New self-assembly luminescent molecular triangle and square rhenium(I) complexes
The design and study of well-arranged metal-containing macrocycles is one of the major current research areas in modern supramolecular chemistry. Apart from their particular structural features, supramolecular species formed by self-assembly of transition metals introduce many special functional properties such as luminescence, redox activity, and magnetism into the structure. More recently, transition metal based molecular squares have been synthesized by utilizing self-assembly of preorganized metal centers and pyridine-based bridging ligands. The 90{degree} bonding angles between ligands in transition metal complexes provide an attractive feature for constructing macrocyclic structures.
- Research Organization:
- State Univ. of New York, Binghamton, NY (US)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- FG02-89ER14039
- OSTI ID:
- 20003187
- Journal Information:
- Inorganic Chemistry, Vol. 38, Issue 19; Other Information: PBD: 20 Sep 1999
- Country of Publication:
- United States
- Language:
- English
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