One-step synthesis of dispersed bimetallic carbides and nitrides from transition metals hexamethylenetetramine complexes
- Institut de Recherche sur la Catalyse, 2 Avenue A. Einstein, 69626 Villeurbanne, Cedex (France)
- Catalysis and Separation Division, Heterogeneous Catalysis Department Institut Francais du Petrole, IFP-LYON, BP 3, 69390 Vernaison (France)
Bimetallic nitrides and carbides Co(Ni)-Mo were obtained from the decomposition of transition metals complexes with hexamethylenetetramine (HMTA) under inert atmosphere. The precursor complexes were prepared by means of aqueous precipitation of ammonium molybdate with cobalt nitrate or nickel nitrate and HMTA. During the decomposition, HMTA acts at once as a reducing agent and as a source of carbon and nitrogen. The precursor's composition and the decomposition conditions are the key parameters to influence the nature of the obtained phases. The method developed provides a simple one-step way to highly divided bimetallic nitrides and carbides. -- Graphical abstract: Bimetallic nitrides and carbides Co(Ni)-Mo were obtained from the decomposition of metals complexes with hexamethylenetetramine (HMTA) under inert atmosphere. During the decomposition, HMTA acts at once as a reducing agent and as a source of carbon and nitrogen. The method provides a simple one-step way to highly divided nitrides and carbides. Display Omitted.
- OSTI ID:
- 20902472
- Journal Information:
- Journal of Solid State Chemistry, Vol. 179, Issue 11; Other Information: DOI: 10.1016/j.jssc.2006.06.026; PII: S0022-4596(06)00363-X; Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA); ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
AMMONIUM COMPOUNDS
COBALT CARBIDES
COBALT COMPLEXES
COBALT COMPOUNDS
COBALT NITRATES
DECOMPOSITION
INERT ATMOSPHERE
MOLYBDATES
MOLYBDENUM CARBIDES
MOLYBDENUM COMPLEXES
MOLYBDENUM NITRIDES
NICKEL CARBIDES
NICKEL COMPLEXES
NICKEL NITRATES
NICKEL NITRIDES
NITRIDES
PRECIPITATION
REDUCING AGENTS
SYNTHESIS
UROTROPIN