Crystal structure and vibrational properties of new luminescent hosts K{sub 3}YF{sub 6} and K{sub 3}GdF{sub 6}
Journal Article
·
· Journal of Solid State Chemistry
- Institute of Low Temperature and Structure Research Polish Academy of Sciences, P.O. Box 1410, 50-950 Wroclaw (Poland)
The luminescence hosts K{sub 3}YF{sub 6} and K{sub 3}GdF{sub 6} were obtained in a single-crystal form. Their crystal structure was determined from single-crystal X-ray diffraction data. Both crystals adopt monoclinic system with space group P2{sub 1}/n, Z=2. Lattice parameters for K{sub 3}YF{sub 6} are refined to the following values a=6.3376(13)A, b=6.5435(13)A, c=9.0390(18)A, {beta}=90.65(3) and for K{sub 3}GdF{sub 6}a=6.3759(13)A, b=6.5922(13)A, c=9.1200(18)A, {beta}=90.80(3). The vibrational analysis, IR and Raman spectroscopy at room temperature, was applied to these compounds in order to study the site symmetry of Y{sup 3+} and Gd{sup 3+} ions.
- OSTI ID:
- 20900857
- Journal Information:
- Journal of Solid State Chemistry, Vol. 179, Issue 10; Other Information: DOI: 10.1016/j.jssc.2006.06.005; PII: S0022-4596(06)00332-X; Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA); ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
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