Reverse micelle synthesis and characterization of superparamagnetic MnFe{sub 2}O{sub 4} spinel ferrite nanocrystallites

doi:https://doi.org/10.1021/jp993552g

Title: Reverse micelle synthesis and characterization of superparamagnetic MnFe{sub 2}O{sub 4} spinel ferrite nanocrystallites

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Abstract

MnFe{sub 2}O{sub 4} nanoparticles are synthesized by using sodium dodecylbenzenesulfonate (NaDBS) to form water-in-toluene reverse micelles. The nanoparticles are single crystalline, and the average particle size can be controlled from 4 to 15 nm. High- and low-resolution transmission electron microscopy characterization has shown that the nanoparticles can have a size distribution as narrow as {approximately}9%. Neutron diffraction and magnetic measurements have been conducted on the nanoparticles with a diameter of 7.7 {+-} 0.7 nm. The results unambiguously prove that these MnFe{sub 2}O{sub 4} nanoparticles are truly superparamagnetic. The synthesis and characterization of these nanoparticles will facilitate the development of MnFe{sub 2}O{sub 4} nanoparticles for the potential applications such as contrast enhancement agents of magnetic resonance imaging and magnetic carriers for site-specific drug delivery.

Authors:: Liu, C; Zou, B; Zhang, Z J

Publication Date:: 2000-02-17

Research Org.:: Georgia Inst. of Tech., Atlanta, GA (US)

Sponsoring Org.:: National Science Foundation (NSF); USDOE

OSTI Identifier:: 20017537

DOE Contract Number:: AC05-96OR22464

Resource Type:: Journal Article

Journal Name:: Journal of Physical Chemistry B: Materials, Surfaces, Interfaces, amp Biophysical

Additional Journal Information:: Journal Volume: 104; Journal Issue: 6; Other Information: PBD: 17 Feb 2000; Journal ID: ISSN 1089-5647

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; SPINELS; MANGANESE OXIDES; IRON OXIDES; MICELLAR SYSTEMS; SYNTHESIS; PARTICLE SIZE; PARAMAGNETISM

Citation Formats


                    Liu, C, Zou, B, Rondinone, A., and Zhang, Z J. Reverse micelle synthesis and characterization of superparamagnetic MnFe{sub 2}O{sub 4} spinel ferrite nanocrystallites.  United States: N. p., 2000. 
        Web.  doi:10.1021/jp993552g.

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                    Liu, C, Zou, B, Rondinone, A., & Zhang, Z J. Reverse micelle synthesis and characterization of superparamagnetic MnFe{sub 2}O{sub 4} spinel ferrite nanocrystallites.  United States.  https://doi.org/10.1021/jp993552g

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                    Liu, C, Zou, B, Rondinone, A., and Zhang, Z J. Thu .  
        "Reverse micelle synthesis and characterization of superparamagnetic MnFe{sub 2}O{sub 4} spinel ferrite nanocrystallites".  United States.  https://doi.org/10.1021/jp993552g.

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@article{osti_20017537,

  title        = {Reverse micelle synthesis and characterization of superparamagnetic MnFe{sub 2}O{sub 4} spinel ferrite nanocrystallites},

  author       = {Liu, C and Zou, B and Rondinone, A. and Zhang, Z J},

  abstractNote = {MnFe{sub 2}O{sub 4} nanoparticles are synthesized by using sodium dodecylbenzenesulfonate (NaDBS) to form water-in-toluene reverse micelles. The nanoparticles are single crystalline, and the average particle size can be controlled from 4 to 15 nm. High- and low-resolution transmission electron microscopy characterization has shown that the nanoparticles can have a size distribution as narrow as {approximately}9%. Neutron diffraction and magnetic measurements have been conducted on the nanoparticles with a diameter of 7.7 {+-} 0.7 nm. The results unambiguously prove that these MnFe{sub 2}O{sub 4} nanoparticles are truly superparamagnetic. The synthesis and characterization of these nanoparticles will facilitate the development of MnFe{sub 2}O{sub 4} nanoparticles for the potential applications such as contrast enhancement agents of magnetic resonance imaging and magnetic carriers for site-specific drug delivery.},

  doi          = {10.1021/jp993552g},

  url          = {https://www.osti.gov/biblio/20017537},
  journal      = {Journal of Physical Chemistry B: Materials, Surfaces, Interfaces, amp Biophysical},

  issn         = {1089-5647},

  number       = 6,

  volume       = 104,

  place        = {United States},

  year         = {2000},

  month        = {2}

}

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