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Title: Neutron diffraction shows a photoinduced isonitrosyl linkage isomer in the metastable state SI of Na{sub 2}[Fe(CN){sub 5}NO]{center_dot}2D{sub 2}O

Abstract

We report neutron diffraction experiments on the light-induced metastable state SI in single crystals of Na{sub 2}[Fe(CN){sub 5}NO]{center_dot}2D{sub 2}O. It is shown that the metastable state SI corresponds to a linkage isomer of the NO group, the so-called isonitrosyl configuration where the NO ligand is oxygen bound to the central iron atom.

Authors:
 [1];  [2];  [3];  [4];  [5]; ;  [6]
  1. Institut fuer Experimentalphysik, Universitaet Wien, Boltzmanngasse 5, A-1090 Wien (Austria)
  2. (Germany)
  3. Institut fuer Mineralogie und Geochemie, Universitaet zu Koeln, Zuelpicherstrasse 49b, D-50674 Koeln (Germany)
  4. Laboratory for Neutron Scattering, ETH Zuerich and Paul Scherrer Institute, 5232 Villigen, PSI (Switzerland)
  5. Institute of Physics, Academy of Sciences of the Czech Republic, Na Slovance 2, 18221 Praha 8 (Czech Republic)
  6. Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, 3000 Bern 9 (Switzerland)
Publication Date:
OSTI Identifier:
20788156
Resource Type:
Journal Article
Resource Relation:
Journal Name: Physical Review. B, Condensed Matter and Materials Physics; Journal Volume: 73; Journal Issue: 17; Other Information: DOI: 10.1103/PhysRevB.73.174108; (c) 2006 The American Physical Society; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; ATOMS; CYANIDES; IRON COMPOUNDS; ISOMERS; LIGANDS; METASTABLE STATES; MONOCRYSTALS; NEUTRON DIFFRACTION; NITRIC OXIDE; SODIUM COMPOUNDS; VISIBLE RADIATION

Citation Formats

Schaniel, D., Institut fuer Mineralogie und Geochemie, Universitaet zu Koeln, Zuelpicherstrasse 49b, D-50674 Koeln, Woike, Th., Schefer, J., Petricek, V., Kraemer, K. W., and Guedel, H. U.. Neutron diffraction shows a photoinduced isonitrosyl linkage isomer in the metastable state SI of Na{sub 2}[Fe(CN){sub 5}NO]{center_dot}2D{sub 2}O. United States: N. p., 2006. Web. doi:10.1103/PHYSREVB.73.1.
Schaniel, D., Institut fuer Mineralogie und Geochemie, Universitaet zu Koeln, Zuelpicherstrasse 49b, D-50674 Koeln, Woike, Th., Schefer, J., Petricek, V., Kraemer, K. W., & Guedel, H. U.. Neutron diffraction shows a photoinduced isonitrosyl linkage isomer in the metastable state SI of Na{sub 2}[Fe(CN){sub 5}NO]{center_dot}2D{sub 2}O. United States. doi:10.1103/PHYSREVB.73.1.
Schaniel, D., Institut fuer Mineralogie und Geochemie, Universitaet zu Koeln, Zuelpicherstrasse 49b, D-50674 Koeln, Woike, Th., Schefer, J., Petricek, V., Kraemer, K. W., and Guedel, H. U.. Mon . "Neutron diffraction shows a photoinduced isonitrosyl linkage isomer in the metastable state SI of Na{sub 2}[Fe(CN){sub 5}NO]{center_dot}2D{sub 2}O". United States. doi:10.1103/PHYSREVB.73.1.
@article{osti_20788156,
title = {Neutron diffraction shows a photoinduced isonitrosyl linkage isomer in the metastable state SI of Na{sub 2}[Fe(CN){sub 5}NO]{center_dot}2D{sub 2}O},
author = {Schaniel, D. and Institut fuer Mineralogie und Geochemie, Universitaet zu Koeln, Zuelpicherstrasse 49b, D-50674 Koeln and Woike, Th. and Schefer, J. and Petricek, V. and Kraemer, K. W. and Guedel, H. U.},
abstractNote = {We report neutron diffraction experiments on the light-induced metastable state SI in single crystals of Na{sub 2}[Fe(CN){sub 5}NO]{center_dot}2D{sub 2}O. It is shown that the metastable state SI corresponds to a linkage isomer of the NO group, the so-called isonitrosyl configuration where the NO ligand is oxygen bound to the central iron atom.},
doi = {10.1103/PHYSREVB.73.1},
journal = {Physical Review. B, Condensed Matter and Materials Physics},
number = 17,
volume = 73,
place = {United States},
year = {Mon May 01 00:00:00 EDT 2006},
month = {Mon May 01 00:00:00 EDT 2006}
}