The fate of a bimetallic ethylene dimerization catalyst: Synthesis and structure of (dfepe){sub 2}Ir{sub 2}({mu}-{eta}{sup 1}:{eta}{sup 3}-C{sub 4}H{sub 6})({mu}-H)(H) (dfepe = (C{sub 2}F{sub 5}){sub 2}PCH{sub 2}CH{sub 2}P(C{sub 2}F{sub 5}){sub 2})
Solutions of (dfepe){sub 2}Ir{sub 2}({mu}-H){sub 3}(H) (1; dfepe = (C{sub 2}F{sub 5}){sub 2}PCH{sub 2}CH{sub 2}P(C{sub 2}F{sub 5}){sub 2}) react with 1 atm of ethylene at ambient temperatures to catalytically produce a mixture of trans- and cis-2-butenes and the diiridium methylallyl complex (dfepe){sub 2}Ir{sub 2}({mu}-{eta}{sup 1}:{eta}{sup 3}-C{sub 4}H{sub 6})({mu}-H)(H) (2).
- Research Organization:
- Univ. of Wyoming, Laramie, WY (US)
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 20013626
- Journal Information:
- Organometallics, Vol. 18, Issue 26; Other Information: PBD: 20 Dec 1999; ISSN 0276-7333
- Country of Publication:
- United States
- Language:
- English
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