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Title: Candidate molecular ions for an electron electric dipole moment experiment

Journal Article · · Physical Review. A
DOI:https://doi.org/10.1103/PHYSREVA.73.0· OSTI ID:20787436
; ;  [1]
  1. Department of Physics, JILA, National Institute of Standards and Technology and University of Colorado, Boulder, Colorado 80309-0440 (United States)

This paper is a theoretical work in support of a newly proposed experiment [R. Stutz and E. Cornell, Bull. Am. Soc. Phys. 89, 76 (2004)] that promises greater sensitivity to measurements of the electron's electric dipole moment (EDM) based on the trapping of molecular ions. Such an experiment requires the choice of a suitable molecule that is both experimentally feasible and possesses an expectation of a reasonable EDM signal. We find that the molecular ions PtH{sup +} and HfH{sup +} are both suitable candidates in their low-lying {sup 3}{delta} states. In particular, we anticipate that the effective electric fields generated inside these molecules are approximately 73 and -17 GV/cm, respectively. As a byproduct of this discussion, we also explain how to make estimates of the size of the effective electric field acting in a molecule, using commercially available nonrelativistic molecular structure software.

OSTI ID:
20787436
Journal Information:
Physical Review. A, Vol. 73, Issue 6; Other Information: DOI: 10.1103/PhysRevA.73.062108; (c) 2006 The American Physical Society; Country of input: International Atomic Energy Agency (IAEA); ISSN 1050-2947
Country of Publication:
United States
Language:
English