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Title: Polarized IR studies of silica glasses exposed to polarized excimer radiation

Journal Article · · Journal of the Optical Society of America. Part B, Optical Physics
; ;  [1]
  1. Science and Technology Division, Corning, Inc., Corning, New York 14830 (United States)

Silica glass exhibits a permanent anisotropic response, polarization-induced birefringence (PIB), when exposed to short-wavelength polarized light. This behavior has been correlated with the OH content of the glass. In this paper we describe polarized infrared studies of silica glasses of different OH content exposed with polarized 157 nm laser light. Changes in the fundamental OH band as a consequence of exposure are shown. We find differential bleaching of a particular OH band where OH species that are oriented parallel to the incident exposing polarization undergo greater bleaching than those oriented perpendicular. The preferential bleaching as a function of exposure time correlates strongly with the evolution of PIB, leading to a bleaching model of OH that is causally linked to PIB.

OSTI ID:
20861437
Journal Information:
Journal of the Optical Society of America. Part B, Optical Physics, Vol. 23, Issue 12; Other Information: DOI: 10.1364/JOSAB.23.002511; (c) 2006 Optical Society of America; Country of input: International Atomic Energy Agency (IAEA); ISSN 0740-3224
Country of Publication:
United States
Language:
English

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