]

Molecular Catalysis and Innovative Materials Laboratory, Department of Chemistry, Fudan University, Shanghai 200433 (China)

Publication Date:: Sat Jul 15 00:00:00 EDT 2006

OSTI Identifier:: 20905333

Resource Type:: Journal Article

Journal Name:: Journal of Solid State Chemistry

Additional Journal Information:: Journal Volume: 179; Journal Issue: 7; Other Information: DOI: 10.1016/j.jssc.2006.03.031; PII: S0022-4596(06)00179-4; Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0022-4596

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; CRYSTAL STRUCTURE; GALLIUM PHOSPHATES; LAYERS; ORGANIC PHOSPHORUS COMPOUNDS; OXALATES

Citation Formats


                    Zhenxia, Chen, Songliang, Tan, Linhong, Weng, Yaming, Zhou, Xiang, Gao, and Dongyuan, Zhao. New organically templated gallium oxalate-phosphate structures based on Ga{sub 4}(PO{sub 4}){sub 4}(C{sub 2}O{sub 4}) building unit.  United States: N. p., 2006. 
        Web.  doi:10.1016/j.jssc.2006.03.031.

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                    Zhenxia, Chen, Songliang, Tan, Linhong, Weng, Yaming, Zhou, Xiang, Gao, & Dongyuan, Zhao. New organically templated gallium oxalate-phosphate structures based on Ga{sub 4}(PO{sub 4}){sub 4}(C{sub 2}O{sub 4}) building unit.  United States.  https://doi.org/10.1016/j.jssc.2006.03.031

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                    Zhenxia, Chen, Songliang, Tan, Linhong, Weng, Yaming, Zhou, Xiang, Gao, and Dongyuan, Zhao. 2006.  
        "New organically templated gallium oxalate-phosphate structures based on Ga{sub 4}(PO{sub 4}){sub 4}(C{sub 2}O{sub 4}) building unit".  United States.  https://doi.org/10.1016/j.jssc.2006.03.031.

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@article{osti_20905333,

  title        = {New organically templated gallium oxalate-phosphate structures based on Ga{sub 4}(PO{sub 4}){sub 4}(C{sub 2}O{sub 4}) building unit},

  author       = {Zhenxia, Chen and Songliang, Tan and Linhong, Weng and Yaming, Zhou and Xiang, Gao and Dongyuan, Zhao},

  abstractNote = {Five organic-inorganic hybrid gallium oxalate-phosphates, [Ga{sub 2}(PO{sub 4}){sub 2}(H{sub 2}O)(C{sub 2}O{sub 4}){sub 0.5}](C{sub 3}N{sub 2}H{sub 12}){sub 0.5}(H{sub 2}O) (1), [Ga{sub 2}(PO{sub 4}){sub 2}(C{sub 2}O{sub 4}){sub 0.5}](C{sub 2}N{sub 2}H{sub 10}){sub 0.5}(H{sub 2}O) (2), [Ga{sub 2}(PO{sub 4}){sub 2}(C{sub 2}O{sub 4}){sub 0.5}](C{sub 3}N{sub 2}H{sub 12}){sub 0.5} (3), [Ga{sub 2}(PO{sub 4}){sub 2}(H{sub 2}PO{sub 4}){sub 0.5}(C{sub 2}O{sub 4}){sub 0.5}](C{sub 4}N{sub 3}H{sub 16}){sub 0.5} (H{sub 2}O){sub 1.5} (4) and [Ga{sub 2.5}(PO{sub 4}){sub 2.5}(H{sub 2}O){sub 1.5}(C{sub 2}O{sub 4}){sub 0.5}](C{sub 4}N{sub 3}H{sub 15}){sub 0.5} (5), have been synthesized by using 1,3-diaminopropane, ethylenediamine and diethylene triamine as structure-directing agents under hydrothermal condition. The structures of 1-5 are based on Ga{sub 4}(PO{sub 4}){sub 4}(C{sub 2}O{sub 4}) building unit made up from Ga{sub 2}O{sub 8}(C{sub 2}O{sub 4}) oxalate-bridging dimer and alternating PO{sub 4} and GaO{sub 4} tetrahedral units. Compound 1 is layered structure where the building units link together in the same orientation. Corner sharing of these similar layers result in three-dimensional (3-D) structure 2. However, in compound 3, the building units arrange in a wave-like way to generate two types of eight member ring (8MR) channels. Both 4 and 5 contain the layers where the building units have an opposite orientation. Those layers are linked by H{sub 2}PO{sub 4} group and Ga(PO{sub 4})(H{sub 2}O){sub 3} cluster, respectively, to form 3-D frameworks with 12MR large pore channels. Compounds 2-5 exhibit intersecting 3-D channels where the protoned amines are located. - Graphical abstract: Compound 4 contains layers where the Ga{sub 4}(PO{sub 4}){sub 4}(C{sub 2}O{sub 4}) building units are connected to each other in an opposite orientation. The phosphorous atom sits on a twofold axis, is positioned between the layers and joins the GaO{sub 4}(C{sub 2}O{sub 4}) group from adjacent layers, generating two types of alternating 8MR and 12MR channels along the [001] direction.},

  doi          = {10.1016/j.jssc.2006.03.031},

  url          = {https://www.osti.gov/biblio/20905333},
  journal      = {Journal of Solid State Chemistry},

  issn         = {0022-4596},

  number       = 7,

  volume       = 179,

  place        = {United States},

  year         = {Sat Jul 15 00:00:00 EDT 2006},

  month        = {Sat Jul 15 00:00:00 EDT 2006}

}

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