Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Enhanced Electron Transport in Nonconjugated Radical Oligomers Occurs by Tunneling

Journal Article · · Nano Letters

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
Air Force Office of Scientific Research (AFOSR)(United States Department of DefenseAir Force Office of Scientific Research (AFOSR)); Organic Materials Chemistry Program; Joint Center for Energy Storage Research (JCESR) - U.S. Department of Energy, Office of Science, Basic Energy Sciences(United States Department of Energy (DOE)); Research Instrumentation Center in the Department of Chemistry at Purdue University
OSTI ID:
2008437
Journal Information:
Nano Letters, Vol. 23, Issue 13
Country of Publication:
United States
Language:
English

References (53)

Stable organic radical polymers: synthesis and applications journal January 2016
Recent advances in the syntheses of radical-containing macromolecules journal March 2016
Persistent and Stable Organic Radicals: Design, Synthesis, and Applications journal February 2021
Organic Radical Polymers book January 2017
100th Anniversary of Macromolecular Science Viewpoint: Fundamentals for the Future of Macromolecular Nitroxide Radicals journal February 2020
Stable Radical Materials for Energy Applications journal June 2018
Electronic and Spintronic Open-Shell Macromolecules, Quo Vadis? journal January 2022
Nitroxide radical polymers – a versatile material class for high-tech applications journal January 2018
Nitroxide radical polymers for emerging plastic energy storage and organic electronics: fundamentals, materials, and applications journal January 2021
Large Magnetoresistance in Single-Radical Molecular Junctions journal August 2016
Design Considerations for Oligo( p -phenyleneethynylene) Organic Radicals in Molecular Junctions journal January 2021
Interplay between Magnetoresistance and Kondo Resonance in Radical Single-Molecule Junctions journal July 2022
Magnetic Fingerprints in an All-Organic Radical Molecular Break Junction journal October 2022
Conductance of a Molecular Junction journal October 1997
Single-Molecule Circuits with Well-Defined Molecular Conductance journal February 2006
Molecular-Scale Electronics: From Concept to Function journal March 2016
Single-Molecule Electron Transfer in Electrochemical Environments journal July 2008
Using automated synthesis to understand the role of side chains on molecular charge transport journal April 2022
Charge Transport in Sequence-Defined Conjugated Oligomers journal February 2020
Mapping Out the Nonconjugated Organic Radical Conductors via Chemical or Physical Pathways journal August 2022
The Environment-Dependent Behavior of the Blatter Radical at the Metal–Molecule Interface journal March 2019
Reversible Switching of Molecular Conductance in Viologens is Controlled by the Electrochemical Environment journal October 2021
Chemical control over the energy-level alignment in a two-terminal junction journal July 2016
Radical‐Enhanced Charge Transport in Single‐Molecule Phenothiazine Electrical Junctions journal September 2017
Redox‐Addressable Single‐Molecule Junctions Incorporating a Persistent Organic Radical** journal April 2022
Highly conducting single-molecule topological insulators based on mono- and di-radical cations journal July 2022
Kondo Effect in a Neutral and Stable All Organic Radical Single Molecule Break Junction journal April 2015
Designing organic spin filters in the coherent tunneling regime journal June 2011
Electron-Catalyzed Dehydrogenation in a Single-Molecule Junction journal May 2021
Transition between Nonresonant and Resonant Charge Transport in Molecular Junctions journal September 2021
Efficient Intermolecular Charge Transport in π-Stacked Pyridinium Dimers Using Cucurbit[8]uril Supramolecular Complexes journal February 2022
Single-Molecule Conductance of Functionalized Oligoynes: Length Dependence and Junction Evolution journal August 2013
Single Molecular Conductance of Tolanes: Experimental and Theoretical Study on the Junction Evolution Dependent on the Anchoring Group journal January 2012
Van der Waals interactions at metal/organic interfaces at the single-molecule level journal August 2012
Voltage-Modulated van der Waals Interaction in Single-Molecule Junctions journal January 2023
Contact Chemistry and Single-Molecule Conductance:  A Comparison of Phosphines, Methyl Sulfides, and Amines journal December 2007
Transition from Tunneling to Hopping in Single Molecular Junctions by Measuring Length and Temperature Dependence journal August 2010
Highly Planar and Completely Insulated Oligothiophenes: Effects of π-Conjugation on Hopping Charge Transport journal May 2019
Molecular Design Features for Charge Transport in Nonconjugated Radical Polymers journal July 2021
Diffusion-Cooperative Model for Charge Transport by Redox-Active Nonconjugated Polymers journal January 2018
Minimal attenuation for tunneling through a molecular wire journal January 1998
Increased Molecular Conductance in Oligo[n]phenylene Wires by Thermally Enhanced Dihedral Planarization journal May 2022
Mechanism of Electron Conduction in Self‐Assembled Alkanethiol Monolayer Devices journal December 2003
Transition from Tunneling to Hopping Transport in Long, Conjugated Oligo-imine Wires Connected to Metals journal March 2010
Electrical Resistance of Long Conjugated Molecular Wires journal June 2008
Extension of the AMBER force-field for the study of large nitroxides in condensed phases: an ab initio parameterization journal January 2010
Automated exploration of the low-energy chemical space with fast quantum chemical methods journal January 2020
Exploration of Chemical Compound, Conformer, and Reaction Space with Meta-Dynamics Simulations Based on Tight-Binding Quantum Chemical Calculations journal April 2019
Ghost transmission: How large basis sets can make electron transport calculations worse journal January 2010
A Green’s-Function Approach to Exchange Spin Coupling As a New Tool for Quantum Chemistry journal November 2015
Multiwfn: A multifunctional wavefunction analyzer journal December 2011
Design of an n-type low glass transition temperature radical polymer journal January 2021
Relationship between Molecular Structure and Electron Transfer in a Polymeric Nitroxyl-Radical Energy Storage Material journal July 2014