Structural determination by single-molecule vibrational spectroscopy and microscopy: Contrast between copper and iron carbonyls
Abstract
A scanning tunneling microscope (STM) was used to synthesize Cu(CO), Fe(CO), Cu(CO){sub 2}, and Fe(CO){sub 2} from individual Cu atoms, Fe atoms, and CO molecules on a Ag(110) surface at 13 K. Inelastic electron tunneling spectroscopy and microscopy together with topographical imaging revealed contrasting bonding geometries for the single Cu and Fe carbonyl products. (c) 2000 The American Physical Society.
- Authors:
-
- Laboratory of Atomic and Solid State Physics and Cornell Center for Materials Research, Cornell University, Ithaca, New York 14853 (United States)
- Publication Date:
- OSTI Identifier:
- 20216884
- Resource Type:
- Journal Article
- Journal Name:
- Physical Review. B, Condensed Matter and Materials Physics
- Additional Journal Information:
- Journal Volume: 61; Journal Issue: 24; Other Information: PBD: 15 Jun 2000; Journal ID: ISSN 1098-0121
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; CARBONYLS; IRON COMPOUNDS; COPPER COMPOUNDS; SCANNING ELECTRON MICROSCOPY; TUNNELING; ELECTRON SPECTROSCOPY; CHEMICAL BONDS; SYNTHESIS; SURFACES; VIBRATIONAL STATES; MOLECULES; EXPERIMENTAL DATA
Citation Formats
Lee, H J, and Ho, W. Structural determination by single-molecule vibrational spectroscopy and microscopy: Contrast between copper and iron carbonyls. United States: N. p., 2000.
Web. doi:10.1103/PhysRevB.61.R16347.
Lee, H J, & Ho, W. Structural determination by single-molecule vibrational spectroscopy and microscopy: Contrast between copper and iron carbonyls. United States. https://doi.org/10.1103/PhysRevB.61.R16347
Lee, H J, and Ho, W. 2000.
"Structural determination by single-molecule vibrational spectroscopy and microscopy: Contrast between copper and iron carbonyls". United States. https://doi.org/10.1103/PhysRevB.61.R16347.
@article{osti_20216884,
title = {Structural determination by single-molecule vibrational spectroscopy and microscopy: Contrast between copper and iron carbonyls},
author = {Lee, H J and Ho, W},
abstractNote = {A scanning tunneling microscope (STM) was used to synthesize Cu(CO), Fe(CO), Cu(CO){sub 2}, and Fe(CO){sub 2} from individual Cu atoms, Fe atoms, and CO molecules on a Ag(110) surface at 13 K. Inelastic electron tunneling spectroscopy and microscopy together with topographical imaging revealed contrasting bonding geometries for the single Cu and Fe carbonyl products. (c) 2000 The American Physical Society.},
doi = {10.1103/PhysRevB.61.R16347},
url = {https://www.osti.gov/biblio/20216884},
journal = {Physical Review. B, Condensed Matter and Materials Physics},
issn = {1098-0121},
number = 24,
volume = 61,
place = {United States},
year = {Thu Jun 15 00:00:00 EDT 2000},
month = {Thu Jun 15 00:00:00 EDT 2000}
}
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