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Title: Two 2-D 3{sup 6} tessellated metal-organic frameworks constructed from trimetallic clusters and dicarboxylate ditopic links

Abstract

Two metal-organic framework compounds, [Zn{sub 3}(1,4-BDC){sub 3}(Py){sub 2}].2(1,4-dioxane) (MOF-CJ6) and [Cd{sub 3}(bpdc){sub 3}(H{sub 2}O){sub 2}] (MOF-CJ7), have been solvothermally synthesized and characterized by single crystal X-ray diffraction, X-ray powder diffraction, ICP, IR and photoluminescence spectroscopy analyses, respectively. MOF-CJ6 crystallizes in monoclinic, space group P2(1)/n (no. 14) with a = 14.6886(14) A, b = 9.6194(6) A, c = 15.9161(16) A and {beta} = 105.687(6){sup o}. Its framework can be described as a 2-D 3{sup 6} tessellated net based on the assembly of trimeric Zn{sub 3}(CO{sub 2}){sub 6} clusters and 1,4-benzenedicarboxylates ditopic links. The 2-D nets can be further linked into a novel 3-D supramolecular hexagonal lattice (hex) network through {pi}-{pi} packing interaction. MOF-CJ7 crystallizes in trigonal, space group R-3 (no. 148) with a = 14.1129(8) A, b = 14.1129(8) A, c = 20.1168(13) A and {gamma} = 120{sup o}. MOF-CJ7 exhibits analogous framework topology with that of MOF-CJ6, consisting of trimeric Cd{sub 3}(CO{sub 2}){sub 6} clusters and 4,4'-biphenyldicarboxylate links.

Authors:
 [1];  [1];  [1];  [1];  [1]
  1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China)
Publication Date:
OSTI Identifier:
20895210
Resource Type:
Journal Article
Journal Name:
Materials Research Bulletin
Additional Journal Information:
Journal Volume: 41; Journal Issue: 5; Other Information: DOI: 10.1016/j.materresbull.2006.01.018; PII: S0025-5408(06)00036-5; Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0025-5408
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; CARBON DIOXIDE; DEUTERIUM COMPOUNDS; DIOXANE; HEXAGONAL LATTICES; METHYL RADICALS; MONOCLINIC LATTICES; MONOCRYSTALS; ORGANOMETALLIC COMPOUNDS; PHOTOLUMINESCENCE; SPACE GROUPS; SPECTROSCOPY; TOPOLOGY; X-RAY DIFFRACTION

Citation Formats

Jianghua, He, Yuetao, Zhang, Jihong, Yu, Qinhe, Pan, and Ruren, Xu. Two 2-D 3{sup 6} tessellated metal-organic frameworks constructed from trimetallic clusters and dicarboxylate ditopic links. United States: N. p., 2006. Web.
Jianghua, He, Yuetao, Zhang, Jihong, Yu, Qinhe, Pan, & Ruren, Xu. Two 2-D 3{sup 6} tessellated metal-organic frameworks constructed from trimetallic clusters and dicarboxylate ditopic links. United States.
Jianghua, He, Yuetao, Zhang, Jihong, Yu, Qinhe, Pan, and Ruren, Xu. Thu . "Two 2-D 3{sup 6} tessellated metal-organic frameworks constructed from trimetallic clusters and dicarboxylate ditopic links". United States.
@article{osti_20895210,
title = {Two 2-D 3{sup 6} tessellated metal-organic frameworks constructed from trimetallic clusters and dicarboxylate ditopic links},
author = {Jianghua, He and Yuetao, Zhang and Jihong, Yu and Qinhe, Pan and Ruren, Xu},
abstractNote = {Two metal-organic framework compounds, [Zn{sub 3}(1,4-BDC){sub 3}(Py){sub 2}].2(1,4-dioxane) (MOF-CJ6) and [Cd{sub 3}(bpdc){sub 3}(H{sub 2}O){sub 2}] (MOF-CJ7), have been solvothermally synthesized and characterized by single crystal X-ray diffraction, X-ray powder diffraction, ICP, IR and photoluminescence spectroscopy analyses, respectively. MOF-CJ6 crystallizes in monoclinic, space group P2(1)/n (no. 14) with a = 14.6886(14) A, b = 9.6194(6) A, c = 15.9161(16) A and {beta} = 105.687(6){sup o}. Its framework can be described as a 2-D 3{sup 6} tessellated net based on the assembly of trimeric Zn{sub 3}(CO{sub 2}){sub 6} clusters and 1,4-benzenedicarboxylates ditopic links. The 2-D nets can be further linked into a novel 3-D supramolecular hexagonal lattice (hex) network through {pi}-{pi} packing interaction. MOF-CJ7 crystallizes in trigonal, space group R-3 (no. 148) with a = 14.1129(8) A, b = 14.1129(8) A, c = 20.1168(13) A and {gamma} = 120{sup o}. MOF-CJ7 exhibits analogous framework topology with that of MOF-CJ6, consisting of trimeric Cd{sub 3}(CO{sub 2}){sub 6} clusters and 4,4'-biphenyldicarboxylate links.},
doi = {},
journal = {Materials Research Bulletin},
issn = {0025-5408},
number = 5,
volume = 41,
place = {United States},
year = {2006},
month = {5}
}