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Title: Premixed ignition behavior of alternative diesel fuel-relevant compounds in a motored engine experiment

Abstract

A motored engine study using premixed charges of fuel and air at a wide range of diesel-relevant equivalence ratios was performed to investigate autoignition differences among surrogates for conventional diesel fuel, gas-to-liquid (GTL) diesel fuel, and biodiesel, as well as n-heptane. Experiments were performed by delivering a premixed charge of vaporized fuel and air and increasing the compression ratio in a stepwise manner to increase the extent of reaction while monitoring the exhaust composition via Fourier transform infrared (FTIR) spectrometry and collecting condensable exhaust gas for subsequent gas chromatography/mass spectrometry (GC/MS) analysis. Each fuel demonstrated a two-stage ignition process, with a low-temperature heat release (LTHR) event followed by the main combustion, or high-temperature heat release (HTHR). Among the three diesel-relevant fuels, the magnitude of LTHR was highest for GTL diesel, followed by methyl decanoate, and conventional diesel fuel last. FTIR analysis of the exhaust for n-heptane, the conventional diesel surrogate, and the GTL diesel surrogate revealed that LTHR produces high concentrations of aldehydes and CO while producing only negligible amounts of CO{sub 2}. Methyl decanoate differed from the other two-stage ignition fuels only in that there were significant amounts of CO{sub 2} produced during LTHR; this was the result ofmore » decarboxylation of the ester group, not the result of oxidation. GC/MS analysis of LTHR exhaust condensate for n-heptane revealed high concentrations of 2,5-heptanedione, a di-ketone that can be closely tied to species in existing autoignition models for n-heptane. GC/MS analysis of the LTHR condensate for conventional diesel fuel and GTL diesel fuel revealed a series of high molecular weight aldehydes and ketones, which were expected, as well as a series of organic acids, which are not commonly reported as products of combustion. The GC/MS analysis of the methyl decanoate exhaust condensate revealed that the aliphatic chain acts similarly to n-paraffins during LTHR, while the ester group remains intact. Thus, although the FTIR data revealed that decarboxylation occurs at significant levels for methyl decanoate, it was concluded that this occurs after the aliphatic chain has been largely consumed by other LTHR reactions. (author)« less

Authors:
; ;  [1];  [2]
  1. Pennsylvania State University, Fuel Science Program, 405 Academic Activities Building, University Park, PA 16802 (United States)
  2. Honda R and D Company, Ltd., Asaka-shi, Saitama 351-0024 (Japan)
Publication Date:
OSTI Identifier:
20880643
Resource Type:
Journal Article
Resource Relation:
Journal Name: Combustion and Flame; Journal Volume: 149; Journal Issue: 1-2; Other Information: Elsevier Ltd. All rights reserved
Country of Publication:
United States
Language:
English
Subject:
33 ADVANCED PROPULSION SYSTEMS; 09 BIOMASS FUELS; 02 PETROLEUM; DIESEL FUELS; HEPTANE; BIOFUELS; EXHAUST GASES; COMBUSTION; CARBON DIOXIDE; AIR; AUTOIGNITION; DECANOIC ACID; ALKANES; ALDEHYDES; ESTERS; DECARBOXYLATION; KETONES; TEMPERATURE RANGE 0400-1000 K; DIESEL ENGINES; CONDENSATES; COMPRESSION RATIO; ORGANIC ACIDS; CARBON MONOXIDE

Citation Formats

Szybist, James P., Boehman, Andre L., Haworth, Daniel C., and Koga, Hibiki. Premixed ignition behavior of alternative diesel fuel-relevant compounds in a motored engine experiment. United States: N. p., 2007. Web. doi:10.1016/J.COMBUSTFLAME.2006.12.011.
Szybist, James P., Boehman, Andre L., Haworth, Daniel C., & Koga, Hibiki. Premixed ignition behavior of alternative diesel fuel-relevant compounds in a motored engine experiment. United States. doi:10.1016/J.COMBUSTFLAME.2006.12.011.
Szybist, James P., Boehman, Andre L., Haworth, Daniel C., and Koga, Hibiki. Sun . "Premixed ignition behavior of alternative diesel fuel-relevant compounds in a motored engine experiment". United States. doi:10.1016/J.COMBUSTFLAME.2006.12.011.
@article{osti_20880643,
title = {Premixed ignition behavior of alternative diesel fuel-relevant compounds in a motored engine experiment},
author = {Szybist, James P. and Boehman, Andre L. and Haworth, Daniel C. and Koga, Hibiki},
abstractNote = {A motored engine study using premixed charges of fuel and air at a wide range of diesel-relevant equivalence ratios was performed to investigate autoignition differences among surrogates for conventional diesel fuel, gas-to-liquid (GTL) diesel fuel, and biodiesel, as well as n-heptane. Experiments were performed by delivering a premixed charge of vaporized fuel and air and increasing the compression ratio in a stepwise manner to increase the extent of reaction while monitoring the exhaust composition via Fourier transform infrared (FTIR) spectrometry and collecting condensable exhaust gas for subsequent gas chromatography/mass spectrometry (GC/MS) analysis. Each fuel demonstrated a two-stage ignition process, with a low-temperature heat release (LTHR) event followed by the main combustion, or high-temperature heat release (HTHR). Among the three diesel-relevant fuels, the magnitude of LTHR was highest for GTL diesel, followed by methyl decanoate, and conventional diesel fuel last. FTIR analysis of the exhaust for n-heptane, the conventional diesel surrogate, and the GTL diesel surrogate revealed that LTHR produces high concentrations of aldehydes and CO while producing only negligible amounts of CO{sub 2}. Methyl decanoate differed from the other two-stage ignition fuels only in that there were significant amounts of CO{sub 2} produced during LTHR; this was the result of decarboxylation of the ester group, not the result of oxidation. GC/MS analysis of LTHR exhaust condensate for n-heptane revealed high concentrations of 2,5-heptanedione, a di-ketone that can be closely tied to species in existing autoignition models for n-heptane. GC/MS analysis of the LTHR condensate for conventional diesel fuel and GTL diesel fuel revealed a series of high molecular weight aldehydes and ketones, which were expected, as well as a series of organic acids, which are not commonly reported as products of combustion. The GC/MS analysis of the methyl decanoate exhaust condensate revealed that the aliphatic chain acts similarly to n-paraffins during LTHR, while the ester group remains intact. Thus, although the FTIR data revealed that decarboxylation occurs at significant levels for methyl decanoate, it was concluded that this occurs after the aliphatic chain has been largely consumed by other LTHR reactions. (author)},
doi = {10.1016/J.COMBUSTFLAME.2006.12.011},
journal = {Combustion and Flame},
number = 1-2,
volume = 149,
place = {United States},
year = {Sun Apr 15 00:00:00 EDT 2007},
month = {Sun Apr 15 00:00:00 EDT 2007}
}