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Title: Solvothermal synthesis and removal capacity for hydrogen chloride gas of Zn(OH)(NO{sub 3}) with a rare (10,3)-d net

Abstract

A basic zinc nitrate, [Zn(OH)(NO{sub 3})]{sub n} with a novel framework reported herein is prepared by solvothermal synthesis, and holds a rare three-dimensional (10,3)-d net called by Wells. It crystallizes in orthorhombic, space group, Pna2{sub 1} (No. 33), a=9.148(3)A, b=7.596(3)A, c=5.500(2)A, Z=4, V=382.2(2)A{sup 3}, {rho}{sub calcd}=2.509Mg/m{sup 3}, {mu}=6.290mm{sup -1}, 3.49<{theta}<27.51, T=293K, R{sub 1}=0.029, wR{sub 2}=0.0773 for 697 (I>2{sigma}(I)) of 1728 [R{sub (int)}=0.0246] unique reflections and 59 parameters. GOF=1.073. Interestingly this basic zinc nitrate, [Zn(OH)(NO{sub 3})]{sub n} behaves well at removal capacity for hydrogen chloride gas, 20.3g HCl/100g, and its framework is not destroyed yet. This adsorption character may be useful for the removal of toxic gases in the environment.

Authors:
 [1];  [2];  [2];  [3];  [3];  [2];  [4];  [5]
  1. Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012 (China) and Department of Chemistry, Fudan University, Shanghai 200433 (China). E-mail: jinyusun@jlu.edu.cn
  2. Department of Chemistry, Fudan University, Shanghai 200433 (China)
  3. Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012 (China)
  4. Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012 (China). E-mail: sqiu@mail.jlu.edu.cn
  5. Department of Chemistry, Fudan University, Shanghai 200433 (China). E-mail: dyzhao@fudan.edu.cn
Publication Date:
OSTI Identifier:
20784979
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 179; Journal Issue: 4; Other Information: DOI: 10.1016/j.jssc.2006.01.039; PII: S0022-4596(06)00038-7; Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ADSORPTION; HYDROCHLORIC ACID; ORTHORHOMBIC LATTICES; SPACE GROUPS; SYNTHESIS; ZINC NITRATES

Citation Formats

Sun Jinyu, Zhou Yaming, Chen Zhenxia, Zhu Guangshan, Fang Qianrong, Yang Rongjing, Qiu Shilun, and Zhao Dongyuan. Solvothermal synthesis and removal capacity for hydrogen chloride gas of Zn(OH)(NO{sub 3}) with a rare (10,3)-d net. United States: N. p., 2006. Web.
Sun Jinyu, Zhou Yaming, Chen Zhenxia, Zhu Guangshan, Fang Qianrong, Yang Rongjing, Qiu Shilun, & Zhao Dongyuan. Solvothermal synthesis and removal capacity for hydrogen chloride gas of Zn(OH)(NO{sub 3}) with a rare (10,3)-d net. United States.
Sun Jinyu, Zhou Yaming, Chen Zhenxia, Zhu Guangshan, Fang Qianrong, Yang Rongjing, Qiu Shilun, and Zhao Dongyuan. Sat . "Solvothermal synthesis and removal capacity for hydrogen chloride gas of Zn(OH)(NO{sub 3}) with a rare (10,3)-d net". United States. doi:.
@article{osti_20784979,
title = {Solvothermal synthesis and removal capacity for hydrogen chloride gas of Zn(OH)(NO{sub 3}) with a rare (10,3)-d net},
author = {Sun Jinyu and Zhou Yaming and Chen Zhenxia and Zhu Guangshan and Fang Qianrong and Yang Rongjing and Qiu Shilun and Zhao Dongyuan},
abstractNote = {A basic zinc nitrate, [Zn(OH)(NO{sub 3})]{sub n} with a novel framework reported herein is prepared by solvothermal synthesis, and holds a rare three-dimensional (10,3)-d net called by Wells. It crystallizes in orthorhombic, space group, Pna2{sub 1} (No. 33), a=9.148(3)A, b=7.596(3)A, c=5.500(2)A, Z=4, V=382.2(2)A{sup 3}, {rho}{sub calcd}=2.509Mg/m{sup 3}, {mu}=6.290mm{sup -1}, 3.49<{theta}<27.51, T=293K, R{sub 1}=0.029, wR{sub 2}=0.0773 for 697 (I>2{sigma}(I)) of 1728 [R{sub (int)}=0.0246] unique reflections and 59 parameters. GOF=1.073. Interestingly this basic zinc nitrate, [Zn(OH)(NO{sub 3})]{sub n} behaves well at removal capacity for hydrogen chloride gas, 20.3g HCl/100g, and its framework is not destroyed yet. This adsorption character may be useful for the removal of toxic gases in the environment.},
doi = {},
journal = {Journal of Solid State Chemistry},
number = 4,
volume = 179,
place = {United States},
year = {Sat Apr 15 00:00:00 EDT 2006},
month = {Sat Apr 15 00:00:00 EDT 2006}
}