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Title: An open-framework three-dimensional indium oxalate: [In(OH)(C{sub 2}O{sub 4})(H{sub 2}O)]{sub 3}.H{sub 2}O

Abstract

By hydrothermal reaction of In{sub 2}O{sub 3} with H{sub 2}C{sub 2}O{sub 4}.2H{sub 2}O in the presence of H{sub 3}BO{sub 3} at 155 deg. C, an open-framework three-dimensional indium oxalate of formula [In(OH)(C{sub 2}O{sub 4})(H{sub 2}O)]{sub 3}.H{sub 2}O (1) has been obtained. The compound crystallizes in the trigonal system, space group R3c with a=18.668(3)A, c=7.953(2)A, V=2400.3(7)A{sup 3}, Z=6, R{sub 1}=0.0352 at 298K. The small pores in 1 are filled with water molecules. It loses its filled water at about 180 deg. C without the change of structure, then the bounded water at 260 deg. C, and completely decompounds at 324 deg. C. The residue is confirmed to be In{sub 2}O{sub 3}.

Authors:
 [1];  [2];  [1];  [1];  [1]
  1. State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China)
  2. State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China). E-mail: liguobao@pku.edu.cn
Publication Date:
OSTI Identifier:
20784817
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 178; Journal Issue: 12; Other Information: DOI: 10.1016/j.jssc.2005.09.025; PII: S0022-4596(05)00427-5; Copyright (c) 2005 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; BORIC ACID; INDIUM OXIDES; OXALATES; SPACE GROUPS; TEMPERATURE RANGE 0400-1000 K; TRIGONAL LATTICES

Citation Formats

Yang Sihai, Li Guobao, Tian Shujian, Liao Fuhui, and Lin Jianhua. An open-framework three-dimensional indium oxalate: [In(OH)(C{sub 2}O{sub 4})(H{sub 2}O)]{sub 3}.H{sub 2}O. United States: N. p., 2005. Web. doi:10.1016/j.jssc.2005.09.025.
Yang Sihai, Li Guobao, Tian Shujian, Liao Fuhui, & Lin Jianhua. An open-framework three-dimensional indium oxalate: [In(OH)(C{sub 2}O{sub 4})(H{sub 2}O)]{sub 3}.H{sub 2}O. United States. doi:10.1016/j.jssc.2005.09.025.
Yang Sihai, Li Guobao, Tian Shujian, Liao Fuhui, and Lin Jianhua. Thu . "An open-framework three-dimensional indium oxalate: [In(OH)(C{sub 2}O{sub 4})(H{sub 2}O)]{sub 3}.H{sub 2}O". United States. doi:10.1016/j.jssc.2005.09.025.
@article{osti_20784817,
title = {An open-framework three-dimensional indium oxalate: [In(OH)(C{sub 2}O{sub 4})(H{sub 2}O)]{sub 3}.H{sub 2}O},
author = {Yang Sihai and Li Guobao and Tian Shujian and Liao Fuhui and Lin Jianhua},
abstractNote = {By hydrothermal reaction of In{sub 2}O{sub 3} with H{sub 2}C{sub 2}O{sub 4}.2H{sub 2}O in the presence of H{sub 3}BO{sub 3} at 155 deg. C, an open-framework three-dimensional indium oxalate of formula [In(OH)(C{sub 2}O{sub 4})(H{sub 2}O)]{sub 3}.H{sub 2}O (1) has been obtained. The compound crystallizes in the trigonal system, space group R3c with a=18.668(3)A, c=7.953(2)A, V=2400.3(7)A{sup 3}, Z=6, R{sub 1}=0.0352 at 298K. The small pores in 1 are filled with water molecules. It loses its filled water at about 180 deg. C without the change of structure, then the bounded water at 260 deg. C, and completely decompounds at 324 deg. C. The residue is confirmed to be In{sub 2}O{sub 3}.},
doi = {10.1016/j.jssc.2005.09.025},
journal = {Journal of Solid State Chemistry},
number = 12,
volume = 178,
place = {United States},
year = {Thu Dec 15 00:00:00 EST 2005},
month = {Thu Dec 15 00:00:00 EST 2005}
}