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Title: Effects of pH on the aqueous solubility of selected chlorinated phenols

Abstract

The aqueous solubilities are reported and correlated for 2,4-dichlorophenol, 2,4,6-trichlorophenol, 2,3,4,6-tetrachlorophenol, and pentachlorophenol over the pH range 2 to 14 as measured by high-pressure liquid chromatography with UV detection at 25 C. Correlation equations are proposed to estimate the aqueous solubility of these chlorophenols as a function of pH. Aqueous solubility influences the fate and toxicity of chemicals; thus, it is useful to determine the effects of environmental factors, such as temperature and pH, on their properties.

Authors:
; ; ; ;
Publication Date:
Research Org.:
Nankai Univ., Tianjin (CN)
OSTI Identifier:
20076017
Resource Type:
Journal Article
Journal Name:
Journal of Chemical and Engineering Data
Additional Journal Information:
Journal Volume: 45; Journal Issue: 3; Other Information: PBD: May-Jun 2000; Journal ID: ISSN 0021-9568
Country of Publication:
United States
Language:
English
Subject:
54 ENVIRONMENTAL SCIENCES; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CHLORINATED AROMATIC HYDROCARBONS; SOLUBILITY; PH VALUE; GROUND WATER; SURFACE WATERS; SOLVENT PROPERTIES; ENVIRONMENTAL TRANSPORT

Citation Formats

Huang, G.L., Xiao, H., Chi, J., Shiu, W.Y., and Mackay, D. Effects of pH on the aqueous solubility of selected chlorinated phenols. United States: N. p., 2000. Web. doi:10.1021/je990262k.
Huang, G.L., Xiao, H., Chi, J., Shiu, W.Y., & Mackay, D. Effects of pH on the aqueous solubility of selected chlorinated phenols. United States. doi:10.1021/je990262k.
Huang, G.L., Xiao, H., Chi, J., Shiu, W.Y., and Mackay, D. Thu . "Effects of pH on the aqueous solubility of selected chlorinated phenols". United States. doi:10.1021/je990262k.
@article{osti_20076017,
title = {Effects of pH on the aqueous solubility of selected chlorinated phenols},
author = {Huang, G.L. and Xiao, H. and Chi, J. and Shiu, W.Y. and Mackay, D.},
abstractNote = {The aqueous solubilities are reported and correlated for 2,4-dichlorophenol, 2,4,6-trichlorophenol, 2,3,4,6-tetrachlorophenol, and pentachlorophenol over the pH range 2 to 14 as measured by high-pressure liquid chromatography with UV detection at 25 C. Correlation equations are proposed to estimate the aqueous solubility of these chlorophenols as a function of pH. Aqueous solubility influences the fate and toxicity of chemicals; thus, it is useful to determine the effects of environmental factors, such as temperature and pH, on their properties.},
doi = {10.1021/je990262k},
journal = {Journal of Chemical and Engineering Data},
issn = {0021-9568},
number = 3,
volume = 45,
place = {United States},
year = {2000},
month = {6}
}