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Title: Design and synthesis of four coordination polymers generated from 2,2'-biquinoline-4,4'-dicarboxylate and aromatic bidentate ligands

Abstract

Four coordination polymers [Zn(bqdc)(phen)]{sub n} (1), [Zn(bqdc)(bpy)(H{sub 2}O)]{sub n} (2), [Mn(bqdc)(bpy)(H{sub 2}O){sub 2}]{sub n} (3) and [Mn(bqdc)(phen)(H{sub 2}O){sub 2}]{sub n} (4) (H{sub 2}bqdc=2,2'-biquinoline-4,4'-dicarboxylic acid, phen=1,10-phenanthroline and bpy=2,2'-bipyridyl) have been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction. Crystal data for 1: monoclinic system, C2/c, a=14.141(3)A, b=10.021(2)A, c=18.511(4)A, {beta}=103.78(3){sup o}, V=2547.6(9)A{sup 3}, Z=4. Crystal data for 2: monoclinic system, p2{sub 1}/n, a=13.656(3)A, b=10.015(2)A, c=19.127(4)A, {beta}=107.13(7){sup o}, V=2500.1(9)A{sup 3}, Z=4. Crystal data for 3: monoclinic system, C2/c, a=14.5050(8)A, b=15.1932(8)A, c=12.7549(6)A, {beta}=116.8010(11){sup o}, V=2508.9(2)A{sup 3}, Z=4. Crystal data for 4: monoclinic system, C2/c, a=14.1732(17)A, b=16.115(3)A, c=12.809(3)A, {beta}=117.04(3){sup o}, V=2605.7(8)A{sup 3}, Z=4. Single helix-like chains exist in 1. The supramolecular structure of 1 exhibits extended two-dimensional network while 2-4 display extended three-dimensional architectures based on interchain hydrogen bonding and {pi}-{pi} interactions. Compounds 1 and 2 show blue photoluminescence under UV light suggesting that they may be employed to develop luminescent materials. Compounds 3 and 4 show interesting magnetic behaviors.

Authors:
 [1];  [1];  [1];  [1];  [1];  [1];  [1];  [2]
  1. Key Laboratory for Supramolecular Structure and Materials of Ministry of Education, College of Chemistry, Jilin University, Changchun 130012 (China)
  2. Key Laboratory for Supramolecular Structure and Materials of Ministry of Education, College of Chemistry, Jilin University, Changchun 130012 (China). E-mail: yuewang@jlu.edu.cn
Publication Date:
OSTI Identifier:
20784881
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 179; Journal Issue: 2; Other Information: DOI: 10.1016/j.jssc.2005.11.003; PII: S0022-4596(05)00515-3; Copyright (c) 2005 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; LIGANDS; MAGNETISM; MANGANESE COMPLEXES; MONOCLINIC LATTICES; MONOCRYSTALS; PHOTOLUMINESCENCE; POLYMERS; SYNTHESIS; ULTRAVIOLET RADIATION; X-RAY DIFFRACTION; ZINC COMPLEXES

Citation Formats

Ye Junwei, Zhang Ping, Ye Kaiqi, Zhang Hongyu, Jiang Shimei, Ye Ling, Yang Guangdi, and Wang Yue. Design and synthesis of four coordination polymers generated from 2,2'-biquinoline-4,4'-dicarboxylate and aromatic bidentate ligands. United States: N. p., 2006. Web.
Ye Junwei, Zhang Ping, Ye Kaiqi, Zhang Hongyu, Jiang Shimei, Ye Ling, Yang Guangdi, & Wang Yue. Design and synthesis of four coordination polymers generated from 2,2'-biquinoline-4,4'-dicarboxylate and aromatic bidentate ligands. United States.
Ye Junwei, Zhang Ping, Ye Kaiqi, Zhang Hongyu, Jiang Shimei, Ye Ling, Yang Guangdi, and Wang Yue. Wed . "Design and synthesis of four coordination polymers generated from 2,2'-biquinoline-4,4'-dicarboxylate and aromatic bidentate ligands". United States. doi:.
@article{osti_20784881,
title = {Design and synthesis of four coordination polymers generated from 2,2'-biquinoline-4,4'-dicarboxylate and aromatic bidentate ligands},
author = {Ye Junwei and Zhang Ping and Ye Kaiqi and Zhang Hongyu and Jiang Shimei and Ye Ling and Yang Guangdi and Wang Yue},
abstractNote = {Four coordination polymers [Zn(bqdc)(phen)]{sub n} (1), [Zn(bqdc)(bpy)(H{sub 2}O)]{sub n} (2), [Mn(bqdc)(bpy)(H{sub 2}O){sub 2}]{sub n} (3) and [Mn(bqdc)(phen)(H{sub 2}O){sub 2}]{sub n} (4) (H{sub 2}bqdc=2,2'-biquinoline-4,4'-dicarboxylic acid, phen=1,10-phenanthroline and bpy=2,2'-bipyridyl) have been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction. Crystal data for 1: monoclinic system, C2/c, a=14.141(3)A, b=10.021(2)A, c=18.511(4)A, {beta}=103.78(3){sup o}, V=2547.6(9)A{sup 3}, Z=4. Crystal data for 2: monoclinic system, p2{sub 1}/n, a=13.656(3)A, b=10.015(2)A, c=19.127(4)A, {beta}=107.13(7){sup o}, V=2500.1(9)A{sup 3}, Z=4. Crystal data for 3: monoclinic system, C2/c, a=14.5050(8)A, b=15.1932(8)A, c=12.7549(6)A, {beta}=116.8010(11){sup o}, V=2508.9(2)A{sup 3}, Z=4. Crystal data for 4: monoclinic system, C2/c, a=14.1732(17)A, b=16.115(3)A, c=12.809(3)A, {beta}=117.04(3){sup o}, V=2605.7(8)A{sup 3}, Z=4. Single helix-like chains exist in 1. The supramolecular structure of 1 exhibits extended two-dimensional network while 2-4 display extended three-dimensional architectures based on interchain hydrogen bonding and {pi}-{pi} interactions. Compounds 1 and 2 show blue photoluminescence under UV light suggesting that they may be employed to develop luminescent materials. Compounds 3 and 4 show interesting magnetic behaviors.},
doi = {},
journal = {Journal of Solid State Chemistry},
number = 2,
volume = 179,
place = {United States},
year = {Wed Feb 15 00:00:00 EST 2006},
month = {Wed Feb 15 00:00:00 EST 2006}
}