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Title: Two novel 3-D coordination polymers based on isonicotinic acid: Syntheses, crystal structures and fluorescence

Abstract

The hydrothermal reactions of isonicotinic acid (HIso) and metal salts yielded two novel 3-D coordination polymers {l_brace}[Cu{sub 4}(Iso){sub 4}({mu} {sub 3}-O){sub 2}(C{sub 2}H{sub 5}OH){sub 2}].2C{sub 2}H{sub 5}OH.C{sub 2}H{sub 6}N{sub 4}{r_brace} {sub n} (1), {l_brace}[Cd(Iso){sub 2}(H{sub 2}O)].OHCCHO{r_brace} {sub n} (2), in which 1 was constructed from 32-membered rings and 3-D interpenetrating network of 2 from 42-membered rings. The fluorescent characterizations show the emissions at 565 nm for 1 and 440 nm for 2 possibly assigned to LMCT and IL, respectively.

Authors:
 [1];  [2];  [3]
  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China). E-mail: bliu_1203@yahoo.com.cn
  2. Department of Chemistry, Sungkyunkwan University, Suwon 440-746 (Korea, Republic of)
  3. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China)
Publication Date:
OSTI Identifier:
20784933
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 179; Journal Issue: 3; Other Information: DOI: 10.1016/j.jssc.2005.12.012; PII: S0022-4596(05)00603-1; Copyright (c) 2005 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CADMIUM COMPLEXES; COPPER COMPLEXES; CRYSTAL STRUCTURE; FLUORESCENCE; POLYMERS; SYNTHESIS

Citation Formats

Liu Bing, Xu Ling, and Guo Guocong. Two novel 3-D coordination polymers based on isonicotinic acid: Syntheses, crystal structures and fluorescence. United States: N. p., 2006. Web.
Liu Bing, Xu Ling, & Guo Guocong. Two novel 3-D coordination polymers based on isonicotinic acid: Syntheses, crystal structures and fluorescence. United States.
Liu Bing, Xu Ling, and Guo Guocong. Wed . "Two novel 3-D coordination polymers based on isonicotinic acid: Syntheses, crystal structures and fluorescence". United States. doi:.
@article{osti_20784933,
title = {Two novel 3-D coordination polymers based on isonicotinic acid: Syntheses, crystal structures and fluorescence},
author = {Liu Bing and Xu Ling and Guo Guocong},
abstractNote = {The hydrothermal reactions of isonicotinic acid (HIso) and metal salts yielded two novel 3-D coordination polymers {l_brace}[Cu{sub 4}(Iso){sub 4}({mu} {sub 3}-O){sub 2}(C{sub 2}H{sub 5}OH){sub 2}].2C{sub 2}H{sub 5}OH.C{sub 2}H{sub 6}N{sub 4}{r_brace} {sub n} (1), {l_brace}[Cd(Iso){sub 2}(H{sub 2}O)].OHCCHO{r_brace} {sub n} (2), in which 1 was constructed from 32-membered rings and 3-D interpenetrating network of 2 from 42-membered rings. The fluorescent characterizations show the emissions at 565 nm for 1 and 440 nm for 2 possibly assigned to LMCT and IL, respectively.},
doi = {},
journal = {Journal of Solid State Chemistry},
number = 3,
volume = 179,
place = {United States},
year = {Wed Mar 15 00:00:00 EST 2006},
month = {Wed Mar 15 00:00:00 EST 2006}
}