Two-dimensional metal-organic framework constructed from 4,4'-bipydine and 1,2,4-benzenetricarboxylate: Synthesis, structure and magnetic properties

doi:10.1016/j.jssc.2005.08.014

Title: Two-dimensional metal-organic framework constructed from 4,4'-bipydine and 1,2,4-benzenetricarboxylate: Synthesis, structure and magnetic properties

Full Record
Other Related Research

Abstract

Two new copper coordination polymers generated from mixed organic ligands 4,4'-bipydine and 1,2,4-benzenetricarboxylate [Cu{sub 3}(1,2,4-BTC){sub 2}(4,4'-bipy)(H{sub 2}O){sub 4}] 1 and [Cu(1,2,4-HBTC)(4,4'-bipy)] 2 (1,2,4-BTC=1,2,4-benzenetricarboxylate) have been prepared hydrothermally and characterized by single crystal X-ray diffraction. Compound 1 crystallizes in the noncentrosymmetric space group Fdd2, with a=19.004(3)A, b=26.711(4)A, c=11.0770(15)A, V=5622.8(14)A{sup 3}, and Z=8. Its structure contains two different one-dimensional (1-D) chains for the Cu ions, namely [Cu{sub 2}(1,2,4-BTC){sub 2}]{sub n}{sup 2n-} and [Cu(4,4{sup '}-bipy)]{sub n}{sup 2n+}; the carboxylate of 1,2,4-BTC ligands links the two different 1-D chains into an interesting steplike neutral framework. Compound 2 crystallizes in the monoclinic space group P2{sub 1}/n, with a=9.9806(8), b=16.5512(16), c=11.3109(7)A, {beta}=99.375(5){sup o}, V=1843.5(3)A{sup 3}, Z=4. Its structure contains novel paddle-wheel clusters Cu{sub 2}(CO{sub 2}){sub 4}(4,4'-bipy){sub 2} as SBUs which are further linked by monoprotonated 1,2,4-BTC ligands into a 2-D neutral framework. The magnetic behaviors of both compounds have been studied.

Authors:

Wang Lei ^[1]; Yang Ming ^[1]; Shi Zhan ^[1]; Chen Yan ^[1]; Feng Shouhua ^[2]

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China)
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China). E-mail: shfeng@mail.jlu.edu.cn

Publication Date:: Tue Nov 15 00:00:00 EST 2005

OSTI Identifier:: 20784770

Resource Type:: Journal Article

Resource Relation:: Journal Name: Journal of Solid State Chemistry; Journal Volume: 178; Journal Issue: 11; Other Information: DOI: 10.1016/j.jssc.2005.08.014; PII: S0022-4596(05)00378-6; Copyright (c) 2005 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA)

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; COPPER COMPLEXES; COPPER IONS; HYDROTHERMAL SYNTHESIS; LIGANDS; MAGNETIC PROPERTIES; MONOCLINIC LATTICES; MONOCRYSTALS; ORTHORHOMBIC LATTICES; SPACE GROUPS; X-RAY DIFFRACTION

Citation Formats


                    Wang Lei, Yang Ming, Shi Zhan, Chen Yan, and Feng Shouhua. Two-dimensional metal-organic framework constructed from 4,4'-bipydine and 1,2,4-benzenetricarboxylate: Synthesis, structure and magnetic properties.  United States: N. p., 2005. 
        Web.  doi:10.1016/j.jssc.2005.08.014.

Copy to clipboard


                    Wang Lei, Yang Ming, Shi Zhan, Chen Yan, & Feng Shouhua. Two-dimensional metal-organic framework constructed from 4,4'-bipydine and 1,2,4-benzenetricarboxylate: Synthesis, structure and magnetic properties.  United States.  doi:10.1016/j.jssc.2005.08.014.

Copy to clipboard


                    Wang Lei, Yang Ming, Shi Zhan, Chen Yan, and Feng Shouhua. Tue .  
        "Two-dimensional metal-organic framework constructed from 4,4'-bipydine and 1,2,4-benzenetricarboxylate: Synthesis, structure and magnetic properties".  United States.  
        doi:10.1016/j.jssc.2005.08.014.

Copy to clipboard


                    
@article{osti_20784770,

  title        = {Two-dimensional metal-organic framework constructed from 4,4'-bipydine and 1,2,4-benzenetricarboxylate: Synthesis, structure and magnetic properties},

  author       = {Wang Lei and Yang Ming and Shi Zhan and Chen Yan and Feng Shouhua},

  abstractNote = {Two new copper coordination polymers generated from mixed organic ligands 4,4'-bipydine and 1,2,4-benzenetricarboxylate [Cu{sub 3}(1,2,4-BTC){sub 2}(4,4'-bipy)(H{sub 2}O){sub 4}] 1 and [Cu(1,2,4-HBTC)(4,4'-bipy)] 2 (1,2,4-BTC=1,2,4-benzenetricarboxylate) have been prepared hydrothermally and characterized by single crystal X-ray diffraction. Compound 1 crystallizes in the noncentrosymmetric space group Fdd2, with a=19.004(3)A, b=26.711(4)A, c=11.0770(15)A, V=5622.8(14)A{sup 3}, and Z=8. Its structure contains two different one-dimensional (1-D) chains for the Cu ions, namely [Cu{sub 2}(1,2,4-BTC){sub 2}]{sub n}{sup 2n-} and [Cu(4,4{sup '}-bipy)]{sub n}{sup 2n+}; the carboxylate of 1,2,4-BTC ligands links the two different 1-D chains into an interesting steplike neutral framework. Compound 2 crystallizes in the monoclinic space group P2{sub 1}/n, with a=9.9806(8), b=16.5512(16), c=11.3109(7)A, {beta}=99.375(5){sup o}, V=1843.5(3)A{sup 3}, Z=4. Its structure contains novel paddle-wheel clusters Cu{sub 2}(CO{sub 2}){sub 4}(4,4'-bipy){sub 2} as SBUs which are further linked by monoprotonated 1,2,4-BTC ligands into a 2-D neutral framework. The magnetic behaviors of both compounds have been studied.},

  doi          = {10.1016/j.jssc.2005.08.014},

  journal      = {Journal of Solid State Chemistry},

  number       = 11,

  volume       = 178,

  place        = {United States},

  year         = {Tue Nov 15 00:00:00 EST 2005},

  month        = {Tue Nov 15 00:00:00 EST 2005}

}

Copy to clipboard

Journal Article:

DOI: 10.1016/j.jssc.2005.08.014

Other availability

Find in Google Scholar

Search WorldCat to find libraries that may hold this journal

Save / Share:

Export Metadata

Save to My Library

Similar records in OSTI.GOV collections:

A two-fold interpenetrating 3D metal-organic framework material constructed from helical chains linked via 4,4'-H{sub 2}bpz fragments

Journal Article Xie Yiming ; College of Materials Science and Engineering, Huaqiao University, the Key Laboratory for Functional Materials of Fujian Higher Education, Quanzhou, Fujian 362021 ; Zhao Zhenguo ; ... - Journal of Solid State Chemistry

A 3-connected dia-f-type metal-organic framework compound {l_brace}[Ag(L){sub 3/2}H{sub 2}PO{sub 4}]{r_brace}{sub n} (1) has been synthesized by self-assembly of 4,4'-H{sub 2}bpz (L=4,4'-H{sub 2}bpz=3,3',5,5'-tetramethyl-4,4'-bipyrazole) and Ag{sub 4}P{sub 2}O{sub 7} under hydrothermal conditions. It crystallizes in the tetragonal space group I4{sub 1}/acd with a=21.406(4) A, b=21.406(4) A, c=36.298(8) A, Z=32. X-ray single-crystal diffraction reveals that 1 has a three-dimensional framework with an unprecedented alternate left- and right-handed helices structure, featuring a non-uniform two-fold interpenetrated (4.14{sup 2}) net. Photoluminescent investigation reveals that the title compound displays interesting emissions in a wide region, which shows that the title compound may be a good potential candidatemore »« less
Microporous metal organic framework [M{sub 2}(hfipbb){sub 2}(ted)] (M=Zn, Co; H{sub 2}hfipbb=4,4-(hexafluoroisopropylidene)-bis(benzoic acid); ted=triethylenediamine): Synthesis, structure analysis, pore characterization, small gas adsorption and CO{sub 2}/N{sub 2} separation properties

Journal Article Xu, William W. ; Princeton High School, 151 Moore Street, Princeton, NJ 08540 ; Pramanik, Sanhita ; ... - Journal of Solid State Chemistry

Carbon dioxide is a greenhouse gas that is a major contributor to global warming. Developing methods that can effectively capture CO{sub 2} is the key to reduce its emission to the atmosphere. Recent research shows that microporous metal organic frameworks (MOFs) are emerging as a promising family of adsorbents that may be promising for use in adsorption based capture and separation of CO{sub 2} from power plant waste gases. In this work we report the synthesis, crystal structure analysis and pore characterization of two microporous MOF structures, [M{sub 2}(hfipbb){sub 2}(ted)] (M=Zn (1), Co (2); H{sub 2}hfipbb=4,4-(hexafluoroisopropylidene)-bis(benzoic acid); ted=triethylenediamine). The CO{submore »« less
DOI: 10.1016/J.JSSC.2012.12.030
[Cu{sub 4}OCl{sub 6}(DABCO){sub 2}].0.5DABCO.4CH{sub 3}OH ('MFU-5'): Modular synthesis of a zeolite-like metal-organic framework constructed from tetrahedral {l_brace}Cu{sub 4}OCl{sub 6}{r_brace} secondary building units and linear organic linkers

Journal Article Liu Yingya ; Grzywa, Maciej ; Weil, Matthias ; ... - Journal of Solid State Chemistry

A novel metal-organic framework (MOF) based on a tetranuclear copper cluster and a linear organic ligand formulated as [Cu{sub 4}OCl{sub 6}(DABCO){sub 2}].0.5DABCO.4CH{sub 3}OH (denoted as MFU-5, MFU=Metal-Organic Framework, Ulm University; DABCO=1,4-diazabicyclo[2.2.2]octane), was prepared via solvothermal synthesis. In contrast with common MOF synthesis strategies, MFU-5 is assembled from pre-defined molecular secondary building units, i.e. {l_brace}Cu{sub 4}OCl{sub 6}{r_brace} moieties, which become the nodes of the coordination framework. The title compound was characterized by single crystal X-ray diffraction, variable temperature powder diffraction (VT-XRPD), thermal analysis, as well as IR- and UV/Vis spectroscopy. Crystal data for MFU-5: hexagonal, P6/mcc (no. 192), a=25.645(9), c=17.105(11) A,more »« less
A three-dimensional porous metal-organic framework constructed from two-dimensional sheets via interdigitation exhibiting dynamic features.

Journal Article Ma, S. ; Sun, D. ; Forster, P. M. ; ... - Inorg. Chem.

A three-dimensional porous metal-organic framework (PCN-18) was constructed through interdigitating two-dimensional grid sheets composed of 4,4{prime}-(anthracene-9,10-diyl)dibenzoate and copper paddlewheel secondary building units, and its dynamic features were evidenced by gas sorption isotherms.
DOI: 10.1021/ic900372t
Hydrothermal synthesis, crystal structure and properties of a 3D-framework polyoxometalate assembly: [Ag(4,4'-bipy)](OH){l_brace}[Ag(4,4'-bipy)]{sub 2}[PAgW{sub 12}O{sub 40}]{r_brace}.3.5H{sub 2}O

Journal Article Chen Jianxin ; Lan Tingyan ; Huang Yuanbiao ; ... - Journal of Solid State Chemistry

A 3D framework assembly based on the Keggin tungstophosphate POM with silver (I) transition metal and N-ligand organic moiety and of formula [Ag(4,4'-bipy)](OH){l_brace}[Ag(4,4'-bipy)]{sub 2}[PAgW{sub 12}O{sub 40}]{r_brace}.3.5H{sub 2}O (1) (bipy=bipyridine) has been synthesized by hydrothermal method and structurally characterized. The crystal of 1 belongs to triclinic, space group P-1, Mr=3857.27, a=10.2741(3)A, b=11.3723(4)A, c=14.0161(5)A, {alpha}=85.7249(5){sup o}, {beta}=72.8795(5){sup o}, {gamma}=79.9543(5){sup o}, V=1540.61(9)A{sup 3}, Z=1, D{sub calc}=4.158Mgm{sup -3}. The final statistics based on F{sup 2} are GOF=1.045, R{sub 1}=0.0326 and wR{sub 2}=0.0843 for I>2{sigma}(I). X-ray diffraction analysis revealed that the molecular structure of 1 consists of a neutral fragment {l_brace}[Ag{sup I}(4,4'-bipy)]{sub 2}[PAg{sup I}W{sup VI}{submore »« less
DOI: 10.1016/j.jssc.2006.03.017

Similar Records