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Title: Studies on lithium salts to mitigate ASR-induced expansion in new concrete: a critical review

Journal Article · · Cement and Concrete Research
 [1];  [1];  [1];  [2];  [3]
  1. Department of Civil Engineering, University of New Brunswick, PO Box 4400, Fredericton, NB E3B 5A3 (Canada)
  2. MRI Center, University of New Brunswick, PO Box 4400, Fredericton, NB E3B 5A3 (Canada)
  3. Department of Civil Engineering, University of Texas, Austin, TX 78712 (United States)

This paper provides a critical review of the research work conducted so far on the suppressive effects of lithium compounds on expansion due to alkali-silica reaction (ASR) in concrete and on the mechanism or mechanisms by which lithium inhibits the expansion. After a thorough examination of the existing literature regarding lithium salts in controlling ASR expansion, a summary of research findings is provided. It shows that all the lithium salts studied, including LiF, LiCl, LiBr, LiOH, LiOH.H{sub 2}O, LiNO{sub 3}, LiNO{sub 2}, Li{sub 2}CO{sub 3}, Li{sub 2}SO{sub 4}, Li{sub 2}HPO{sub 4}, and Li{sub 2}SiO{sub 3}, are effective in suppressing ASR expansion in new concrete, provided they are used at the appropriate dosages. Among these compounds, LiNO{sub 3} appears to be the most promising one. Although the mechanism(s) for the suppressive effects of lithium are not well understood, several mechanisms have been proposed. A detailed discussion about these existing mechanisms is provided in the paper. Finally, some recommendations for future studies are identified.

OSTI ID:
20706236
Journal Information:
Cement and Concrete Research, Vol. 35, Issue 9; Other Information: DOI: 10.1016/j.cemconres.2004.10.013; PII: S0008-8846(04)00450-8; Copyright (c) 2004 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA); ISSN 0008-8846
Country of Publication:
United States
Language:
English