Self-assembly of polyoxometalate clusters into a 3-D heterometallic framework via covalent bonding: synthesis, structure and characterization of Na{sub 4}[Nd{sub 8}(dipic){sub 12}(H{sub 2}O){sub 9}][Mo{sub 8}O{sub 26}].8H{sub 2}O
Journal Article
·
· Journal of Solid State Chemistry
- Department of Chemistry, Institute of Polyoxometalate Chemistry, Northeast Normal University, Changchun City, Jilin Province 130024 (China)
An unprecedented hybrid solid obtained by self-assembly of octamolybdate clusters into a three-dimensional alkali metal modified neodymium-organic heterometallic framework is described. Crystal data: monoclinic, space group P21/n, a=21.868(4)A, b=13.039(3)A, c=22.479(5)A, {beta}=98.90(3){sup o}; V=6332(2)A3; Z=2, R (final)=0.0474. The data were collected on a Rigaku R-AXIS RAPID IP diffractometer at 293K using graphite-monochromated MoK{alpha} radiation ({lambda}=0.71073A) and oscillation scans technique in the range of 1.98 deg. {theta}27.48 deg.
- OSTI ID:
- 20658214
- Journal Information:
- Journal of Solid State Chemistry, Vol. 177, Issue 11; Other Information: DOI: 10.1016/j.jssc.2004.08.007; PII: S0022-4596(04)00440-2; Copyright (c) 2004 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA); ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
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