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Title: Analytical solution of the elastic Boltzmann transport equation in an infinite uniform medium using cumulant expansion

Journal Article · · Journal of Physical Chemistry B: Materials, Surfaces, Interfaces, amp Biophysical
DOI:https://doi.org/10.1021/jp994447+· OSTI ID:20050854

The authors study the analytical solution of the time-dependent elastic Boltzmann transport equation in an infinite uniform isotropic medium with an arbitrary phase function. The exact distribution in angle, and the spatial cumulants at any angle, exact up to an arbitrary high order n are calculated. At the second order, n = 2, an analytical, hence extremely useful combined distribution in position and angle, is obtained as a function of time. This distribution is Gaussian in position, but not in angle. The average center and spread of the half-width are exact. By the central limit theorem the complete distribution approaches this Gaussian distribution as the number of collisions (or time) increases. The center of this distribution advances in time, and an ellipsoidal contour that grows and changes shape provides a clear picture of the time evolution of the particle migration from near ballistic, though snake-like, and into the final diffusive regime. This second-order cumulant approximation also provides the correct ballistic limit. Algebraic expressions for the nth order cumulants are provided. The number of terms grows rapidly with n, but the expressives are recursive and easily automated.

Research Organization:
City Univ. of New York, NY (US)
Sponsoring Organization:
National Aeronautics and Space Administration; USDOE
OSTI ID:
20050854
Journal Information:
Journal of Physical Chemistry B: Materials, Surfaces, Interfaces, amp Biophysical, Vol. 104, Issue 16; Other Information: PBD: 27 Apr 2000; ISSN 1089-5647
Country of Publication:
United States
Language:
English

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