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Title: Synthesis and characterization of K(In{sub 6.5}Ag{sub 6.5})

Abstract

The pseudo-ternary compound K(In{sub 6.5}Ag{sub 6.5}) has been synthesized from the elements and either excess indium or excess indium and silver. Single-crystal X-ray diffraction shows that K(In{sub 6.5}Ag{sub 6.5}) crystallizes in the cubic space group Fm3-bar c, a=13.5101(6)A(Z=8), and adopts the NaZn{sub 13} structure type (R{sub 1}=0.0338). Four probe resistivity measurements show K(In{sub 6.5}Ag{sub 6.5}) to be a metal with a room temperature resistivity of 81{mu}{omega}cm and a weak temperature dependence.

Authors:
 [1];  [2];  [3]
  1. Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853 (United States)
  2. Department of Physics, Cornell University, Ithaca, NY 14853 (United States)
  3. Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853 (United States). E-mail: fjd3@cornell.edu
Publication Date:
OSTI Identifier:
20784789
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 178; Journal Issue: 11; Other Information: DOI: 10.1016/j.jssc.2005.09.004; PII: S0022-4596(05)00405-6; Copyright (c) 2005 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CUBIC LATTICES; ELECTRIC CONDUCTIVITY; INDIUM; INDIUM COMPOUNDS; MONOCRYSTALS; POTASSIUM COMPOUNDS; SILVER; SILVER COMPOUNDS; SPACE GROUPS; SYNTHESIS; TEMPERATURE DEPENDENCE; TEMPERATURE RANGE 0273-0400 K; X-RAY DIFFRACTION

Citation Formats

Bailey, Mark S., McGuire, Michael A., and DiSalvo, Francis J. Synthesis and characterization of K(In{sub 6.5}Ag{sub 6.5}). United States: N. p., 2005. Web. doi:10.1016/j.jssc.2005.09.004.
Bailey, Mark S., McGuire, Michael A., & DiSalvo, Francis J. Synthesis and characterization of K(In{sub 6.5}Ag{sub 6.5}). United States. doi:10.1016/j.jssc.2005.09.004.
Bailey, Mark S., McGuire, Michael A., and DiSalvo, Francis J. Tue . "Synthesis and characterization of K(In{sub 6.5}Ag{sub 6.5})". United States. doi:10.1016/j.jssc.2005.09.004.
@article{osti_20784789,
title = {Synthesis and characterization of K(In{sub 6.5}Ag{sub 6.5})},
author = {Bailey, Mark S. and McGuire, Michael A. and DiSalvo, Francis J.},
abstractNote = {The pseudo-ternary compound K(In{sub 6.5}Ag{sub 6.5}) has been synthesized from the elements and either excess indium or excess indium and silver. Single-crystal X-ray diffraction shows that K(In{sub 6.5}Ag{sub 6.5}) crystallizes in the cubic space group Fm3-bar c, a=13.5101(6)A(Z=8), and adopts the NaZn{sub 13} structure type (R{sub 1}=0.0338). Four probe resistivity measurements show K(In{sub 6.5}Ag{sub 6.5}) to be a metal with a room temperature resistivity of 81{mu}{omega}cm and a weak temperature dependence.},
doi = {10.1016/j.jssc.2005.09.004},
journal = {Journal of Solid State Chemistry},
number = 11,
volume = 178,
place = {United States},
year = {Tue Nov 15 00:00:00 EST 2005},
month = {Tue Nov 15 00:00:00 EST 2005}
}